1-乙基-4-[3-(3-乙基-3H-苯并恶唑-2-亚基)丙-1-烯基]喹啉鎓碘化物 | 32151-96-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 中文名称: 1-乙基-4-[3-(3-乙基-3H-苯并恶唑-2-亚基)丙-1-烯基]喹啉鎓碘化物
• 英文名称: 1-(3-ethyl-benzoxazol-2-yl)-3-(1-ethyl-[4]quinolyl)-trimethinium ; iodide
• 英文别名: 1-(3-Aethyl-benzoxazol-2-yl)-3-(1-aethyl-[4]chinolyl)-trimethinium; Jodid；1-ethyl-4-[3-(3-ethyl-3H-benzoxazol-2-ylidene)prop-1-enyl]quinolinium iodide；1,3'-Diaethyl-4,2'-chinolyloxacarbocyanin Iodid；1-Ethyl-4-(3-(3-ethyl-3H-benzoxazol-2-ylidene)prop-1-enyl)quinolinium iodide；(2E)-3-ethyl-2-[(E)-3-(1-ethylquinolin-1-ium-4-yl)prop-2-enylidene]-1,3-benzoxazole;iodide
• CAS: 32151-96-5
• 化学式: C₂₃H₂₃N₂O*I
• 分子量: 470.353
• InChiKey: ZIENXIAZWJNLEK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.92
• 重原子数：
  27
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  16.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-乙基-2-甲基-苯并恶唑翁碘化物 在 sulfonyl chloride resin 、 N,N-二异丙基乙胺 、 原甲酸三乙酯 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 生成 1-乙基-4-[3-(3-乙基-3H-苯并恶唑-2-亚基)丙-1-烯基]喹啉鎓碘化物
  参考文献：
  名称：

  Solid-Phase Catch, Activate, and Release Synthesis of Cyanine Dyes

  摘要：

  [graphics]Trimethine cyanine dye was synthesized by capture and activation of a hemicyanine intermediate on sulfonyl chloride resin followed by reaction and concomitant cleavage by a heterocyclic carbon nucleophile. A small array of dyes were synthesized and characterized to demonstrate the versatility of this chemistry for a number of hemicyanines and heterocyclic nucleophiles.

  DOI：

  10.1021/ol026836j

文献信息

• PHOSPHOR SHEET, WHITE LIGHT SOURCE DEVICE HAVING SAID PHOSPHOR SHEET, AND DISPLAY APPARATUS HAVING SAID WHITE LIGHT SOURCE DEVICE
  申请人：Dexerials Corporation

  公开号：EP3321718A1

  公开（公告）日：2018-05-16

  Disclosed are a phosphor sheet capable of improving color purity of each of RGB reproduced through a color filter, a white light source device including the phosphor sheet, and a display device including the white light source device. The disclosed phosphor sheet is a phosphor sheet for converting LED light into white light, including: a phosphor layer containing at least a phosphor and a resin; and a pair of transparent substrates sandwiching the phosphor layer, in which the phosphor sheet includes a coloring material having an absorption maximum wavelength of at least one of from 480 nm to 510 nm or from 570 nm to 620 nm.

  本发明公开了一种能够提高通过彩色滤光片再现的 RGB 各色彩纯度的荧光粉片、一种包括该荧光粉片的白光光源装置，以及一种包括该白光光源装置的显示装置。所公开的荧光粉片是一种用于将 LED 光转换为白光的荧光粉片，包括：至少含有荧光粉和树脂的荧光粉层；以及夹住荧光粉层的一对透明基板，其中荧光粉片包括一种着色材料，该材料的吸收最大波长至少为 480 纳米至 510 纳米或 570 纳米至 620 纳米中的一种。
• Phosphor sheet, white light source device including the phosphor sheet, and display device including the white light source device
  申请人：Dexerials Corporation

  公开号：US11183617B2

  公开（公告）日：2021-11-23

  Disclosed are a phosphor sheet capable for converting light from LEDs into white light, a white light source device including the phosphor sheet, and a display device including the white light source device. The disclosed phosphor sheet includes a phosphor layer containing at least a phosphor and a resin; and a pair of transparent substrates sandwiching the phosphor layer. The phosphor sheet comprises a coloring material having an absorption maximum wavelength of at least one of from 480 nm to 510 nm or from 570 nm to 620 nm. The coloring material is contained in the phosphor layer. The transparent substrates are adhered to both surfaces of the phosphor layer. the phosphor layer has a thickness of 20 μm to 200 μm. An indicator of the usage amount of the coloring material defined by the following formula is 0.003 to 0.028: (indicator of the usage amount of the coloring material)=((blending amount of the coloring material in the phosphor layer)/(blending amount of a resin in the phosphor layer))×(the thickness of the phosphor layer (μm)).

  所公开的是一种能够将发光二极管发出的光转换成白光的荧光粉片、一种包括该荧光粉片的白光光源装置，以及一种包括该白光光源装置的显示装置。所公开的荧光粉片包括至少含有荧光粉和树脂的荧光粉层；以及夹住荧光粉层的一对透明基板。荧光粉片包含一种着色材料，其吸收最大波长为 480 纳米至 510 纳米或 570 纳米至 620 纳米中的至少一种。着色材料包含在荧光粉层中。荧光粉层的厚度为 20 μm 至 200 μm。由下式定义的着色材料用量指标为 0.003 至 0.028：（着色材料用量指标）=（（荧光粉层中着色材料的混合量）/（荧光粉层中树脂的混合量））×（荧光粉层的厚度（μm））。
• Photographic emulsion containing supersensitized-4'-carbocyanines
  申请人：EASTMAN KODAK CO

  公开号：US02158883A1

  公开（公告）日：1939-05-16
• Color and Constitution. VII.¹ Interpretation of Absorptions of Dyes Containing Heterocyclic Nuclei of Different Basicities
  作者：L. G. S. Brooker、A. L. Sklar、H. W. J. Cressman、G. H. Keyes、L. A. Smith、R. H. Sprague、E. Van Lare、G. Van Zandt、F. L. White、W. W. Williams

  DOI：10.1021/ja01227a002

  日期：1945.11
• PHOSPHOR SHEET, WHITE LIGHT SOURCE DEVICE INCLUDING THE PHOSPHOR SHEET, AND DISPLAY DEVICE INCLUDING THE WHITE LIGHT SOURCE DEVICE
  申请人：Dexerials Corporation

  公开号：US20190006563A1

  公开（公告）日：2019-01-03

  Disclosed are a phosphor sheet capable of improving color purity of each of RGB reproduced through a color filter, a white light source device including the phosphor sheet, and a display device including the white light source device. The disclosed phosphor sheet is a phosphor sheet for converting LED light into white light, including: a phosphor layer containing at least a phosphor and a resin; and a pair of transparent substrates sandwiching the phosphor layer, in which the phosphor sheet includes a coloring material having an absorption maximum wavelength of at least one of from 480 nm to 510 nm or from 570 nm to 620 nm.