perylene-3,10-diyldiamine | 252756-17-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: perylene-3,10-diyldiamine
• 英文别名: Perylen-3,10-diyldiamin；3.10-Diamino-perylen；3,10-Diaminoperylen；perylene-3,10-diamine
• CAS: 252756-17-5
• 化学式: C₂₀H₁₄N₂
• 分子量: 282.345
• InChiKey: KDMSENVISSGISJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  perylene-3,10-diyldiamine 在 硝基苯 作用下， 生成 N-[10-(4-chloro-benzoylamino)-perylen-3-yl]-phthalimide
  参考文献：
  名称：

  Funke; Kirchmayr; Wolf, Monatshefte fur Chemie, 1929, vol. 51, p. 226

  摘要：

  DOI：
• 作为产物：
  描述：

  3,10-dinitroperylene 在 苯肼 作用下， 生成 perylene-3,10-diyldiamine
  参考文献：
  名称：

  Funke; Kirchmayr; Wolf, Monatshefte fur Chemie, 1929, vol. 51, p. 226

  摘要：

  DOI：

文献信息

• Compound for organic electroluminescence device and organic electroluminescence device
  申请人：TOYO INK MFG. CO., LTD.

  公开号：EP0965629A1

  公开（公告）日：1999-12-22

  A compound suitable for use in an organic electroluminescence device, having the formula [1],    wherein each of Ar3 to Ar10 are the same or different and represent a substituted or non-substituted aromatic monocyclic group, a substituted or non-substituted fused polycyclic group or a substituted or non-substituted aromatic heterocyclic group, or Ar3 and Ar4 and/or Ar5 and Ar6 and/or Ar7 and Ar8 and/or Ar9 and Ar10, together with the nitrogen atom to which they are attached, together form a fused or non-fused, aromatic or non-aromatic heterocyclic ring.

  一种适用于有机电致发光器件的化合物，具有式[1]、 其中 Ar3 至 Ar10 各自相同或不同，代表取代或非取代的芳香族单环基团、取代或非取代的融合多环基团或取代或非取代的芳香族杂环基团，或 Ar3 和 Ar4 和/或 Ar5 和 Ar6 和/或 Ar7 和 Ar8 和/或 Ar9 和 Ar10 与它们所连接的氮原子一起形成一个融合或非融合的芳香族或非芳香族杂环。
• NOVEL BRANCHED OLIGOARYLSILANES AND METHOD FOR PRODUCING SAME
  申请人："Luminescent Innovation Technologies" Limited Liability Company

  公开号：EP3006486A1

  公开（公告）日：2016-04-13

  Novel branched oligoarylsilanes and a method of their preparation are claimed. Novel branched oligoarylsilanes of general formula (I) where R stands for a substituent from the row: linear or branched C1-C20 alkyl groups; linear or branched C1-C20 alkyl groups, separated by at least one oxygen atom; linear or branched C1-C20 alkyl groups, separated by at least one sulfur atom; branched C3-C20 alkyl groups, separated by at least one silicon atom; C2-C20 alkenyl groups; Ar stands for identical or different arylene or hetetoarylene radicals, selected from the row: substituted or unsubstituted thienyl-2,5-diyl, substituted or unsubstituted phenyl-1,4-diyl, substituted or unsubstituted 1,3-oxazole-2,5-diyl, substituted fluorene-4,4'-diyl, substituted cyclopentadithiophene-2,7-diyl; Q stands for a radical from the row described above for Ar; X stands for at least one radical, selected from the row described above for Ar and/or a radical from the row: 2,1,3-benzothiodiazole-4,7-diyl, antracene-9,10-diyl, 1,3,4-oxadiazole-2,5-diyl, 1-phenyl-2-pyrazolene-3,5-diyl, perylene-3,10-diyl where n stands for an integer from the row from 2 to 4; m stands for an integer from the row from 1 to 3; k stands for an integer from the row from 1 to 3. A method of preparation of branched oligoarylsilanes is that a compound of general formula (III) where Y stands for a residue of boronic acid or its ester or Br or I, reacts under Suzuki conditions with a reagent of general formula (IV) A - Xm - A (IV), where A stands for: Br or I, provided that Y stands for a residue of boronic acid or its ester; or a residue of boronic acid or its ester, provided that Y stands for Br or I. A technical result is preparation of novel compounds, featured by a high luminescence efficiency, efficient intramolecular energy transfer from some molecular fragments to others, and an increased thermal stability.

  本发明要求获得新型支链低聚芳基硅烷及其制备方法。通式为(I)的新型支链低聚芳基硅烷 其中 R 代表来自以下一行的取代基：直链或支链 C1-C20 烷基；直链或支链 C1-C20 烷基，至少被一个氧原子隔开；直链或支链 C1-C20 烷基，至少被一个硫原子隔开；支链 C3-C20 烷基，至少被一个硅原子隔开；C2-C20 烯基；Ar 代表来自以下一行的相同或不同的芳基或四芳基：取代或未取代的噻吩基-2,5-二基；取代或未取代的噻吩基-2,5-二基；取代或未取代的噻吩基-2,5-二基；取代或未取代的噻吩基-2,5-二基；取代或未取代的噻吩基-2,5-二基：取代或未取代的噻吩-2,5-二基、取代或未取代的苯基-1,4-二基、取代或未取代的 1,3-恶唑-2,5-二基、取代的芴-4,4'-二基、取代的环戊二烯噻吩-2,7-二基；Q 代表上述 Ar 一列中的一个基团；X 代表至少一个基团，选自上述 Ar 一列和/或上述 Ar 一列中的一个基团：2,1,3-苯并噻二唑-4,7-二基、蒽-9,10-二基、1,3,4-恶二唑-2,5-二基、1-苯基-2-吡唑啉-3,5-二基、亚珀-3,10-二基 其中 n 代表 2 至 4 行的整数；m 代表 1 至 3 行的整数；k 代表 1 至 3 行的整数。一种制备支链低聚芳基硅烷的方法是将通式(III)的化合物 其中 Y 代表硼酸或其酯或 Br 或 I 的残余物，在铃木条件下与通式 (IV) A - Xm - A (IV) 的试剂反应，其中 A 代表：技术成果是制备出了新型化合物，其特点是发光效率高、分子内能量从一些分子片段高效转移到另一些分子片段，而且热稳定性更高。
• Untersuchungen �ber Perylen und seine Derivate
  作者：Konrad Funke

  DOI：10.1007/bf01518467

  日期：1933.2
• Funke; Wolf, Monatshefte fur Chemie, 1929, vol. 52, p. 3
  作者：Funke、Wolf

  DOI：——

  日期：——
• HETEROCYCLIC COMPOUND, ORGANIC LIGHT-EMITTING DIODE INCLUDING THE HETEROCYCLIC COMPOUND, AND FLAT DISPLAY DEVICE INCLUDING THE ORGANIC LIGHT-EMITTING DIODE
  申请人：Jung Hye-Jin

  公开号：US20130099206A1

  公开（公告）日：2013-04-25

  A heterocyclic compound represented by Formula 1 below, and an organic light-emitting diode including the heterocyclic compound, and a flat display device including the organic light-emitting diode. wherein Ar 1 to Ar 4 , X 1 , X 2 , Y 1 , Y 2 , L 1 , and m are defined as in the specification.