十八碳-17-烯酸 | 19307-16-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 十八碳-17-烯酸
• 英文名称: octadec-17-enoic acid
• 英文别名: Octadec-17-ensaeure；Heptadecen-(16)-carbonsaeure；Δ¹⁷-Octadecensaeure；Octadec-17-encarbonsaeure；17-Octadecensaeure；17-Octadecenoic acid
• CAS: 19307-16-5
• 化学式: C₁₈H₃₄O₂
• 分子量: 282.467
• InChiKey: CYSXFFUIJWHWRH-UHFFFAOYSA-N

物化性质

• 熔点：
  25.01°C (estimate)
• 沸点：
  397.91°C (estimate)
• 密度：
  0.8945 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  20
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-O-(3,4-isopropylidene-β-D-galactopyranosyl)-2,3:5,6-bis-O-isopropylidene-D-glucose dimethyl acetal 、 十八碳-17-烯酸 以 水 、 甲苯 为溶剂， 反应 6.0h， 生成
  参考文献：
  名称：

  Chemo‐enzymatic synthesis of disaccharide fatty acid esters

  摘要：

  摘要 以固定化 Mucor miehei 脂肪酶（Lipozyme IM-60; Novo Nordisk, Bagsvaerd, Denmark）为催化剂，开发了一种合成二糖脂肪酸酯的新型酶法。从相应的糖缩醛和脂肪酸中制备出一系列乳糖和麦芽糖单酯，总产率为 48-77%。

  DOI：

  10.1007/bf02541426
• 作为产物：
  描述：

  7-羟基庚酸乙酯 在 sodium hydroxide 作用下， 生成 十八碳-17-烯酸
  参考文献：
  名称：

  Hydrogenation of oriented monolayers of .omega.-unsaturated fatty acids supported on platinum

  摘要：

  DOI：

  10.1021/ja00489a011

文献信息

• Methods and Systems for Making Thiol Compounds from Terminal Olefinic Compounds
  申请人：Upshaw Thomas A.

  公开号：US20090264669A1

  公开（公告）日：2009-10-22

  The application discloses thiol ester molecules and α-hydroxy thiol ester molecules having a thiol group located on one of the final two carbon atoms in a carbon chain or a terminal or α-hydroxyl groups, respectively. The disclosed thiol ester molecules and or α-hydroxyl thiol ester molecules es may be made from unsaturated ester molecules having one or more terminal alkene groups. The disclosed techniques also provide methods for making unsaturated ester molecules having one or more terminal alkene groups by the metathesis of unsaturated esters having one or more internal carbon-carbon double bonds (e.g. natural source oils). The thiol ester molecules or α-hydroxy thiol ester molecule may be used in reactions with isocyanate monomers, epoxide monomer, or material having multiple alkene groups to make sealants, coatings, adhesives, and other products.

  本发明揭示了具有巴豆醇基位于碳链的最后两个碳原子之一或具有末端或α-羟基的巴豆醇酯分子和α-羟基巴豆醇酯分子。所述的巴豆醇酯分子或α-羟基巴豆醇酯分子可以由具有一个或多个末端烯烃基团的不饱和酯分子制备而成。本发明还提供了通过不饱和酯类之间的交换反应（例如天然源油）制备具有一个或多个末端烯烃基团的不饱和酯分子的方法。巴豆醇酯分子或α-羟基巴豆醇酯分子可以与异氰酸酯单体，环氧单体或具有多个烯烃基团的材料反应，制备密封剂，涂料，粘合剂和其他产品。
• Water-based fluorine-containing paint
  申请人：CENTRAL GLASS COMPANY, LIMITED

  公开号：EP0743347A2

  公开（公告）日：1996-11-20

  The invention provides a first water-based fluorine-containing paint including a water-based emulsion containing a fluorine-containing copolymer dispersed therein, and 1-50 parts by weight of a hardener per 100 parts by weight of the copolymer. The copolymer is prepared by copolymerizing 30-65 mol% of a fluoroolefin, 14-69 mol% of a copolymerizable vinyl-containing compound, and 1-30 mol % of a hydroxyl-containing compound and/or a polymerizable carboxyl-containing compound. The hardener is prepared by mixing 1 part by weight of a self-emulsifiable polyisocyanate with 0.01-1 part by weight of a compound containing in the molecule an oxyethylene unit and an alkoxysilyl group. When mixed with the emulsion, the hardener becomes well dispersed therein. The invention further provides a second water-based fluorine-containing paint including a water-based emulsion containing a fluorine-containing copolymer dispersed therein, and a hardener which is a compound containing in the molecule at least two hydrazino groups. The fluorine-containing copolymer is prepared by emulsion polymerization of 30-65 mol% of a fluoroolefin, 0.1-20 mol% of a polymerizable unsaturated carboxylic acid, 1-30 mol% of a polymerizable acetoacetylallyl compound, and 20-65 mol% of one of a vinyl ester and a vinyl ether. The second paint does not cure at ambient temperature, even after the hardener has been added thereto, and thus is usable as a one-package paint.

  本发明提供了第一种水基含氟涂料，包括含有分散在其中的含氟共聚物的水基乳液，以及每 100 重量份共聚物中含 1-50 重量份固化剂。共聚物是由 30-65 摩尔%的含氟烯烃、14-69 摩尔%的可共聚的含乙烯基化合物和 1-30 摩尔%的含羟基化合物和/或可聚合的含羧基化合物共聚而成。硬化剂的制备方法是将 1 份（重量）可自乳化的多异氰酸酯与 0.01-1 份（重量）分子中含有氧 乙烯单元和烷氧基硅基的化合物混合。当与乳液混合时，固化剂会在其中充分分散。本发明进一步提供了第二种水性含氟涂料，包括一种分散有含氟共聚物的水性乳液和一种固化剂，固化剂是一种分子中至少含有两个肼基的化合物。含氟共聚物是由 30-65 摩尔%的氟烯烃、0.1-20 摩尔%的可聚合不饱和羧酸、1-30 摩尔%的可聚合乙酰乙酰烯丙基化合物和 20-65 摩尔%的乙烯基酯和乙烯基醚中的一种进行乳液聚合制备而成。第二种涂料即使在加入固化剂后，也不会在环境温度下固化，因此可用作单组分涂料。
• Water-based fluorine-containing plant
  申请人：CENTRAL GLASS COMPANY, LIMITED

  公开号：EP1123943A1

  公开（公告）日：2001-08-16

  The invention provides a water-based fluorine-containing paint including a water-based emulsion containing a fluorine-containing copolymer dispersed therein, and a hardener which is a compound containing in the molecule at least two hydrazino groups. The fluorine-containing copolymer is prepared by emulsion polymerization of 30-65 mol% of a fluoroolefin, 0,1-20 mol% of a polymerizable unsaturated carboxylic acid, 1-30 mol% of a polymerizable acetoacetylallyl compound, and 20-65 mol% of one of a vinyl ester and a vinyl ether. The paint does not cure at ambient temperature, even after the hardener has been added thereto, and thus is usable as a one-package paint.

  本发明提供了一种水基含氟涂料，包括一种含有分散在其中的含氟共聚物的水基乳液和一种固化剂，固化剂是一种在分子中至少含有两个肼基的化合物。含氟共聚物是由 30-65 摩尔%的氟烯烃、0.1-20 摩尔%的可聚合不饱和羧酸、1-30 摩尔%的可聚合乙酰乙酰烯丙基化合物和 20-65 摩尔%的乙烯基酯和乙烯基醚中的一种进行乳液聚合制备而成。这种涂料即使在加入固化剂后，也不会在环境温度下固化，因此可用作单组分涂料。
• Process for producing a copolymer of a non-polar olefin and a polar olefin and the copolymer obtained thereby
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1170308A2

  公开（公告）日：2002-01-09

  A process for producing a polar olefin copolymer comprises copolymerizing a non-polar olefin and a polar olefin in the presence of a transition metal compound selected from Groups 4, 5, 6 and 11 of the periodic table, which is represented by the following formula (IV): wherein M' is a transition metal atom selected from Groups 4, 5, 6 and 11 of the periodic table, m is an integer of 1 to 6, A is -O-, -Si-, -Se-, -N(R6)-, n is a number satisfying a valence of M', R1 to R4 and R6 are each a hydrogen atom, a halogen atom, a hydrocarbon group and the like, and X is a halogen atom, an oxygen atom, a hydrocarbon group and the like, and at least one compound (B) selected from the group consisting of an organometallic compound (B-1), an organoaluminum oxy-compound (B-2) and an ionic ionizing compound (B-3). Therefore, the process is capable of obtaining a polar olefin copolymer having excellent properties under mild polymerization conditions.

  一种生产极性烯烃共聚物的工艺，包括在选自元素周期表第 4、5、6 和 11 族的过渡金属化合物存在下，使非极性烯烃和极性烯烃共聚，该过渡金属化合物由下式(IV)表示： 其中 M' 是选自元素周期表第 4、5、6 和 11 族的过渡金属原子，m 是 1 至 6 的整数，A 是-O-、-Si-、-Se-、-N(R6)-，n 是满足 M' 的价数，R1 至 R4 和 R6 各为氢原子、卤素原子、烃基等、X 是卤素原子、氧原子、烃基等，以及至少一种选自有机金属化合物（B-1）、有机铝氧 化物（B-2）和离子电离化合物（B-3）的化合物（B）。因此，该工艺能够在温和的聚合条件下获得性能优异的极性烯烃共聚物。
• TRIPHENYLBORON-CONTAINING POLYMERS AND USE THEREOF
  申请人：Yoshitomi Fine Chemicals, Ltd.

  公开号：EP1227111A1

  公开（公告）日：2002-07-31

  A polymer containing a triphenylboron-containing constituting unit of the formula [I]: wherein each symbol is as defined in the specification, shows a superior adhesion-preventive effect against aquatic fouling organisms, such as coelenterates, shellfish, tubicolous polychaetes and the like, for a long time, shows a function of not only an active ingredient but also a binder, the polymer characteristically shows fine miscibility with other coating resins and a less adverse influence on the environment. Therefore, it can be used as a superior preventive of fouling due to the adhesion of aquatic fouling organisms.

  一种含有式[I]的含三苯基硼构成单元的聚合物： 其中各符号如本说明书所定义，对水生污损生物（如腔肠动物、贝类、管状多毛类动物等）具有卓越的长期防污效果，不仅具有活性成分的功能，还具有粘合剂的功能，该聚合物与其他涂层树脂具有良好的混溶性，对环境的不利影响较小。因此，它可用作防止水生污损生物附着造成污损的优质防污剂。