1-[4-(1-氧代-哌啶-1-基)-苯基]-乙酮 | 106947-63-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-[4-(1-氧代-哌啶-1-基)-苯基]-乙酮
• 英文名称: 1-[4-(1-Oxidopiperidin-1-ium-1-yl)phenyl]ethanone
• CAS: 106947-63-1
• 化学式: C₁₃H₁₇NO₂
• 分子量: 219.283
• InChiKey: AQFVZSFICXWJOE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  35.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-[4-(1-氧代-哌啶-1-基)-苯基]-乙酮 以 1,4-二氧六环 为溶剂， 反应 6.0h， 以90%的产率得到1-[4-(哌啶-1-氧基)-苯基]-乙酮
  参考文献：
  名称：

  Studies of tertiary amine oxides. 9. Thermal rearrangement of 1-(4-substituted) phenylpiperidine N-oxides to the corresponding N-hydroxylamines

  摘要：

  DOI：

  10.1021/jo00385a012
• 作为产物：
  描述：

  4-哌啶苯乙酮 在 双氧水 作用下， 以 甲酸 为溶剂， 反应 16.0h， 以76%的产率得到1-[4-(1-氧代-哌啶-1-基)-苯基]-乙酮
  参考文献：
  名称：

  Studies of tertiary amine oxides. 9. Thermal rearrangement of 1-(4-substituted) phenylpiperidine N-oxides to the corresponding N-hydroxylamines

  摘要：

  DOI：

  10.1021/jo00385a012

文献信息

• Synthesis and characterization of some olefin/phosphine-tert-amine N-oxide platinum(II) complexes
  作者：Talal A.K. L-Allaf、Abdul-Hussain Khuthier、Hatham J. Abdul-Gani

  DOI：10.1016/s0020-1693(00)84370-4

  日期：1987.10

  Eighteen olefin (or tert-phosphine)-tert-amine N-oxide platinum(II) complexes of the general formula trans-[PtL(tert-amine N-oxide)Cl2] have been prepared, where L is ethylene, styrene, or triethylphosphine. The tert-amine N-oxides used in the complexation were of the N-aryl saturated heterocyclic type substituted at the ortho- or para-position with an electron withdrawal group, i.e. NO2, CN, COCH3

  已经制备了十八种通式为反式-[PtL（叔胺N-氧化物）Cl 2 ]的烯烃（或叔膦）-叔胺N-氧化物铂（II）配合物，其中L为乙烯，苯乙烯，或三乙基膦。用于络合的叔胺N-氧化物是在邻位或对位被电子撤离基团（即NO 2，CN，COCH 3，COC 6 H 5和）取代的N-芳基饱和杂环类型。COOC 2 ħ 5。通过元素分析，IR和1 H NMR光谱对复合物进行表征。
• MECHANOCHROMIC LUMINESCENT DIFLUOROBORON BETA-DIKETONATES
  申请人：Fraser Cassandra L.

  公开号：US20130210053A1

  公开（公告）日：2013-08-15

  The invention provides luminescent solid-state compositions comprising difluoroboron beta-diketonates wherein the compositions can exhibit mechanochromic luminescence. The mechanochromic effect on the luminescence can be reversible, such as thermally reversible. Various solid-state forms of the invention can have emission spectra that differ from the properties of the respective difluoroboron beta-diketonate in solution. The mechanochromic effect can be stimulated by pressure such as hand-writing, and can be reversed over a period of minutes to hours at room temperature. The invention also provides methods of making and methods of using the solid-state compositions, such as for sensors and for information displays for use in biological sensing, and in art, design, and consumer products. Compositions of the invention, such as compositions in nanoparticulate form, or contained within a matrix material, can be used in conjunction with fluorescence microscopy to provide information concerning pressures and tensions within and external to living cells, tissues, or organisms.

  本发明提供了包含二氟硼酮基二酮酸盐的发光固态组合物，其中该组合物可以表现出机械致发光性。该发光的机械致变色效应可以是可逆的，例如热可逆的。本发明的各种固态形式可以具有与相应的二氟硼酮基二酮酸盐在溶液中的性质不同的发射光谱。该机械致变色效应可以通过压力（如手写）刺激，并可以在室温下在几分钟到几小时内被逆转。本发明还提供了制备和使用固态组合物的方法，例如用于生物传感、艺术、设计和消费品的信息显示和传感器。本发明的组合物，例如纳米粒子形式的组合物或包含在基质材料中的组合物，可以与荧光显微镜一起使用，以提供有关细胞、组织或生物体内外压力和张力的信息。
• KHUTHIER, ABDUL-HUSSAIN;AL-MALLAH, KHAWLA Y.;HANNA, S. Y.;ABDULLA, NOOR-A+, J. ORG. CHEM., 52,(1987) N 9, 1710-1713
  作者：KHUTHIER, ABDUL-HUSSAIN、AL-MALLAH, KHAWLA Y.、HANNA, S. Y.、ABDULLA, NOOR-A+

  DOI：——

  日期：——
• US9074129B2
  申请人：——

  公开号：US9074129B2

  公开（公告）日：2015-07-07
• [EN] MECHANOCHROMIC LUMINESCENT DIFLUOROBORON BETA-DIKETONATES<br/>[FR] ?-DICÉTONATES DE DIFLUOROBORE MÉCANOCHROMIQUES LUMINESCENTS
  申请人：FRASER CASSANDRA L

  公开号：WO2011068537A2

  公开（公告）日：2011-06-09

  The invention provides luminescent solid-state compositions comprising difluoroboron beta-diketonates wherein the compositions can exhibit mechanochromic luminescence. The mechanochromic effect on the luminescence can be reversible, such as thermally reversible. Various solid-state forms of the invention can have emission spectra that differ from the properties of the respective difluoroboron beta-diketonate in solution. The mechanochromic effect can be stimulated by pressure such as handwriting, and can be reversed over a period of minutes to hours at room temperature. The invention also provides methods of making and methods of using the solid-state compositions, such as for sensors and for information displays for use in biological sensing, and in art, design, and consumer products. Compositions of the invention, such as compositions in nanoparticulate form, or contained within a matrix material, can be used in conjunction with fluorescence microscopy to provide information concerning pressures and tensions within and external to living cells, tissues, or organisms.