3,3'-(ethane-1,2-diyl)bis(1-phenyl-1H-pyrazole-5-carboxylic acid)

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 3,3'-(ethane-1,2-diyl)bis(1-phenyl-1H-pyrazole-5-carboxylic acid)
• 英文别名: 5-[2-(5-Carboxy-1-phenylpyrazol-3-yl)ethyl]-2-phenylpyrazole-3-carboxylic acid；5-[2-(5-carboxy-1-phenylpyrazol-3-yl)ethyl]-2-phenylpyrazole-3-carboxylic acid
• 化学式: C₂₂H₁₈N₄O₄
• 分子量: 402.409
• InChiKey: BFTKAVAHWZYCCP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  30
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  110
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3,3'-(ethane-1,2-diyl)bis(1-phenyl-1H-pyrazole-5-carboxylic acid) 在 potassium permanganate 、 水 作用下， 生成 1-苯基-3-吡唑甲酸
  参考文献：
  名称：

  Musante; Berretti, Gazzetta Chimica Italiana, 1949, vol. 79, p. 666,673

  摘要：

  DOI：
• 作为产物：
  描述：

  diethyl 2,4,7,9-tetraoxodecanedione 在 氢氧化钾 、 溶剂黄146 作用下， 生成 3,3'-(ethane-1,2-diyl)bis(1-phenyl-1H-pyrazole-5-carboxylic acid)
  参考文献：
  名称：

  Musante; Berretti, Gazzetta Chimica Italiana, 1949, vol. 79, p. 666,673

  摘要：

  DOI：

文献信息

• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20150380666A1

  公开（公告）日：2015-12-31

  Compounds having the structure of Formula M(L A ) x (L B ) y and Formula III, are disclosed. In Formula M(L A ) x (L B ) y , Ligand L A is and ligand L B is a mono anionic bidentate ligand. In these compounds, metal M has an atomic number greater than 40; x is 1, 2, or 3; y is 0, 1, or 2; x+y is the oxidation state of metal M; L 11 represents a linking group selected from alkyl, cycloalkyl, aryl, and heteroaryl; L 12 represents a linking group selected from NR 15 and PR 15 ; each R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 11 , R 12 , R 13 , R 14 , and R 15 is independently selected from a group of substituents, wherein any adjacent substituents are optionally joined to form a fused or unfused ring; and L A and L B are optionally joined to form a ligand that is at least tetradentate. Formulations and devices, such as OLEDs, that include the compound of Formula M(L A ) x (L B ) y are also described.

  揭示了具有Formula M(LA)x(LB)y和Formula III结构的化合物。在Formula M(LA)x(LB)y中，配体LA和配体LB分别是单阴离子双齿配体。在这些化合物中，金属M的原子序数大于40；x为1、2或3；y为0、1或2；x+y为金属M的氧化态；L11代表从烷基、环烷基、芳基和杂环烷基中选择的连接基；L12代表从NR15和PR15中选择的连接基；每个R1、R2、R3、R4、R5、R6、R11、R12、R13、R14和R15都是从一组取代基中独立选择的，其中任何相邻的取代基可以选择连接以形成融合或非融合环；LA和LB可以选择连接以形成至少四齿配体。还描述了包括Formula M(LA)x(LB)y化合物的配方和器件，例如OLEDs。
• 네일건용 와셔 세트 구조
  申请人：YOUNGWOO FASTENERS CO., LTD. (주) 영우화스너(119950083608) Corp. No ▼ 134511-0007622

  公开号：KR20160001679U

  公开（公告）日：2016-05-18

  일종의 네일건용 와셔 세트 구조는 다수의 편평상 플라스틱 와셔와 연결봉을 포함한다. 각각의 편평상 플라스틱 와셔의 양면은 모두 평탄면이고, 또한 중앙에 관통공이 구비된다. 연결봉은 각각의 편평상 플라스틱 와셔의 관통공에 관통 설치되어, 각각의 편평상 플라스틱 와셔를 직렬로 중첩 연결시킨다. 그 중 상단에 당김부가 구비되고, 하단에 근접한 부위에 편평상 플라스틱 와셔의 관통홀 직경보다 큰 걸림부가 구비된다. [색인어] 네일건용 와셔 세트 구조, 편평상 플라스틱 와셔, 표면, 오목부, 관통공, 금속 연결봉, 당김부, 걸림부

  一种指甲用垫圈套装结构包括多个扁平状塑料垫圈和连接杆。每个扁平状塑料垫圈的两面均为平面，并且中间设有贯通孔。连接杆分别安装在每个扁平状塑料垫圈的贯通孔中，将每个扁平状塑料垫圈串联连接。在顶部设有拉力部分，并且在靠近底部的区域设有比扁平状塑料垫圈的贯通孔直径更大的挂钩部分。【索引词】指甲用垫圈套装结构，扁平状塑料垫圈，表面，凹部，贯通孔，金属连接杆，拉力部分，挂钩部分
• Organic electroluminescent materials and devices
  申请人：Universal Display Corporation

  公开号：US10700293B2

  公开（公告）日：2020-06-30

  Compounds having the structure of Formula M(LA)x(LB)y and Formula III, are disclosed. In Formula M(LA)x(LB)y, Ligand LA is and ligand LB is a mono anionic bidentate ligand. In these compounds, metal M has an atomic number greater than 40; x is 1, 2, or 3; y is 0, 1, or 2; x+y is the oxidation state of metal M; L11 represents a linking group selected from alkyl, cycloalkyl, aryl, and heteroaryl; L12 represents a linking group selected from NR15 and PR15; each R1, R2, R3, R4, R5, R6, R11, R12, R13, R14, and R15 is independently selected from a group of substituents, wherein any adjacent substituents are optionally joined to form a fused or unfused ring; and LA and LB are optionally joined to form a ligand that is at least tetradentate. Formulations and devices, such as OLEDs, that include the compound of Formula M(LA)x(LB)y(LC)z are also described.

  具有式 M(LA)x(LB)y 和式 III 结构的化合物、 公开了具有式 M(LA)x(LB)y 和式 III 结构的化合物。在式 M(LA)x(LB)y 中，配体 LA 是 配体 LB 是单阴离子双齿配体。在这些化合物中，金属 M 的原子序数大于 40；x 为 1、2 或 3；y 为 0、1 或 2；x+y 为金属 M 的氧化态；L11 代表选自烷基、环烷基、芳基和杂芳基的连接基团；L12 代表选自 NR15 和 PR15 的连接基团；每个 R1、R2、R3、R4、R5、R6、R11、R12、R13、R14 和 R15 都独立地选自一组取代基，其中任何相邻取代基可选择连接以形成融合或未融合的环；以及 LA 和 LB 可选择连接以形成至少为四价的配体。还描述了包括式 M(LA)x(LB)y(LC)z 的化合物的制剂和器件，如 OLED。
• US9911931B2
  申请人：——

  公开号：US9911931B2

  公开（公告）日：2018-03-06
• Musante; Berretti, Gazzetta Chimica Italiana, 1949, vol. 79, p. 666,673
  作者：Musante、Berretti

  DOI：——

  日期：——