2-[2-(2-乙氧基乙氧基)乙氧基]乙基丙烯酸酯 | 45180-95-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-[2-(2-乙氧基乙氧基)乙氧基]乙基丙烯酸酯
• 英文名称: 3,6,9-trioxaundecyl acrylate
• 英文别名: 2-(2-(2-ethoxyethoxy)ethoxy)ethyl acrylate；2-[2-(2-ethoxyethoxy)ethoxy]ethyl prop-2-enoate
• CAS: 45180-95-8
• 化学式: C₁₁H₂₀O₅
• 分子量: 232.277
• InChiKey: WPDXVLVDHUDHPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  16
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  反式-β-金合欢烯 、 2-[2-(2-乙氧基乙氧基)乙氧基]乙基丙烯酸酯 在 5%-palladium/activated carbon 氢气 作用下， 以 甲苯 为溶剂， 75.0 ℃ 、2.86 MPa 条件下， 反应 30.0h， 生成 2-(2-(2-ethoxyethoxy)ethoxy)ethyl 3-(4,8-dimethylnonyl)cyclohexanecarboxylate 、 2-(2-(2-ethoxyethoxy)ethoxy)ethyl 4-(4,8-dimethylnonyl)cyclohexane-carboxylate
  参考文献：
  名称：

  [EN] SURFACTANTS
  [FR] TENSIOACTIFS

  摘要：

  这个应用涉及到碳氢化合物萜类化合物（例如，肉豆蔻烯或芬尼烯）的衍生物，制备这些衍生物的方法，以及将这些衍生物用作表面活性剂的用途。

  公开号：

  WO2012103156A1
• 作为产物：
  描述：

  三乙二醇 在 氢氧化钾 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 生成 2-[2-(2-乙氧基乙氧基)乙氧基]乙基丙烯酸酯
  参考文献：
  名称：

  通过自由基环化形成大环醚：链长，取代基和溶剂的影响。

  摘要：

  通过三丁基锡烷自由基还原衍生自三，四，五，五，六和七乙二醇的ω-碘多聚氧杂烷基丙烯酸酯，得到未环化还原产物和通过内环化形成的大环醚的混合物。在精心定义的条件下，确定80℃下苯中的中间体自由基环化的速率常数为15 x 10（4），13 x 10（4），5.1 x 10（4），10 x 10（4）和3.6 x 10（4）s（-）（1），分别用于形成12、15、18、21和24元环。这些值表明，与先前报道的烯基物质的环化相比，链中氧原子的存在使速率增加了10-30倍。苯在80摄氏度时的速率常数和甲基丙烯酸酯，巴豆酸酯，已经确定了8-碘-3,6-二氧杂辛醇的肉桂酸酯，马来酸酯和富马酸酯。在极性不同的溶剂中丙烯酸8-碘-3,6-二氧杂辛酯的还原表明环化速率具有相对较低的溶剂依赖性。

  DOI：

  10.1021/jo980259o

文献信息

• METHOD FOR PREVENTION OF PREMATURE POLYMERIZATION
  申请人：Nitto Europe N.V.

  公开号：US20160280673A1

  公开（公告）日：2016-09-29

  The present invention relates to a method for prevention of premature polymerization during the preparation, purification, transportation and storage of a polymerizable compound with at least one conjugated unsaturated group in the presence of an azine dye-based compound as inhibitor. Further the present invention relates to methods of preparing such inhibitors as well as to the inhibitors itself, as well as to methods of improving solubility and stability of dissolved inhibitors.

  本发明涉及一种在具有至少一个共轭不饱和基团的聚合物化合物的制备、纯化、运输和储存过程中预防聚合物过早聚合的方法，其中存在一种以偶氮染料为基础的化合物作为抑制剂。此外，本发明还涉及制备此类抑制剂的方法，以及抑制剂本身，以及改善溶解的抑制剂的溶解性和稳定性的方法。
• INK COMPOSITION, INKJET RECORDING METHOD AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：MOCHIZUKI Kyohei

  公开号：US20110242191A1

  公开（公告）日：2011-10-06

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a 1 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b 1 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a 2 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b 2 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c 2 ) a molding step of molding the printed material.

  提供了一种墨水组合物，包括（组分a）一种开链和/或环状醚键含有单官能基（甲基）丙烯酸酯，（组分b）一种或多种单官能基乙烯基不饱和化合物，所述化合物选自包含多环脂肪族基的单官能基（甲基）丙烯酸酯和N-乙烯基-2-己内酰胺的群组，（组分c）一种聚合引发剂，（组分e）一种多官能基（甲基）丙烯酸酯，相对于墨水组合物不大于10重量％，以及（组分f）一种含有氟代烃基或硅氧烷结构的聚合物，其中（组分a）/（组分b）的重量比为0.7到1.9。还提供了一种喷墨记录方法，包括（a1）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤和（b1）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得固化图像，以及一种生产模塑印刷材料的过程，包括（a2）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤，（b2）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得具有固化图像的印刷材料，以及（c2）模塑印刷材料的模塑步骤。
• METAL FILM MATERIAL AND METHOD FOR MANUFACTURING THE SAME
  申请人：Fujifilm Corporation

  公开号：US20130186672A1

  公开（公告）日：2013-07-25

  The present invention provides a method for manufacturing a metal film material, the method including: applying an ink composition by discharging the ink composition onto a substrate via an inkjet method, the ink composition containing at least one first monomer having at least one group selected from the group consisting of a cyano group, an alkyloxy group, an amino group, a pyridine residue, a pyrrolidone residue, an imidazole residue, an alkylsulfanyl group, or a cyclic ether residue, at least one second monomer that has polyfunctionality, and at least one polymerization initiator, a total monomer content in the ink composition being 85% by mass or greater; forming a cured film by carrying out at least one of light exposure or heating of the ink composition that has been applied; applying a plating catalyst or a precursor thereof to the cured film; and a plating processing step of performing plating with respect to the plating catalyst or precursor thereof that has been applied.

  本发明提供了一种制造金属薄膜材料的方法，该方法包括：通过喷墨方法将含有至少一种第一单体的油墨组成物排放到基板上，所述第一单体至少包含以下组中的一种：氰基、烷氧基、氨基、吡啶残基、吡咯烷酮残基、咪唑残基、烷基硫基或环氧基，同时含有至少一种具有多重功能的第二单体和至少一种聚合引发剂，油墨组成物中的总单体含量为85％或更高；通过进行光照或加热已施加的油墨组成物形成固化膜；将电镀催化剂或其前体应用于固化膜上；并对已应用的电镀催化剂或其前体进行电镀处理步骤。
• Novel scale inhibiting copolymer and method for inhibiting scale deposition
  申请人：The B.F. GOODRICH Company

  公开号：EP0133210A2

  公开（公告）日：1985-02-20

  Water-soluble copolymers are useful in treating industrial process water in threshold inhibition amounts. Such copolymers are selected from copolymers of an acrylic acid, an acrylamide, and an alkoxyalkyl acrylate ester; and copolymers of an acrylic acid or a salt thereof, a lower alkenyl carboxylate, and optionally a salt of a lower alkenyl sulfonate.

  水溶性共聚物可用于处理阈值抑制量的工业加工用水。此类共聚物可选自丙烯酸、丙烯酰胺和丙烯酸酯烷氧基烷基酯的共聚物；以及丙烯酸或其盐、低级烯基羧酸盐和低级烯基磺酸盐的共聚物。
• UV-Ray curable resin composition and coated optical fiber
  申请人：NIPPON TELEGRAPH AND TELEPHONE CORPORATION

  公开号：EP0200366A1

  公开（公告）日：1986-11-05

  A UV-ray curable resin composition comprising a polyurethane derived from a polyether polyol and a diene polymer having hydroxyl group, said polyurethane having polymerizable double bond different from the carbon-carbon double bonds contained in said diene polymer having hydroxyl group, and a coated optical fiber having a coated layer comprising the cured product of said resin composition. This composition has good coating characteristics, and the cured product thereof has small modulus over a wide temperature range and good hydrolysis resistance, and water absorption resistance. The coated optical fiber has small transmission loss over a wide temperature range and has high strength even in water.

  一种可紫外线固化的树脂组合物，包含由聚醚多元醇衍生的聚氨酯和具有羟基的二烯聚合物，所述聚氨酯具有与所述具有羟基的二烯聚合物所含碳碳双键不同的可聚合双键；以及一种涂覆光纤，其涂覆层包含所述树脂组合物的固化产物。 该组合物具有良好的涂覆特性，其固化产物在较宽的温度范围内具有较小的模量、良好的耐水解性和抗吸水性。 所涂覆的光纤在较宽的温度范围内具有较小的传输损耗，即使在水中也具有较高的强度。