2,9-bis(5-tert-butyl-2-hydroxyphenyl)-1,10-phenanthroline | 241822-69-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2,9-bis(5-tert-butyl-2-hydroxyphenyl)-1,10-phenanthroline
• 英文别名: 2,9-bis(5-tert-butyl-2-hydroxyphenyl)-1,10-phenanthrolinechloride；4-Tert-butyl-2-[9-(5-tert-butyl-2-hydroxyphenyl)-1,10-phenanthrolin-2-yl]phenol；4-tert-butyl-2-[9-(5-tert-butyl-2-hydroxyphenyl)-1,10-phenanthrolin-2-yl]phenol
• CAS: 241822-69-5
• 化学式: C₃₂H₃₂N₂O₂
• 分子量: 476.618
• InChiKey: AVDMEDJYTRSOKM-UHFFFAOYSA-N

物化性质

• 沸点：
  661.9±55.0 °C(Predicted)
• 密度：
  1.177±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  36
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  66.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,9-bis(5-tert-butyl-2-hydroxyphenyl)-1,10-phenanthroline 在 四丁基溴化铵 、 potassium carbonate 、 三氟乙酸 作用下， 以 乙醇 、 氯仿 为溶剂， 反应 9.0h， 生成 2,9-(R,R)-N,N'-bis(5-tert-butyl-salicylidene)-1,2-cyclohexanediamine-1,10-phenanthroline
  参考文献：
  名称：

  Synthesis of dinucleating phenanthroline-based ligands

  摘要：

  The phenolic bridged dinucleating phenanthroline-pyridine, phenanthroline-phosphine, phenanthroline-alcohol, and phenanthroline-imine ligands have been synthesized from I,10-phenanthroline via key Stille and Suzuki cross couplings. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00428-7
• 作为产物：
  描述：

  2,9-bis(5-tert-butyl-2-methoxyphenyl)-1,10-phenanthroline 在 吡啶盐酸盐 作用下， 反应 3.0h， 以91%的产率得到2,9-bis(5-tert-butyl-2-hydroxyphenyl)-1,10-phenanthroline
  参考文献：
  名称：

  Synthesis of dinucleating phenanthroline-based ligands

  摘要：

  The phenolic bridged dinucleating phenanthroline-pyridine, phenanthroline-phosphine, phenanthroline-alcohol, and phenanthroline-imine ligands have been synthesized from I,10-phenanthroline via key Stille and Suzuki cross couplings. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00428-7

文献信息

• Synthesis and Reactivity of Nonbridged Metal−Metal Bonded Rhodium and Iridium Phenanthroline-Based N₂O₂ Dimers
  作者：Maoqi Feng、Kin Shing Chan

  DOI：10.1021/om010903g

  日期：2002.6.1

  Nonbridged metal dimers of phenanthroline-based N2O2 ligands of rhodium and iridium have been synthesized from the reactions of metal hydrides with TEMPO (2,2‘,6,6‘-tetramethylpiperidinyloxy). Modification of phenathroline ligands has led to more lipophilic metal complexes. The oxidative additions of the metal dimers with methyl iodide, silane, and hydrogen have been studied.

  从金属氢化物与TEMPO（2,2'，6,6'-四甲基哌啶基氧基）的反应合成了基于菲咯啉的铑和铱的N 2 O 2配体的非桥金属二聚体。菲咯啉配体的修饰导致了更多的亲脂性金属络合物。已经研究了金属二聚体与甲基碘，硅烷和氢的氧化加成。
• EP2133336
  申请人：——

  公开号：——

  公开（公告）日：——
• MODIFIED METAL COMPLEX AND USE THEREOF
  申请人：Matsunaga Tadafumi

  公开号：US20100105909A1

  公开（公告）日：2010-04-29

  A modified metal complex obtained by subjecting a metal complex containing an organic compound having one nitrogen-containing aromatic heterocycle and four or more structures of a phenol, thiophenol, aniline or nitrogen-containing aromatic heterocyclic ring or an organic compound having two or more phenol rings and three or more nitrogen-containing aromatic heterocycles, in its molecule as a ligand, to a heating, radiation irradiation or discharge treatment until a mass reduction rate after the treatment becomes from 1 to 90 mass %, thereby the complex shows a carbon content after the treatment of 5 mass % or more.
• US8519131B2
  申请人：——

  公开号：US8519131B2

  公开（公告）日：2013-08-27