(N,N,N',N'-tetramethylethylenediamine)Pt(OH)(OCH3)(CH3)2 | 215101-95-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (N,N,N',N'-tetramethylethylenediamine)Pt(OH)(OCH3)(CH3)2
• 英文别名: carbanide;methanolate;platinum(4+);N,N,N',N'-tetramethylethane-1,2-diamine;hydroxide
• CAS: 215101-95-4
• 化学式: C₉H₂₆N₂O₂Pt
• 分子量: 389.398
• InChiKey: CWGCHTVLITYSFK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (N,N,N',N'-tetramethylethylenediamine)Pt(hydroperoxy)(OCH3)(CH3)2 以 甲醇 为溶剂， 生成 (N,N,N',N'-tetramethylethylenediamine)Pt(OH)(OCH3)(CH3)2 、 氧气
  参考文献：
  名称：

  Structural and Mechanistic Investigations of the Oxidation of Dimethylplatinum(II) Complexes by Dioxygen

  摘要：

  The oxidation of (tmeda)Pt-II(CH3)(2) (1, tmeda = N,N,N',N'-tetramethylethylenediamine) to (tmeda)Pt-IV(OH)(OCH3)(CH3)(2) (3) by dioxygen in methanol proceeds via a two-step mechanism. The initial reaction between (tmeda)Pt(CH3)(2) and dioxygen yields a hydroperoxoplatinum(IV) intermediate, (tmeda)Pt(OOH)(OCH3)(CH3)(2) (2), which reacts with a second equivalent of (tmeda)Pt(CH3)(2) to afford the final product 3. Both 2 and 3 have been fully characterized, including X-ray crystallographic structure determinations. The effect of ligand variation on the oxidation of several dimethylplatinum (11) complexes by 2 as well as by dioxygen has been examined.

  DOI：

  10.1021/ic0112903

文献信息

• Oxidation of Dimethylplatinum(II) Complexes with Dioxygen
  作者：Vsevolod V. Rostovtsev、Jay A. Labinger、John E. Bercaw、Tami L. Lasseter、Karen I. Goldberg

  DOI：10.1021/om980541l

  日期：1998.10.1

  Dimethylplatinum(II) complexes (L-L)Pt-(CH3)(2) (L-L = bpy, phen, tmeda) are oxidized by dioxygen in methanol to the corresponding alkoxoplatinum(IV) complexes (L-L)Pt(CH3)(2)(OH)(OCH3).