[11-[(2-溴-2-甲基丙酰基)氧基]十一烷基]膦酸 | 1095957-23-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 中文名称: [11-[(2-溴-2-甲基丙酰基)氧基]十一烷基]膦酸
• 英文名称: 2-bromo-2-methyl-propionic acid 11-phosphono-undecyl ester
• 英文别名: [11-[(2-Bromo-2-methylpropanoyl)oxy]undecyl]phosphonic Acid；11-(2-bromo-2-methylpropanoyl)oxyundecylphosphonic acid
• CAS: 1095957-23-5
• 化学式: C₁₅H₃₀BrO₅P
• 分子量: 401.278
• InChiKey: SBFNQWAMVLRANY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  22
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

安全信息

• WGK Germany：
  3

反应信息

• 作为产物：
  描述：

  11'-bromoundecyl-2-bromo-2-methyl propionate 在 三甲基溴硅烷 作用下， 反应 18.75h， 生成 [11-[(2-溴-2-甲基丙酰基)氧基]十一烷基]膦酸
  参考文献：
  名称：

  Inorganic Oxide Core, Polymer Shell Nanocomposite as a High K Gate Dielectric for Flexible Electronics Applications

  摘要：

  Organic/inorganic core shell nanoparticles have been synthesized using high K TiO2 as the core nanoparticle, and polystyrene as the shell. This material is easy to process and forms transparent continuous thin films, which exhibit a dielectric constant enhancement of over 3 times that of bulk polystyrene. This new dielectric material has been incorporated into capacitors and thin film transistors (TFTs). Mobilities approaching 0.2 cm(2)/V (.) s have been measured for pentacene TFTs incorporating the new TiO2 polystyrene nanostructured gate dielectric, indicating good surface properties for pentacene film growth. This novel strategy for generating high K flexible gate dielectrics will be of value in improving organic and flexible electronic device performance.

  DOI：

  10.1021/ja052035a

文献信息

• Shaving article with surface modification
  申请人：The Gillette Company LLC

  公开号：US10751896B2

  公开（公告）日：2020-08-25

  A method of making a shaving article comprising a substrate comprising stainless steel; and an external polymer coating comprising polymer brushes, the method comprising the steps of: providing said substrate; providing a initiating species comprising an anchor group that is chemically reactive with surface moieties on the substrate, and a polymerization initiator group; reacting said anchor group with said surface moieties of the substrate; providing monomers reactive for polymerization with the polymerization initiator; and polymerizing the monomers with the initiator group of the initiating species.

  一种制造剃须用品的方法，包括由不锈钢组成的基材；以及由聚合物刷组成的外部聚合物涂层，该方法包括以下步骤：提供所述基材；提供由与基材表面分子具有化学反应性的锚基团和聚合引发剂基团组成的引发剂；使所述锚基团与基材的所述表面分子反应；提供与聚合引发剂具有聚合反应性的单体；以及使单体与引发剂的引发剂基团聚合。
• Betaine polymer coatings prepared by living polymerization
  申请人：Aculon, Inc.

  公开号：US11214691B2

  公开（公告）日：2022-01-04

  A betaine-containing polymer film that can be formed on a substrate surface using living polymerization such as controlled radical polymerization is disclosed.

  本发明公开了一种含甜菜碱的聚合物薄膜，该薄膜可通过活聚合（如受控自由基聚合）在基底表面形成。
• COATING OF METAL PIGMENTS USING PHOSPHONIC ACID-BASED COMPOUNDS
  申请人：SUNDARARAMAN Anand

  公开号：US20140076201A1

  公开（公告）日：2014-03-20

  A coated metal pigment that has excellent passivation, dispersion and adhesion properties, a method for producing the coated metal pigment and a coating composition that includes the coated metal pigment are described. The disclosed method generally involves the use of a compound with the following formula (A)
• US20140272149A1
  申请人：——

  公开号：US20140272149A1

  公开（公告）日：2014-09-18
• US20140272150A1
  申请人：——

  公开号：US20140272150A1

  公开（公告）日：2014-09-18