triethylgallium diethyl ether adduct | 31121-29-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: triethylgallium diethyl ether adduct
• 英文别名: triethylgallium etherate；triethyl gallium ; compound with diethyl ether；Et3Ga*Et2O；Triaethyl-gallium; Verbindung mit Diaethylaether；Triethylgallium-diethyletherat；Ethoxyethane;triethylgallane
• CAS: 31121-29-6
• 化学式: C₄H₁₀O*C₆H₁₅Ga
• 分子量: 231.031
• InChiKey: UIUZVKGHFLUOFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.58
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  triethylgallium diethyl ether adduct 在 HCl 、 H₂O 作用下， 以 水 为溶剂， 生成 二乙基氯化镓
  参考文献：
  名称：

  GALLIUM TRIETHYL MONOETHERATE, GALLIUM TRIETHYL, GALLIUM TRIETHYL AMMINE¹

  摘要：

  DOI：

  10.1021/ja01340a024
• 作为产物：
  描述：

  乙基溴化镁 在 gallium(III) bromide 、 乙醚 作用下， 生成 triethylgallium diethyl ether adduct
  参考文献：
  名称：

  GALLIUM TRIETHYL MONOETHERATE, GALLIUM TRIETHYL, GALLIUM TRIETHYL AMMINE¹

  摘要：

  DOI：

  10.1021/ja01340a024

文献信息

• Synthesis, Structures and Thermal Decomposition of Monomeric Aluminium, Gallium and Indium Silylphosphanides
  作者：Manuel Kapitein、Carsten von Hänisch

  DOI：10.1002/ejic.201402996

  日期：2015.2

  Monomeric N-heterocyclic carbene (NHC)-stabilized compounds (IMes)R2MP(H)SitBuPh2 (2: M = Al, R = Et; 3: M = Ga, R = Et; 4: M = Ga, R = iPr; 5: M = In, R = Et) have been prepared in moderate yields through the cleavage of four-membered metal phosphine rings like [iPr2GaP(H)SitBuPh2]2 (1) described herein. These compounds were isolated and characterized by means of X-ray crystallographic analysis as

  单体 N-杂环卡宾 (NHC)-稳定化合物 (IMes)R2MP(H)SitBuPh2 (2: M = Al, R = Et; 3: M = Ga, R = Et; 4: M = Ga, R = iPr; 5：M = In，R = Et) 通过四元金属膦环的裂解，如本文所述的 [iPr2GaP(H)SitBuPh2]2 (1) 以中等产率制备。这些化合物通过 X 射线晶体学分析和 NMR 光谱进行分离和表征。在此基础上，讨论了结构特性，特别是 M-P 键长和 CNHC-M-P 角，并尽可能与文献已知的化合物进行比较。从磷结合的氢和金属结合的有机取代基之间的顺式设置开始，具有非常低的扭转角，导致几乎共面的排列，描述了热诱导消除反应的结果。
• Diorgano-gallium and -indium complexes with salen ligands: Synthesis, characterization, crystal structure and C–C coupling reactions
  作者：Nisha P. Kushwah、Manoj K. Pal、Amey P. Wadawale、Vimal K. Jain

  DOI：10.1016/j.jorganchem.2009.03.029

  日期：2009.7

  The reactions of triorgano-gallium and -indium etherate with salen ligands in benzene afforded complexes of the type [R2MOC6H4CR'=NCH2-](2), (R/M/R' = Me/Ga/H (1), Et/Ga/H (2), Me/In/H (3), Et/Ga/Me (4)) in nearly quantitative yields. These complexes have been characterized by elemental analysis, IR, UV-Vis, NMR (H-1 and C-13H-1}) and mass spectral data. The organogallium complexes showed photoluminescence in blue-green region. The complex, [(Me2Ga)(2)(O-(C6H4)CH=N-CH2-)(2)] on recrystallization from benzene-hexane and dichloromethane gave orthorhombic and monoclinic forms, respectively. Both the forms are dimeric with gallium atoms acquiring a distorted tetrahedral configuration defined by two methyl groups, phenolate oxygen and azomethene nitrogen. The complexes [(Me2Ga)(2)(O-(C6H4)CH=N-CH2-)(2)] and [(Me2In)(2)(O-(C6H4)CH=N-CH2-)(2)] have been employed as alkylating agent for C-C coupling reaction of 1-bromonaphthalene in presence of PdCl2(PPh3)(2). (C) 2009 Elsevier B.V. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ga: MVol., 40, page 92 - 94
  作者：

  DOI：——

  日期：——
• Synthesis, characterization, photoluminescence and computational studies of mono- and diorgano-gallium complexes containing azo linked salicylaldimine Schiff bases
  作者：Manoj K. Pal、Nisha Kushwah、Amey P. Wadawale、Debashree Manna、V. Sudarsan、Tapan K. Ghanty、Vimal K. Jain

  DOI：10.1016/j.jorganchem.2014.10.024

  日期：2015.1

  The reactions of triorgano-gallium etherate with azo linked salicylaldimine Schiff bases in benzene gave complexes of the type [R2GaOC6H3(N=NPh) (CH=NAr)], [R2GaOC6H3(N=NPh) (CH=NCH2-)](2), [R2GaOC6H3(N=NPh) (CH=NCH2CH2}(3)N] and [C6H5-N=N-C6H3(4'-OGaRO)-3'-CH=N-C6H4] (R = Me or Et; Ar = Ph or tol-4). These complexes have been characterized by elemental analysis, IR, UV-Vis, NMR (H-1 and C-13H-1}) spectroscopy. The molecular structures of [Me2GaOC6H3(N=NPh)CH=NPh].1/2C(6)H(6) (5a.1/2C(6)H(6)) and [Me2GaOC6H3(N=NPh) (CH=Ntol-4)] (5c) were established by X-ray crystallography. Density functional calculations have also been performed to obtain structure and energetic information for the bare ligands and the metal-ligand complexes. Photoluminescence studies of these complexes showed that the quantum yield is always higher than that of the corresponding ligands and the emission peaks of complexes are blue shifted with respect to ligand. (C) 2014 Elsevier B.V. All rights reserved.
• Kushwah, Nisha P; Pal, Manoj K; Wadawale, Amey P, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2011, vol. 50, # 5, p. 674 - 679
  作者：Kushwah, Nisha P、Pal, Manoj K、Wadawale, Amey P、Jain, Vimal K

  DOI：——

  日期：——