| 157103-00-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• CAS: 157103-00-9
• 化学式: C₁₂H₁₀F₁₃NO₃
• 分子量: 463.196
• InChiKey: DOTAPLPPYWKGRE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  29.0
• 可旋转键数：
  10.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  66.4
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  在 sodium acetate 、 乙酸酐 作用下， 反应 2.0h， 以60%的产率得到
  参考文献：
  名称：

  Synthesis of graft copolymers of polyethylene: grafting of fluorinated model compound oligomers

  摘要：

  The condensation reaction of perfluorinated amines on to (succinic anhydride)-HDPE (high-density polyethylene) graft copolymer have been studied. Four different amine structures have been synthesized which have been analyzed by H-1 NMR spectroscopy GC-MS methods. Model structures of succinimide and succinamic acid have been synthesized with each amine and analyzed by FT-IR spectroscopy in order to determine the structure of the copolymer obtained. A scale of reactivity has been deduced as a function of the amine structure. Grafting levels of copolymer have been determined by elemental analysis of fluorine.

  DOI：

  10.1016/0022-1139(93)03043-l
• 作为产物：
  描述：

  8-azido-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorooctane 在 ammonium hydroxide 、 三苯基膦 作用下， 以 氯仿 为溶剂， 反应 2.0h， 生成
  参考文献：
  名称：

  Synthesis of graft copolymers of polyethylene: grafting of fluorinated model compound oligomers

  摘要：

  The condensation reaction of perfluorinated amines on to (succinic anhydride)-HDPE (high-density polyethylene) graft copolymer have been studied. Four different amine structures have been synthesized which have been analyzed by H-1 NMR spectroscopy GC-MS methods. Model structures of succinimide and succinamic acid have been synthesized with each amine and analyzed by FT-IR spectroscopy in order to determine the structure of the copolymer obtained. A scale of reactivity has been deduced as a function of the amine structure. Grafting levels of copolymer have been determined by elemental analysis of fluorine.

  DOI：

  10.1016/0022-1139(93)03043-l