(R)-[(2R,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methanol | 104016-94-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (R)-[(2R,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methanol
• CAS: 104016-94-6
• 化学式: C₃₀H₆₄O₇Si₃
• 分子量: 621.09
• InChiKey: KTVJCLANESZNOS-JVIQZWCRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.46
• 重原子数：
  40.0
• 可旋转键数：
  9.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  75.61
• 氢给体数：
  1.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  phenylsulfonyl 3,4,6-tri-O-butyldimethylsilyl-2-deoxy-α,β-D-arabino-hexopyranoside 、 (R)-(+)-2,2-二甲基-1,3-二氧戊环-4-甲醛 生成 (R)-[(2R,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methanol 、 (R)-[(2R,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methanol
  参考文献：
  名称：

  D-glycopyranosyl phenylsulfones: Their use in a stereocontrolledsynthesis of cis-2,6-disubstituted tetrahydropyrans (β-d-c-clycosides)

  摘要：

  DOI：

  10.1016/s0040-4039(00)95049-4