1H,1H,2H,2H,3H,3H-全氟-1-十一醇 | 25600-66-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1H,1H,2H,2H,3H,3H-全氟-1-十一醇
• 英文名称: 1H,1H,2H,2H,3H,3H-pentadecafluoro-decan-1-ol
• 英文别名: 4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Pentadecafluor-decylalkohol；1H,1H,2H,2H,3H,3H-Pentadecafluordecanol；4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Pentadecafluorodecan-1-ol
• CAS: 25600-66-2
• 化学式: C₁₀H₇F₁₅O
• 分子量: 428.141
• InChiKey: LWCLGUDCFDTQBF-UHFFFAOYSA-N

物化性质

• 熔点：
  28-29
• 沸点：
  106-107/9mm
• 密度：
  1.567±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  16

安全信息

• 危险品标志：
  Xi
• 海关编码：
  2905590090

反应信息

• 作为产物：
  描述：

  E-3-F-庚基-2-丙烯腈 在 palladium on activated charcoal lithium aluminium tetrahydride 、 硫酸 、 氢气 作用下， 以 乙醚 、 乙醇 为溶剂， 反应 46.0h， 生成 1H,1H,2H,2H,3H,3H-全氟-1-十一醇
  参考文献：
  名称：

  Coe,P.L. et al., Journal of the Chemical Society. Perkin transactions I, 1975, p. 654 - 656

  摘要：

  DOI：

文献信息

• METHOD FOR PREPARING FLUORINATED BENZOTRIAZOLE COMPOUNDS
  申请人：BOARDMAN Larry D.

  公开号：US20080114177A1

  公开（公告）日：2008-05-15

  Fluorinated benzotriazole compounds may be prepared by contacting a fluorochemical monofunctional compound, such a fluorinated alcohol, with a carboxybenzotriazole in the presence of a coupling agent, and an optional amine catalyst.

  氟化苯并三唑化合物可以通过将氟化单官能化合物（如氟化醇）与羧基苯并三唑在偶联剂和可选的胺催化剂的存在下接触而制备。
• [EN] FLUORINATED AROMATIC BIS(ACYL)-CONTAINING COMPOUNDS AND POLYESTERS PREPARED THEREFROM<br/>[FR] COMPOSÉS CONTENANT UN BIS(ACYLE) AROMATIQUES FLUORÉS ET POLYESTERS PRÉPARÉS À PARTIR DE CEUX-CI
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2011005396A1

  公开（公告）日：2011-01-13

  A fluorinated bis(acyl)-containing compound of Formula (I), where R1, Ar, L, R2, R3, Rf, n, p and q are as defined in the claims, and a fluorinated polyester formed from the fluorinated bis(acyl) compound are described. More particularly, the fluorinated bis(acyl) has an aromatic ring bonded to two acyl groups plus at least one third group that contains a perfluoroalkylsulfonamido group. The fluorinated polyesters formed from the fluorinated bis(acyl)-containing compound can be used to provide a low energy surface with a relatively low refractive index compared to many other polyesters. A method of preparing a monosubstituted-arylene compound of formula Rf1-L2 -CH2-Ar2-CH2-W, where Ar2, Rf1, L2, R6 and W are as defined in the claims by reaction of a compound of formula Rf1-L2-H with a compound of formula W-CH2-Ar2-CH2-W.

  描述了一种含有Fluorinated bis(acyl)化合物的化合物Formula (I)，其中R1、Ar、L、R2、R3、Rf、n、p和q如索赔中所定义，并且由Fluorinated bis(acyl)化合物形成的氟化聚酯。更具体地说，Fluorinated bis(acyl)具有与两个酰基结合的芳香环，再加上至少一个含有全氟烷基磺酰胺基团的第三基团。由含有Fluorinated bis(acyl)化合物形成的氟化聚酯可用于提供低能量表面，其折射率相对于许多其他聚酯来说相对较低。通过将Formula Rf1-L2-CH2-Ar2-CH2-W的单取代芳基化合物制备方法，其中Ar2、Rf1、L2、R6和W如索赔中所定义，通过化合物Rf1-L2-H与化合物W-CH2-Ar2-CH2-W的反应。
• FLUORINATED ETHER URETHANES AND METHODS OF USING THE SAME
  申请人：Dams Rudolf J.

  公开号：US20110232530A1

  公开（公告）日：2011-09-29

  Compounds comprising end groups represented by formula (Rf-Q) a -X-(A-) b and compounds comprising the reaction product of components comprising a multifunctional isocyanate compound and a fluorinated compound represented by formula (Rf-Q) a -X—(Z) b . Each Rf is independently a partially fluorinated or fully fluorinated group selected from Rf A (O) 2 CHL′-(CF 2 ) n —; [Rf B —(O) 1 —C(L)H—CF 2 —O] m —W—; CF 3 CFH—O—(CF 2 ) p —; CF 3 —(O—CF 2 )Z—; and CF 3 —O—(CF 2 ) 3 —O—CF—. Methods of making an article having a surface using the fluorinated compounds and treated articles are also disclosed.

  本文描述了由式(Rf-Q)a-X-(A-)b表示的末端基团组成的化合物以及由多功能异氰酸酯化合物和式(Rf-Q)a-X—(Z)b表示的氟化合物反应产物组成的化合物。其中，每个Rf都是独立的部分氟化或完全氟化的基团，选自RfA(O)2CHL′-(CF2)n—; [RfB—(O)1—C(L)H—CF2—O]m—W—; CF3CFH—O—(CF2)p—; CF3—(O—CF2)Z—; 和 CF3—O—(CF2)3—O—CF—。还公开了使用这些氟化合物制备具有表面的物品的方法和处理过的物品。
• Urethane-based stain-release coatings
  申请人：——

  公开号：US20030105263A1

  公开（公告）日：2003-06-05

  This invention relates to chemical compositions comprising one or more urethane oligomers of at least two repeating units selected from the group consisting of fluorine-containing urethane oligomers and long-chain hydrocarbon-containing urethane oligomers. These urethane oligomers comprise the reaction product of (a) one or more polyfunctional isocyanate compounds; (b) one or more polyols; (c) one or more monoalcohols selected from the group consisting of fluorochemical monoalcohols, optionally substituted long-chain hydrocarbon monoalcohols, and mixtures thereof; (d) one or more silanes; and optionally (e) one or more water-solubilizing compounds comprising one or more water-solubilizing groups and at least one isocyanate-reactive hydrogen containing group. The chemical compositions of the present invention can be applied as coatings and these coatings can impart stain-release characteristics and resist being worn-off due to wear and abrasion.

  本发明涉及一种化学组合物，包括至少两个重复单元选自含氟尿素低聚物和长链烃基尿素低聚物的尿素低聚物。这些尿素低聚物包括以下反应产物：（a）一种或多种多官能异氰酸酯化合物；（b）一种或多种多元醇；（c）一种或多种单醇，选自含氟化合物单醇，可选取取代的长链烃基单醇和它们的混合物；（d）一种或多种硅烷；以及可选的（e）一种或多种水溶化化合物，包括一种或多种水溶化基团和至少一个异氰酸酯反应性氢含有基团。本发明的化学组合物可用作涂层，这些涂层可以赋予防污特性并抵抗由磨损和磨蚀引起的磨损。
• PARTICLES COMPRISING A FLUORINATED SILOXANE AND METHODS OF MAKING AND USING THE SAME
  申请人：Fan Wayne W.

  公开号：US20100018706A1

  公开（公告）日：2010-01-28

  Particles, including proppants, comprising a fluorinated siloxane. The particles are useful as proppants in fractured a subterranean geological formation comprising hydrocarbons.

  包括支撑剂在内的颗粒物，包含一种氟硅氧烷。这些颗粒物在包含碳氢化合物的地下岩石裂缝地层中作为支撑剂很有用。