(2-甲基-[3]喹啉基)-苯基-胺 | 103161-52-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 中文名称: (2-甲基-[3]喹啉基)-苯基-胺
• 英文名称: (2-methyl-[3]quinolyl)-phenyl-amine
• 英文别名: (2-Methyl-[3]chinolyl)-phenyl-amin；2-methyl-N-phenylquinolin-3-amine
• CAS: 103161-52-0
• 化学式: C₁₆H₁₄N₂
• 分子量: 234.301
• InChiKey: VIAIPHLQMZNAJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  24.9
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2-甲基-[3]喹啉基)-苯基-胺 在 1,4-二氧六环 、 selenium(IV) oxide 、 水 作用下， 生成 3-anilino-quinoline-2-carbaldehyde
  参考文献：
  名称：

  融合杂环第二部分。喹啉-(2:3:3':2')-喹啉的合成：花萼的异构体

  摘要：

  讨论了生物碱花萼脱氢产物花萼的构成。制备了花椰菜二苦酸，并根据其分析和花椰菜的红外光谱，提出了花椰菜的喹啉喹啉结构。描述了喹啉-(2:3:3':2')-喹啉的合成。

  DOI：

  10.1139/v58-214
• 作为产物：
  描述：

  3-anilino-2-methyl-quinoline-4-carboxylic acid 生成 (2-甲基-[3]喹啉基)-苯基-胺
  参考文献：
  名称：

  融合杂环第二部分。喹啉-(2:3:3':2')-喹啉的合成：花萼的异构体

  摘要：

  讨论了生物碱花萼脱氢产物花萼的构成。制备了花椰菜二苦酸，并根据其分析和花椰菜的红外光谱，提出了花椰菜的喹啉喹啉结构。描述了喹啉-(2:3:3':2')-喹啉的合成。

  DOI：

  10.1139/v58-214

文献信息

• Oxo-nitrogenated vanadium complex, catalytic system comprising said oxo-nitrogenated vanadium complex and process for (co)polymerising conjugated dienes
  申请人：VERSALIS S.p.A.

  公开号：US10301408B2

  公开（公告）日：2019-05-28

  An oxo-nitrogenated vanadium complex having the general formula (I): in which: —R1, R2, R3, R4, R5, R6 and R7, mutually identical or different, represent a hydrogen atom; or are selected from optionally halogenated, linear or branched C1-C20, preferably C1-C15, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; —X1 and X2, mutually identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or are selected from linear or branched C1-C20, preferably C1-C15, alkyl groups, —OCOR8 groups or —OR8 groups in which R8 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups; —Y is selected from ethers such as, for example, diethyl ether, tetrahydrofuran (THF), dimethoxyethane, preferably is tetrahydrofuran (THF); —n is 0 or 1. Said oxo-nitrogenated vanadium complex having the general formula (I) may advantageously be used in a catalytic system for (co)polymerizing conjugated dienes.

  具有通式(I)的氧氮化钒络合物： 其中相互相同或不同的-R1、R2、R3、R4、R5、R6 和 R7 代表氢原子；或选自任选卤代、直链或支链 C1-C20，优选 C1-C15，烷基、任选取代的环烷基、任选取代的芳基；相互相同或不同的-X1 和 X2 代表卤原子，例如氯、溴、碘，优选氯；或选自直链或支链 C1-C20，优选 C1-C15，烷基、-OCOR8 基团或-OR8 基团，其中 R8 选自直链或支链 C1-C20，优选 C1-C15，烷基；-Y 选自醚类，例如二乙醚、四氢呋喃（THF）、二甲氧基乙烷，优选四氢呋喃（THF）；-n 为 0 或 1。具有通式(I)的所述氧化-氮化钒络合物可有利地用于共轭二烯（共）聚合的催化系统中。
• DE630769
  申请人：——

  公开号：——

  公开（公告）日：——
• OXO-NITROGENATED VANADIUM COMPLEX, CATALYTIC SYSTEM COMPRISING SAID OXO-NITROGENATED VANADIUM COMPLEX AND PROCESS FOR (CO)POLYMERISING CONJUGATED DIENES
  申请人：Versalis S.p.A.

  公开号：EP3237463B1

  公开（公告）日：2019-10-23
• [EN] OXO-NITROGENATED VANADIUM COMPLEX, CATALYTIC SYSTEM COMPRISING SAID OXO-NITROGENATED VANADIUM COMPLEX AND PROCESS FOR (CO)POLYMERISING CONJUGATED DIENES<br/>[FR] COMPLEXE DE VANADIUM OXO-AZOTÉ, SYSTÈME CATALYTIQUE COMPRENANT LEDIT COMPLEXE DE VANADIUM OXO-AZOTÉ ET PROCÉDÉ DE (CO)POLYMÉRISATION DE DIÈNES CONJUGUÉS
  申请人：VERSALIS SPA

  公开号：WO2016102639A1

  公开（公告）日：2016-06-30

  An oxo-nitrogenated vanadium complex having the general formula (I): in which: - R1, R2, R3, R4, R5, R6 and R7, mutually identical or different, represent a hydrogen atom; or are selected from optionally halogenated, linear or branched C1-C20, preferably C1-C15, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; - X1 and X2, mutually identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or are selected from linear or branched C1-C20, preferably C1-C15, alkyl groups, -OCOR8 groups or -OR8 groups in which R8 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups; - Y is selected from ethers such as, for example, diethyl ether, tetrahydrofuran (THF), dimethoxyethane, preferably is tetrahydrofuran (THF); - n is 0 or 1. Said oxo-nitrogenated vanadium complex having the general formula (I) may advantageously be used in a catalytic system for (co)polymerising conjugated dienes.