(E)-2,7-二甲基-3-辛烯-5-炔 | 55956-33-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 中文名称: (E)-2,7-二甲基-3-辛烯-5-炔
• 英文名称: (E)-2,7-dimethyl-3-octen-5-yne
• 英文别名: 2,7-dimethyl-oct-3t-en-5-yne；3-Octen-5-yne, 2,7-dimethyl-, (E)-；(E)-2,7-dimethyloct-3-en-5-yne
• CAS: 55956-33-7
• 化学式: C₁₀H₁₆
• 分子量: 136.237
• InChiKey: FGLNIYXXYPEICN-FNORWQNLSA-N

物化性质

• 沸点：
  176.3±9.0 °C(Predicted)
• 密度：
  0.795±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  Diisopropyl-1,3-butadiin 生成 (E)-2,7-二甲基-3-辛烯-5-炔
  参考文献：
  名称：

  A Stereoselective Synthesis of Symmetrically Substitutedtrans-Enynes from Conjugated Diynes

  摘要：

  DOI：

  10.1055/s-1977-24274

文献信息

• Controlling the Catalytic Oligomerization of Terminal Alkynes Promoted by Organoactinides:  A Strategy to Short Oligomers
  作者：Ariel Haskel、Ji Quan Wang、Thomas Straub、Tal Gueta Neyroud、Moris S. Eisen

  DOI：10.1021/ja983640z

  日期：1999.4.1

  presence of terminal alkynes. However, the addition of specific amines ensures the selective synthesis of short oligomers. Catalytic “tailoring” to dimers or a mixture of dimers and trimers can be achieved by using nonbulky or bulky amines, respectively. The kinetics in the catalytic oligomerization of 1-hexyne, in the presence of i-BuNH2, mediated by Cp*2ThMe2 are first order in [alkyne], first order in

  已经开发了一种用于催化合成末端炔烃的短寡聚体、二聚体和/或三聚体的新策略。该方法允许控制由双（五甲基环戊二烯基）锕系二甲基配合物（Cp*2AnMe2；Cp*=C5Me5，An=Th，U）促进的末端炔的催化低聚反应的程度，在某些情况下还可以控制其区域特异性。已知这些茂金属前体在末端炔烃的存在下促进同时产生大量不同尺寸的低聚物。然而，特定胺的添加确保了短寡聚物的选择性合成。通过分别使用非大体积或大体积胺，可以催化“定制”二聚体或二聚体和三聚体的混合物。在 i-BuNH2 存在下，1-己炔催化低聚反应的动力学，由 Cp*2ThMe2 介导的 [炔] 中的一级、[Th] 中的一级和 [胺] 中的反向一级。动力学、光谱和机械数据表明，t ...
• Et2SiH2 assisted the selective dimerization of terminal alkynes catalyzed by Cp*2UMe2
  作者：Ji Quan Wang、Moris S. Eisen

  DOI：10.1016/s0022-328x(02)02136-8

  日期：2003.3

  A practical approach has been developed for the catalytic synthesis of short oligomers, dimers and/or trimers of terminal alkynes. The method allows control of the extent and, in some cases, the regiospecificity in the catalyzed oligornerization of terminal alkynes promoted by bis(pentamethylcyclopentadienyl)uranium dimethyl complex (Cp-2*U(CH3)(2), Cp* = C5Me5). The metallocene precursor is known to promote the simultaneous production of a large number of differently sized oligomers in the presence of terminal alkynes. However, the addition of a specific secondary silane ensures the selective synthesis of short oligomers. (C) 2003 Elsevier Science B.V. All rights reserved.
• A Stereoselective Synthesis of Symmetrically Substituted<i>trans</i>-Enynes from Conjugated Diynes
  作者：George ZWEIFEL、Richard A. LYND、Rex E. MURRAY

  DOI：10.1055/s-1977-24274

  日期：——