4-Cyclohexyl-cyclohex-2-en-1-on | 63539-26-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-Cyclohexyl-cyclohex-2-en-1-on
• 英文别名: 4-Cyclohexylcyclohex-2-en-1-one
• CAS: 63539-26-4
• 化学式: C₁₂H₁₈O
• 分子量: 178.274
• InChiKey: FIDRQIBRBXDGGX-UHFFFAOYSA-N

物化性质

• 沸点：
  286.9±10.0 °C(Predicted)
• 密度：
  1.010±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-Cyclohexyl-cyclohex-2-en-1-on 在 过氧乙酸 、 ruthenium trichloride 作用下， 以 二氯甲烷 、 水 、 乙腈 为溶剂， 以55%的产率得到2,3-Dihydroxy-bicyclohexyl-2-en-4-one
  参考文献：
  名称：

  Oxidation of α,β-unsaturated carbonyl groups with ruthenium (III)-chloride and peracetic acid: a new access to α-oxo-ene-diols

  摘要：

  A one pot oxidation of cyclic unsaturated carbonyl and carboxylic compounds with ruthenium (III)-chloride and peracetic acid to the corresponding alpha-oxo-ene-diols (aci-reductones) has been developed. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)01663-3
• 作为产物：
  描述：

  1-(4-甲氧基苯基)环己醇 在 硫酸 作用下， 生成 4-Cyclohexyl-cyclohex-2-en-1-on
  参考文献：
  名称：

  Humphreys,D.J. et al., Journal of the Chemical Society. Perkin transactions I, 1978, p. 24 - 33

  摘要：

  DOI：

文献信息

• [EN] ETHYLENICALLY UNSATURATED MONOMERS COMPRISING ALIPHATIC AND AROMATIC MOIETIES<br/>[FR] MONOMÈRES À INSATURATION ÉTHYLÉNIQUE COMPRENANT DES FRACTIONS ALIPHATIQUES ET AROMATIQUES
  申请人：DOW GLOBAL TECHNOLOGIES INC

  公开号：WO2009114466A1

  公开（公告）日：2009-09-17

  Polymerizable monomers comprising at least one 1- or 2-propylene moiety and further comprising both aromatic moieties and additional aliphatic moieties and polymerizable mixtures, resins and thermoset products based on these monomers.

  含有至少一个1-或2-丙烯基团的可聚合单体，同时含有芳香基团和额外的脂肪基团，以及基于这些单体的可聚合混合物、树脂和热固性产品。
• Cyclohexene Oxide Compound Having Cyclohexyl Group or Long-Chain Alkyl Group, and Use Thereof
  申请人：Kato Hisao

  公开号：US20080108725A1

  公开（公告）日：2008-05-08

  An object of the present invention is to provide a cyclohexene oxide compound that gives a cured resin having a low refractive index and excellent transparency, curability, mold release properties, and mechanical properties, and that can be used as a component of an actinic radiation curing composition and/or heat curing composition. The present invention is a cyclohexene oxide compound having a cyclohexyl group or a long-chain alkyl group, represented by Formula (1) below (in Formula (1), A denotes a cyclohexyl group, Formula (2) below, or an optionally branched alkyl group having 8 to 16 carbons) (in Formula (2), R 1 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons and R 2 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons).

  本发明的目的是提供一种环己烯氧化物化合物，该化合物能够产生具有低折射率和优异透明度、可固化性、模具脱模性和机械性能的固化树脂，并可用作光敏辐射固化组合物和/或热固化组合物的组分。本发明是一种具有环己基或长链烷基的环己烯氧化物化合物，由下式（1）表示（在式（1）中，A表示环己基、下式（2）或具有8至16个碳的可选支链烷基）（在式（2）中，R1表示氢原子或具有1至4个碳的可选支链烷基，R2表示氢原子或具有1至4个碳的可选支链烷基）。
• METHOD OF MANUFACTURING 4,4"-DIHYDROXY-M-TERPHENYL
  申请人：Honshu Chemical Industry Co., Ltd.

  公开号：US20150158800A1

  公开（公告）日：2015-06-11

  To achieve the object of providing a new method of manufacturing 4,4″-dihydroxy-m-terphenyl, the present invention provides a method of manufacturing 4,4″-dihydroxy-m-terphenyl expressed by General Formula (4) below, characterized in that such method uses a 2-cyclohexene-1-one expressed by General Formula (1) below or 3-hydroxycyclohexane-1-one expressed by General Formula (2) below, and phenol expressed by General Formula (3) below as materials and implements Step (A), Step (B), and Step (C) below, in this order, or Step (D) and Step (C) below, in this order: (In the formulas, each R 2 independently represents an alkyl group, alkoxy group, aromatic hydrocarbon group, or halogen atom, while m independently indicates 0 or an integer of 1 to 4, where R 2 substitution does not occur in the third position when m is 1 or greater, and when m is 2 or greater, R 2 's may be identical or different, and R 2 substitution does not occur in two positions of the same carbon atom. In addition, R 2 and m in General Formula (1) may be identical to or different from R 2 and m in General Formula (2), respectively.) (In the formula, each R 1 independently represents an alkyl group, alkoxy group, aromatic hydrocarbon group, halogen atom, or hydroxyl group, while n indicates 0 or an integer of 1 to 4, where R 1 's may be identical or different when n is 2 or greater.) Step (A): Step to obtain a 1,1,3-trisphenol by causing the 2-cyclohexene-1-one or 3-hydroxycyclohexane-1-one and phenol to react with each other in the presence of a catalyst. Step (B): Step to obtain a bis(4-hydroxyphenyl)cyclohexene by causing the 1,1,3-trisphenol to undergo breakdown reaction. Step (C): Step to obtain a 4,4″-dihydroxy-m-terphenyl by dehydrogenating the bis(4-hydroxyphenyl)cyclohexene. Step (D): Step to obtain a bis(4-hydroxyphenyl)cyclohexene by causing the 2-cyclohexene-1-one or 3-hydroxycyclohexane-1-one and phenol to react with each other in the presence of a catalyst. (In the formula, each R 1 and n is independently the same as the corresponding items in General Formula (3), respectively, while R 2 and m are the same as the corresponding items in General Formula (1) or General Formula (2), respectively.)

  为了提供一种制造4,4″-二羟基-m-联苯的新方法，本发明提供了一种制造4,4″-二羟基-m-联苯的方法，其由下式（4）表示，其特征在于该方法使用下式（1）表示的2-环己烯-1-酮或下式（2）表示的3-羟基环己烷-1-酮以及下式（3）表示的苯酚作为原料，并按照以下顺序实施步骤（A）、（B）和（C），或按照以下顺序实施步骤（D）和（C）：（在公式中，每个R2独立表示烷基、烷氧基、芳香烃基或卤素原子，而m独立表示0或1至4的整数，在m为1或更大时不在第三位置发生R2取代，在m为2或更大时，R2可以相同或不同，并且在同一碳原子的两个位置不发生R2取代。此外，通式（1）中的R2和m可以与通式（2）中的R2和m分别相同或不同。）（在公式中，每个R1独立表示烷基、烷氧基、芳香烃基、卤素原子或羟基，而n表示0或1至4的整数，在n为2或更大时，R1可以相同或不同。）步骤（A）：在催化剂的存在下，使2-环己烯-1-酮或3-羟基环己烷-1-酮和苯酚相互反应以获得1,1,3-三酚。步骤（B）：使1,1,3-三酚发生分解反应以获得双（4-羟基苯基）环己烯。步骤（C）：通过脱氢反应获得4,4″-二羟基-m-联苯。步骤（D）：在催化剂的存在下，使2-环己烯-1-酮或3-羟基环己烷-1-酮和苯酚相互反应以获得双（4-羟基苯基）环己烯。（在公式中，每个R1和n分别独立于相应的通式（3）中的相应项，而R2和m与相应的通式（1）或通式（2）中的相应项相同。）
• CYCLOHEXENE OXIDE COMPOUND HAVING CYCLOHEXYL GROUP OR LONG-CHAIN ALKYL GROUP AND USE THEREOF
  申请人：TOAGOSEI CO., LTD.

  公开号：EP1798251A1

  公开（公告）日：2007-06-20

  An object of the present invention is to provide a cyclohexene oxide compound that gives a cured resin having a low refractive index and excellent transparency, curability, mold release properties, and mechanical properties, and that can be used as a component of an actinic radiation curing composition and/or heat curing composition. The present invention is a cyclohexene oxide compound having a cyclohexyl group or a long-chain alkyl group, represented by Formula (1) below (in Formula (1), A denotes a cyclohexyl group, Formula (2) below, or an optionally branched alkyl group having 8 to 16 carbons) (in Formula (2), R1 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons and R2 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons).

  本发明的目的是提供一种环己烯氧化物化合物，它能使固化树脂具有低折射率和优异的透明度、固化性、脱模性能和机械性能，并可用作光辐射固化组合物和/或热固化组合物的组分。 本发明是一种具有环己基或长链烷基的环己烯氧化物化合物，如下式（1）所示 式（1）中，A 表示下式（2）中的环己基或具有 8 至 16 个碳原子的任选支链烷基）。 式（2）中，R1 表示氢原子或碳原子数为 1 至 4 的任选支链烷基，R2 表示氢原子或碳原子数为 1 至 4 的任选支链烷基）。
• METHOD FOR PRODUCING 4,4''-DIHYDROXY-M-TERPHENYLS
  申请人：Honshu Chemical Industry Co., Ltd.

  公开号：EP2851359B1

  公开（公告）日：2017-03-29