2-(2,5-二甲基-苯基)-喹啉 | 76890-09-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 中文名称: 2-(2,5-二甲基-苯基)-喹啉
• 英文名称: 2-(2,5-dimethylphenyl)quinoline
• 英文别名: 2-(2,5-dimethylphenyl)quinolone；2-(2,5-dimethyl-phenyl)-quinoline；2-(2,5-Dimethyl-phenyl)-chinolin
• CAS: 76890-09-0
• 化学式: C₁₇H₁₅N
• mdl: MFCD00819570
• 分子量: 233.313
• InChiKey: XLKRTIKIQUGWGJ-UHFFFAOYSA-N

物化性质

• 熔点：
  143 °C
• 沸点：
  199-222 °C(Press: 6 Torr)
• 密度：
  1.087±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(2,5-Dimethyl-phenyl)-1,2-dihydro-quinoline 、 2-(2,5-二甲基-苯基)-喹啉 生成 7-Methyl-10H-indeno<1,2-b>quinoline
  参考文献：
  名称：

  PROSTAKOV N. S.; PLESHAKOV V. G.; ZAJNUL ABEDIN MD.; ZVOLINSKIJ V. P.; ZA+, ZH. ORGAN. XIMII, 1980, 16, HO 11, 2451-2452

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(2,5-二甲基苯基)喹啉-4-羧酸 生成 2-(2,5-二甲基-苯基)-喹啉
  参考文献：
  名称：

  The Pfitzinger Reaction in the Synthesis of Quinoline Derivatives

  摘要：

  DOI：

  10.1021/jo50015a019

文献信息

• A nanoscale iron catalyst for heterogeneous direct <i>N</i>- and <i>C</i>-alkylations of anilines and ketones using alcohols under hydrogen autotransfer conditions
  作者：Madhu Nallagangula、Chandragiri Sujatha、Venugopal T. Bhat、Kayambu Namitharan

  DOI：10.1039/c9cc04120f

  日期：——

  report a commercially available nanoscale Fe catalyst for heterogeneous direct N- and C-alkylation reactions of anilines and methyl ketones with alcohols. A hydrogen autotransfer mechanism has been found to operate in these reactions by deuterium labelling studies. In addition, dehydrogenative quinoline synthesis has been demonstrated from amino benzyl alcohols and acetophenones.

  在这里，我们报告了一种可商购的纳米级Fe催化剂，用于苯胺和甲基酮与醇的异质直接N-和C-烷基化反应。通过氘标记研究，发现氢自动转移机制在这些反应中起作用。另外，已经证明从氨基苄醇和苯乙酮合成脱氢喹啉。
• Pyridine mediated transition-metal-free direct alkylation of anilines using alcohols <i>via</i> borrowing hydrogen conditions
  作者：Rajagopal Pothikumar、Venugopal T Bhat、Kayambu Namitharan

  DOI：10.1039/d0cc05912a

  日期：——

  azaaromatics as efficient biomimetic hydrogen shuttles for a transition-metal-free direct N-alkylation of aryl and heteroaryl amines using a variety of benzylic and straight chain alcohols. Mechanistic studies including deuterium labeling and the isolation of dihydro-intermediates of the benzannulated pyridine confirmed the role of pyridine and a borrowing hydrogen process operating in these reactions

  在这里，我们报道吡啶和其他类似的氮杂芳香族化合物作为有效的仿生氢穿梭，可使用多种苄基和直链醇对芳基和杂芳基胺进行无过渡金属的直接N-烷基化。包括氘标记和苯甲酰吡啶的二氢中间体的分离在内的机理研究证实了吡啶的作用以及在这些反应中进行的借入氢过程。此外，我们已经将这种方法扩展到开发喹啉和吲哚的脱氢合成以及酮的转移加氢。
• PRODUCING METHOD FOR IRIDIUM COMPLEX
  申请人：Kamatani Jun

  公开号：US20070232803A1

  公开（公告）日：2007-10-04

  The invention provides a method for producing an iridium complex with a high yield at a low temperature, and an organic electroluminescence device (organic EL device) having an light output high in efficiency and high luminance in a range from blue to red region. An iridium complex for the organic EL device is produced from an iridium complex having a 4-membered ring structure as an auxiliary ligand. The organic EL device is composed of at least a pair of electrodes serving as an anode and a cathode, and an organic compound layer interposed between the electrodes, and the organic compound layer contains an iridium complex represented by a following structure:

  本发明提供了一种在低温下高产率制备铱配合物的方法，以及具有从蓝色到红色区域高效率和高亮度的光输出的有机电致发光装置（有机EL装置）。该有机EL装置的铱配合物是由具有4元环结构的铱配合物作为辅助配体制备而成。该有机EL装置由至少一对作为阳极和阴极的电极和介于电极之间的有机化合物层组成，其中有机化合物层含有下述结构的铱配合物：
• Prostakov, N. S.; Pleshakov, V. G.; Abedin, Md. Zainul, Journal of Organic Chemistry USSR (English Translation), 1982, vol. 18, p. 556 - 566
  作者：Prostakov, N. S.、Pleshakov, V. G.、Abedin, Md. Zainul、Kordova, I. R.、Zakharov, V. F.、Zvolinskii, V. P.

  DOI：——

  日期：——
• ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
  申请人：ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.

  公开号：US20200207712A1

  公开（公告）日：2020-07-02

  The present disclosure relates to an organic electroluminescent compound and an organic electroluminescent device comprising the same. The organic electroluminescent device having a low driving voltage and/or a high luminous efficiency and/or a long lifespan can be provided, by comprising an organic electroluminescent compound according to the present disclosure.