3-methylbicyclo<4.3.0^2,4>octan-1-one | 64558-16-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-methylbicyclo<4.3.0^2,4>octan-1-one
• 英文别名: 3-Methyl-hexahydro-indanon-(1)；3-methyl-hexahydro-indan-1-one；3-Methyl-hexahydro-indan-1-on；1H-Inden-1-one, octahydro-3-methyl-；3-methyl-2,3,3a,4,5,6,7,7a-octahydroinden-1-one
• CAS: 64558-16-3
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: CQLYRJDTAQYJIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-methylbicyclo<4.3.0^2,4>octan-1-one 、 聚合甲醛 、 盐酸二甲胺 以32%的产率得到
  参考文献：
  名称：

  BRANCACCIO, G.;LETTIERI, G.;MONFORTE, P.;LARIZZA, A., FARMACO. ED. SCI., 1983, 38, N 9, 702-708

  摘要：

  DOI：
• 作为产物：
  描述：

  顺-1,2-环己烷二羧酸二乙酯 在 镍 、 sodium hydride 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 生成 3-methylbicyclo<4.3.0^2,4>octan-1-one
  参考文献：
  名称：

  .beta.-Keto sulfoxides. V. Condensation of dimethyl sulfoxide and dimethyl sulfone with dibasic esters

  摘要：

  DOI：

  10.1021/jo01260a020

文献信息

• PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION, DYE-ABSORBED ELECTRODE, AND METHOD FOR MANUFACTURING DYE-SENSITIZED SOLAR CELL
  申请人：Fujifilm Corporation

  公开号：EP2933875A1

  公开（公告）日：2015-10-21

  A photoelectric conversion element including an electrically conductive support, a photoconductor layer containing an electrolyte, a charge transfer layer containing an electrolyte, and a counter electrode, wherein the photoconductor layer contains semiconductor fine particles carrying a metal complex dye represented by Formula (I); a metal complex dye, a dye solution, a dye-adsorbed electrode, a dye-sensitized solar cell, and a method for producing dye-sensitized solar cell:         M(LD)(LA)·(CI)     Formula(I) wherein, in the formula, M represents a metal ion; LD represents a tridentate ligand represented by formulas (DL-1) to (DL-4); LA represents a specific tridentate ligand; and CI represents a counter ion to neutralize an electric charge: Y1 and Y2 represent an oxygen atom, a sulfur atom, a substituted or unsubstituted nitrogen atom, or a substituted or unsubstituted phosphorus atom; the rings AD and BD represent a hydrocarbon ring or a hetero ring; L represents a linking group represented by the following formulas (L-1) to (L-4); and Ra and Rb each independently represent a substituent, X represents a nitrogen atom or a carbon atom; the ring CD represents a nitrogen-containing hetero ring; T represents -O-, -S-, -NRL2- or -PRL3-; RL1 to RL3 represent a hydrogen atom or a substituent; and Alk represents an alkylene group.

  一种光电转换元件，包括导电支架、含有电解质的光电导层、含有电解质的电荷转移层和对电极，其中光电导层含有携带由式（I）表示的金属络合染料的半导体微粒；一种金属络合染料、一种染料溶液、一种染料吸附电极、一种染料敏化太阳能电池和一种生产染料敏化太阳能电池的方法： M(LD)(LA)-(CI) 式(I) 式中，M 代表金属离子；LD 代表由式（DL-1）至（DL-4）表示的三叉配体；LA 代表特定的三叉配体；CI 代表用于中和电荷的反离子： Y1 和 Y2 代表氧原子、硫原子、取代或未取代的氮原子或取代或未取代的磷原子；环 AD 和 BD 代表烃环或杂环；L 代表由下列式子（L-1）至（L-4）表示的连接基团；Ra 和 Rb 各自独立地代表取代基、 X 代表氮原子或碳原子；环 CD 代表含氮杂环；T 代表-O-、-S-、-NRL2-或-PRL3-；RL1 至 RL3 代表氢原子或取代基；Alk 代表亚烷基。
• Electroorganic chemistry. 140. Electroreductively promoted intra- and intermolecular couplings of ketones with nitriles.
  作者：Tatsuya Shono、Naoki Kise、Taku Fujimoto、Naoto Tominaga、Hiroshi Morita

  DOI：10.1021/jo00052a036

  日期：1992.12

  Electroreduction of gamma and delta-cyano ketones in i-PrOH with Sn cathode gave alpha-hydroxy ketones and their dehydroxylated ketones as the intramolecularly coupled products. Guaiazulene, (-)-valeranone, polyquinanes, dihydrojasmone, methyl dihydrojasmonate, and rosaprostol have been synthesized by utilizing this electroreductive intramolecular coupling of gamma and delta-cyano ketones in one of the key steps. Similarly, electroreduction of a mixture of ketone and nitrile gave the corresponding intermolecularly coupled product. The product obtained by the electroreductive intermolecular coupling of (+)-dihydrocarvone with acetonitrile has been found to be the precursor of an effective chiral ligand for the enantioselective addition of diethylzinc to aldehydes.
• Oxidation of unsaturated linear and cyclic hydrocarbons by molecular oxygen catalyzed by complexes of transition metals
  作者：G. A. Dzhemileva、V. N. Odinokov、U. M. Dzhemilev

  DOI：10.1007/bf00953862

  日期：1987.1
• Nasarow; Pinkina, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1946, p. 633,641
  作者：Nasarow、Pinkina

  DOI：——

  日期：——
• PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION, DYE-ADSORBED ELECTRODE, AND METHOD FOR PRODUCING DYE-SENSITIZED SOLAR CELL
  申请人：FUJIFILM CORPORATION

  公开号：EP2933875B1

  公开（公告）日：2017-03-29