(Z)-2,6-dimethyl-5,7-octadien-4-ol | 65442-32-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (Z)-2,6-dimethyl-5,7-octadien-4-ol
• 英文别名: 2,6-dimethylocta-5(Z),7-dien-4-ol；(Z)-2,6-dimethyl-octa-5,7-dien-4-ol；cis-2,6-Dimethyl-octa-5,7-dien-4-ol；(5Z)-2,6-dimethylocta-5,7-dien-4-ol
• CAS: 65442-32-2
• 化学式: C₁₀H₁₈O
• 分子量: 154.252
• InChiKey: URNNEBUYFWSLAH-CLFYSBASSA-N

物化性质

• 沸点：
  85-88 °C(Press: 1 Torr)
• 密度：
  0.855±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.53
• 重原子数：
  11.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  3-甲基-3-丁烯-1-醇 在 正丁基锂 、 5,6-二氢-4-甲基-2-(2-甲基丙基)-2H-吡喃 、 硫酸 、 potassium tert-butylate 、 二异丙胺 作用下， 反应 5.0h， 生成 (Z)-2,6-dimethyl-5,7-octadien-4-ol
  参考文献：
  名称：

  1,2-Elimination of alcohol from homoallyl ethers under the influence of mixed metal bases

  摘要：

  DOI：

  10.1016/s0040-4020(01)82022-6

文献信息

• A simple synthesis of (±)-2,6-dimethylocta-5(Z),7-diene-4-ol and its attractant activity for the bark beetle Ips typographus
  作者：V. V. Veselovsky、A. V. Lozanova、R. R. Khairetdinov、N. V. Vendilo、K. V. Lebedeva

  DOI：10.1007/s11172-005-0129-3

  日期：2004.10

  A simple method for the synthesis of (±)-2,6-dimethylocta-5(Z),7-diene-4-ol possessing a high pheromone activity for the bark beetle Ips typographus was developed.

  一种合成具有高信息素活性的（±）-2,6-二甲基-5（Z），7-辛二烯-4-醇的简单方法被开发出来，该化合物对树皮甲虫Ips typographus具有高信息素活性。
• A regio- and stereocontrolled access to 2,4-dienols by amide/alcoholate-promoted ring-opening of dihydro-pyrans
  作者：Christian Margot、Manfred Schlosser

  DOI：10.1016/s0040-4039(00)98505-8

  日期：1985.1
• Narcissus trevithian and Narcissus geranium: Analysis and synthesis of compounds
  作者：Hans M. van Dort、Paul P. Jagers、Roel. ter Heide、Anton J. A. van der Weerdt

  DOI：10.1021/jf00035a047

  日期：1993.11

  The essential oils of two narcissus varieties, Narcissus trevithian and Narcissus geranium, obtained by extraction of flowers followed by high vacuum distillation of the absolute, were analyzed by GC/MS. After separation in fractions, unknown compounds were isolated by preparative GLC and their structures established by NMR/IR spectroscopy. The synthesis of a number of new compounds, found for the first time in narcissus oil, is described. The two narcissus species are compared with respect to their main components and odor quality. All compounds found so far in narcissus varieties are listed.
• Khrimyan, A. P.; Garibyan, O. A.; Panosyan, G. A., Russian Journal of Organic Chemistry, 1993, vol. 29, # 12, p. 1961 - 1973
  作者：Khrimyan, A. P.、Garibyan, O. A.、Panosyan, G. A.、Mailyan, N. Sh.、Kinoyan, F. S.、et al.

  DOI：——

  日期：——
• MARGOT, CHRISTIAN;RIZZOLIO, MICHELE;SCHLOSSER, MANFRED, TETRAHEDRON, 46,(1990) N, C. 2411-2424
  作者：MARGOT, CHRISTIAN、RIZZOLIO, MICHELE、SCHLOSSER, MANFRED

  DOI：——

  日期：——