(1,1,2,3,3,3-hexafluoro-propyl)-propyl ether | 357-99-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (1,1,2,3,3,3-hexafluoro-propyl)-propyl ether
• 英文别名: (1,1,2,3,3,3-Hexafluor-propyl)-propyl-aether；1,1,1,2,3,3-Hexafluoro-3-propoxypropane
• CAS: 357-99-3
• 化学式: C₆H₈F₆O
• 分子量: 210.119
• InChiKey: RALMJSSSISMLSH-UHFFFAOYSA-N

物化性质

• 沸点：
  92-93 °C
• 密度：
  1.260 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  丙醇 、 六氟丙烯 在 氢氧化钾 作用下， 生成 (1,1,2,3,3,3-hexafluoro-propyl)-propyl ether
  参考文献：
  名称：

  Knunjanz et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1953, p. 282,288;engl.Ausg.S.255,259

  摘要：

  DOI：

文献信息

• PROCESS FOR PRODUCING 1,1,1,3,3-PENTAFLUOROPROPANE
  申请人：Daikin Industries, Ltd.

  公开号：EP1231195A1

  公开（公告）日：2002-08-14

  In a process for producing 1,1,1,3,3-pentafluoropropane which comprises a liquid-phase reaction step for fluorination of 1,1,1,3,3-pentahalopropane (wherein at least one of halogen atoms is not fluorine) with HF in the presence of an antimony pentahalide catalyst in a reactor to obtain a reaction mixture comprising 1,1,1,3,3-pentafluoropropane and the antimony pentahalide catalyst, the fluorination is conducted at a reaction temperature less than 50 °C.

  在一种生产 1,1,1,3,3-五氟丙烷的工艺中，包括一个液相反应步骤，在五卤 化锑催化剂存在下，将 1,1,1,3,3-五氟丙烷（其中至少一个卤素原子不是氟）与氢氟酸 在反应器中进行氟化反应，得到一种反应混合物，其中包括 1、1,1,3,3-五氟丙烷和五卤化锑催化剂的反应混合物，氟化反应在低于 50 °C 的反应温度下进行。
• METHOD FOR PRODUCING FLUORINE-CONTAINING CARBOXYLIC ACID ESTER
  申请人：Central Glass Company, Limited

  公开号：EP2161249A1

  公开（公告）日：2010-03-10

  [Task] It is to provide a production method that the target fluorine-containing carboxylic acid ester can be obtained from a fluorine-containing ether by a one-step reaction, that a complicated step and a troublesome operation are not necessary, and that an excessive energy is not consumed. [Solving Means] A fluorine-containing carboxylic acid ester represented by the general formula R1HCFCOOR2 is produced by reacting a fluorine-containing ether represented by the general formula R1HCFCF2OR2 (R1 represents either of a fluorine atom and a C1-4 perfluoroalkyl group, and R2 represents a monovalent organic group) with water in the presence of a solid catalyst.

  [任务]提供一种生产方法，它可以通过一步反应从含氟醚中获得目标含氟羧酸酯，不需要复杂的步骤和麻烦的操作，也不会消耗过多的能量。 [解决方法]通式 R1HCFCOOR2 所代表的含氟羧酸酯是由通式 R1HCFCF2OR2 所代表的含氟醚（R1 代表氟原子和 C1-4 全氟烷基中的任一个，R2 代表一价有机基团）在固体催化剂存在下与水反应制得的。
• Process for producing 1,1,1,3,3-pentafluoropropane
  申请人：Daikin Industries, Ltd.

  公开号：US20040162451A1

  公开（公告）日：2004-08-19

  In a process for producing 1,1,1,3,3-pentafluoropropane which has a liquid-phase reaction step for fluorination of 1,1,1,3,3-pentahalopropane (wherein at least one of halogen atoms is not fluorine) with HF in the presence of antimony pentahalide catalyst in a reactor to obtain a reaction mixture comprising 1,1,1,3,3-pentafluoropropane and the antimony pentahalide catalyst, the fluorination is conducted at a reaction temperature less than 50° C.

  一种生产 1,1,1,3,3-五氟丙烷的工艺，其液相反应步骤是在五卤化锑催化剂存在下，在反应器中将 1,1,1,3,3-五氟丙烷（其中至少有一个卤素原子不是氟）与氢氟酸进行氟化反应，得到一种反应混合物，该混合物包括 1、1,1,3,3-五氟丙烷和五卤化锑催化剂的反应混合物，氟化反应在低于 50°C 的反应温度下进行。
• METHOD FOR PURIFYING 1,1,1,3,3-PENTAFLUOROPROPANE
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0921109B1

  公开（公告）日：2002-01-23
• Method for Producing Fluorine-Containing Carboxylic Acid Ester
  申请人：Kondo Takeshi

  公开号：US20100197957A1

  公开（公告）日：2010-08-05

  [Task] It is to provide a production method that the target fluorine-containing carboxylic acid ester can be obtained from a fluorine-containing ether by a one-step reaction, that a complicated step and a troublesome operation are not necessary, and that an excessive energy is not consumed. [Solving Means] A fluorine-containing carboxylic acid ester represented by the general formula R 1 HCFCOOR 2 is produced by reacting a fluorine-containing ether represented by the general formula R 1 HCFCF 2 OR 2 (R 1 represents either of a fluorine atom and a C 1-4 perfluoroalkyl group, and R 2 represents a monovalent organic group) with water in the presence of a solid catalyst.