1-(3-甲基环己烯-1-基)乙酮 | 60048-69-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-(3-甲基环己烯-1-基)乙酮
• 英文名称: 1-(3-methyl-cyclohex-1-enyl)-ethanone
• 英文别名: 1-(3-Methyl-cyclohex-1-enyl)-aethanon；1-Acetyl-3-methylcyclohexen；1-(3-Methylcyclohex-1-en-1-yl)ethan-1-one；1-(3-methylcyclohexen-1-yl)ethanone
• CAS: 60048-69-3
• 化学式: C₉H₁₄O
• 分子量: 138.21
• InChiKey: KUAOSSRFCWYCMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  甲基碘化镁 、 乙醚 、 1-(3-甲基环己烯-1-基)乙酮 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Haworth; Perkin; Wallach, Justus Liebigs Annalen der Chemie, 1911, vol. 379, p. 142

  摘要：

  DOI：
• 作为产物：
  描述：

  1-(3-甲基环己-2-烯-1-基)乙酮 在 盐酸 作用下， 以 乙醇 为溶剂， 以82 mg的产率得到1-(3-甲基环己烯-1-基)乙酮
  参考文献：
  名称：

  .gamma.-Alkylation of .alpha.,.beta.-unsaturated ketones. .gamma.-Arylsulfonyl groups as regioselective control elements

  摘要：

  DOI：

  10.1021/ja00525a023

文献信息

• Allylic Oxidations Catalyzed by Dirhodium Catalysts under Aqueous Conditions
  申请人：Doyle Michael P.

  公开号：US20090093638A1

  公开（公告）日：2009-04-09

  The present invention relates to compositions and methods for achieving the efficient allylic oxidation of organic molecules, especially olefins and steroids, under aqueous conditions. The invention concerns the use of dirhodium (II,II) “paddlewheel complexes, and in particular, dirhodium carboximate and tert-butyl hydroperoxide as catalysts for the reaction. The use of aqueous conditions is particularly advantageous in the allylic oxidation of 7-keto steroids, which could not be effectively oxidized using anhydrous methods, and in extending allylic oxidation to enamides and enol ethers.

  本发明涉及在水相条件下实现有机分子的高效烯丙基氧化的组合物和方法，特别是烯烃和类固醇。该发明涉及使用二铑（II,II）“桨轮”配合物，特别是二铑羧酸酯和叔丁基过氧化氢作为催化剂进行反应。在烯丙基氧化7-酮类固醇中使用水相条件特别有优势，无法使用无水方法有效氧化，以及将烯丙基氧化扩展到烯酰胺和烯醇醚。
• Sato,T. et al., Journal of the Chemical Society. Perkin transactions I, 1976, p. 788 - 791
  作者：Sato,T. et al.

  DOI：——

  日期：——
• LANSBURY P. T.; ERWIN R. W.; JEFFREY D. A., J. AMER. CHEM. SOC., 1980, 102, NO 5, 1602-1608
  作者：LANSBURY P. T.、 ERWIN R. W.、 JEFFREY D. A.

  DOI：——

  日期：——
• COOLING SENSATION AGENT COMPOSITION AND SENSORY STIMULATION AGENT COMPOSITION
  申请人：Ishida Kenya

  公开号：US20110117147A1

  公开（公告）日：2011-05-19

  The invention relates to a cooling sensation agent composition with a prolonged cool sensation effect comprising at least one compound selected from Formula (1) wherein each of A and B is a hydrogen atom or a hydrocarbon group which may have one or more substituents, in which A and B are not hydrogen atoms simultaneously, and the total number of carbon atoms in A and B is in the range of 6 to 18; and Formulae (2) to (4) wherein R1, R2, and R3 each represent a residue of an alcohol selected from 1-menthol, 1-isopulegol, 3-(1-menthoxy)propan-1,2-diol, 2-(1-menthoxy)ethan-1-ol, 3-(1-menthoxy)propan-1-ol, 2-methyl-3-(1-menthoxy)propan-1,2-diol and para-menthan-3,8-diol), and R4 represents a residue of a branched or straight-chain, cyclic or linear, or saturated or unsaturated alcohol having 6 to 18 carbon atoms that may have one or more aromatic rings that may have a condensed ring and substituent groups such as hydroxyl and ether groups; and R6 represents a hydrocarbon group having 11 to 19 carbon atoms that may be branched and contain one or more unsaturated bonds. The invention also relates to a sensory stimulation agent composition comprising the cooling sensation agent composition; a flavor or fragrance composition, a beverage or food product, a perfume or cosmetic product, a toiletry product, a daily utensil product or grocery, a fiber, a fiber product, a cloth or a medicine comprising the cooling sensation agent composition or the sensory stimulation agent composition; a production method thereof; a cooling processing method of a fiber, fiber product or a cloth, comprising compounding the cooling sensation agent composition or the sensory stimulation agent composition; and new compounds.
• US8163944B2
  申请人：——

  公开号：US8163944B2

  公开（公告）日：2012-04-24