N,N-二甲基苯胺硫酸盐 | 58888-49-6

• 物质功能分类: 有机原料 - 氨基化合物 - 环烷胺、芳香单胺、芳香多胺及其衍生物和盐
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N-二甲基苯胺硫酸盐
• 中文别名: N,N-二甲基苯胺,硫酸盐
• 英文名称: N,N-dimethyl-N-phenylammonium hydrogen sulfate
• 英文别名: N,N-dimethylaniline sulfate；N,N-dimethyl-aniline; hydrogen sulfate；N,N-Dimethyl-anilin; Hydrogensulfat；N,N-Dimethyl-anilin; Sulfat；dimethyl(phenyl)azanium;hydrogen sulfate
• CAS: 58888-49-6
• 化学式: C₈H₁₂N*HO₄S
• 分子量: 219.262
• InChiKey: GVDIQFPDYZBNMO-UHFFFAOYSA-N

物化性质

• 熔点：
  88-89℃

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  86.2
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  N,N-二甲基苯胺硫酸盐 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Willcox, American Chemical Journal, 1904, vol. 32, p. 452

  摘要：

  DOI：
• 作为产物：
  描述：

  甲醇 、 苯胺 在 硫酸 作用下， 反应 2.0h， 生成 N,N-二甲基苯胺硫酸盐 、 苯基三甲基甲硫酸铵
  参考文献：
  名称：

  Shner, V. F.; Nikitenkova, L. P.; Salov, B. V., Journal of Organic Chemistry USSR (English Translation), 1992, vol. 28, # 2.2, p. 350

  摘要：

  DOI：

文献信息

• Synthesis, Structures, and Reactivity of Weakly Coordinating Anions with Delocalized Borate Structure:  The Assessment of Anion Effects in Metallocene Polymerization Catalysts
  作者：Jiamin Zhou、Simon J. Lancaster、Dennis A. Walker、Stefan Beck、Mark Thornton-Pett、Manfred Bochmann

  DOI：10.1021/ja002820h

  日期：2001.1.1

  [CPh(3)][ClB(C(6)F(5))(3)] (2), [NHMe(2)Ph](2)[Ni[CNB(C(6)F(5))(3)](4)].2Me(2)CO (4b.2Me(2)CO), [CPh(3)](2)[Ni[CNB(C(6)F(5))(3)](4)].2CH(2)Cl(2) (4c.2CH(2)Cl(2)), and [CPh(3)](2)[Pd[CNB(C(6)F(5))(3)](4)].2CH(2)Cl(2) (5c.2CH(2)Cl(2)) are reported. The CN stretching frequencies in 4 and 5 are shifted by approximately 110 cm(-1) to higher wavenumbers compared to the parent tetracyano complexes in aqueous solution

  三（五氟苯基）硼烷与强配位阴离子如 CN(-) 和 [M(CN)(4)](2)(-) (M = Ni, Pd) 的加合物的形成是一种合成简便的途径体积大、配位极弱的阴离子 [CN[B(C(6)F(5))(3)](2)](-) 和 [M[CNB(C(6)F(5))(3)] (4)](2-) 分离为稳定的 NHMe(2)Ph(+) 和 CPh(3)(+) 盐。[CPh(3)][CN[B(C(6)F(5))(3)](2)] (1), [CPh(3)][ClB(C(6)F]的晶体结构(5))(3)] (2), [NHMe(2)Ph](2)[Ni[CNB(C(6)F(5))(3)](4)].2Me(2)CO (4b.2Me(2)CO), [CPh(3)](2)[Ni[CNB(C(6)F(5))(3)](4)].2CH(2)Cl(2) (4c.2CH(2)Cl(2)) 和 [CPh(3)](2)[Pd
• Recovery of sulfur dioxide from gas mixtures
  申请人：Asarco Incorporated

  公开号：US03959451A1

  公开（公告）日：1976-05-25

  SO.sub.2 is removed from a SO.sub.2 - containing gas mixture utilizing an aromatic amine as absorbent, followed by scrubbing the SO.sub.2 - depleted, aromatic amine - enriched gas with sulfurous acid solution to remove most of the gaseous aromatic amine therefrom and then with dilute sulfuric acid solution to remove substantially all of the small amount of residual gaseous aromatic amine from the gas. The aqueous scrubbing solutions containing aromatic amine sulfite and aromatic amine sulfate from the respective sulfurous acid and sulfuric acid scrubbing zones are combined and ammonia is added thereto, resulting in release of the aromatic amine and in the formation of ammonium sulfate. Aqueous solution containing the ammonium sulfate is introduced into the upper portion of the sulfurous acid scrubbing section.

  利用芳香胺作为吸收剂，从含SO.sub.2的气体混合物中去除SO.sub.2，然后用含亚硫酸的溶液洗涤SO.sub.2-贫化的芳香胺-富集气体，以去除大部分气态芳香胺，然后用稀硫酸溶液去除气体中残留的极少量气态芳香胺。从分别从亚硫酸和硫酸洗涤区域中得到的含芳香胺亚硫酸盐和芳香胺硫酸盐的水性洗涤溶液被混合，然后加入氨，导致芳香胺的释放并形成硫酸铵。含硫酸铵的水溶液被引入到亚硫酸洗涤部分的上部。
• Photopolymerizable compositions and image-forming materials using said compositions
  申请人：KONICA CORPORATION

  公开号：EP0089802A1

  公开（公告）日：1983-09-28

  A photopolymerizable composition comprises an organic solvent-soluble ethylenic unsaturated compound, an organic sblvent-dispersible, water-insoluble granular dispersion and an organic solvent-soluble photopolymerization initiator, mutually dissolved or dispersed in a solvent composed mainly of an organic solvent. The photopolymerizable composition is developable with water in a short period of time, has high film strength and water resistance of a photosensitive layer, high lipophilic properties and superior film-forming capability, and can be used to produce highly sensitive resists and image-forming materials.

  一种可光聚合的组合物包括一种有机溶剂可溶的乙烯基不饱和化合物、一种有机溶剂可分散的不溶于水的颗粒分散体和一种有机溶剂可溶的光聚合引发剂，它们相互溶解或分散在一种主要由有机溶剂组成的溶剂中。 这种可光聚合的组合物可在短时间内用水显影，具有较高的感光层膜强度和耐水性、较高的亲油性和优异的成膜能力，可用于生产高灵敏度的抗蚀剂和图像形成材料。
• Tetrakis(fluoroaryl) borate/ether complexes and process for preparing the same
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP1400524A1

  公开（公告）日：2004-03-24

  The invention provides a tetrakis(fluoroaryl) borate/ether complex, and the process for preparing the same, The ether complex can be easily purified to a high purity and hence is suitable as an intermediate for the preparation of various tetrakis(fluoroaryl)borate derivatives.

  本发明提供了一种四(氟芳基)硼酸酯/醚络合物及其制备方法，该醚络合物很容易提纯到高纯度，因此适合作为制备各种四(氟芳基)硼酸酯衍生物的中间体。
• Process for preparing tetrakis (fluoroaryl) borate derivatives
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP1400525A1

  公开（公告）日：2004-03-24

  The invention provides a tetrakis(fluoroaryl) borate/ether complex, a process for preparing the same, and a process for preparing a tetrakis(fluoroaryl)borate derivative (Ar4BZ) by using the ether complex and the compound capable of generating monovalent cationic species as starting compounds. The ether complex can be easily purified to a high purity and hence is suitable as an intermediate for the preparation of various tetrakis(fluoroaryl)borate derivatives.

  本发明提供了一种四(氟芳基)硼酸酯/醚络合物、制备该络合物的工艺，以及使用该醚络合物和能够生成一价阳离子物种的化合物作为起始化合物制备四(氟芳基)硼酸酯衍生物(Ar4BZ)的工艺。醚络合物很容易提纯到高纯度，因此适合用作制备各种四（氟芳基）硼酸酯衍生物的中间体。