bis(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexanesulfonyl)imide | 213342-85-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: bis(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexanesulfonyl)imide
• 英文别名: bis((perfluorohexyl)sulfonyl)amine；bis(1,1,2,2,3,3,4,4,5,5,6,6,6)-tridecafluoro-n-hexylsulfinimide；1,1,2,2,3,3,4,4,5,5,6,6,6-Tridecafluoro-N-((perfluorohexyl)sulfonyl)hexane-1-sulfonamide；1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-N-(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexylsulfonyl)hexane-1-sulfonamide
• CAS: 213342-85-9
• 化学式: C₁₂HF₂₆NO₄S₂
• 分子量: 781.235
• InChiKey: NZCVFAPYZQZVIO-UHFFFAOYSA-N

物化性质

• 熔点：
  132.5 °C
• 沸点：
  328.0±52.0 °C(Predicted)
• 密度：
  1.861±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  45
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  97.1
• 氢给体数：
  1
• 氢受体数：
  31

反应信息

• 作为反应物：
  描述：

  bis(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexanesulfonyl)imide 在 lithium hydride 作用下， 以 甲基叔丁基醚 为溶剂， 以88%的产率得到lithium bis((perfluorohexyl)sulfonyl)amide
  参考文献：
  名称：

  TW2018/43166

  摘要：

  公开号：
• 作为产物：
  描述：

  全氟正己基磺酰胺 在 硫酸 、 lithium hydride 作用下， 以 四氢呋喃 、 乙醚 、 水 为溶剂， 反应 18.25h， 生成 bis(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexanesulfonyl)imide
  参考文献：
  名称：

  TW2018/43166

  摘要：

  公开号：

文献信息

• Synthesis of symmetric and dissymetric bisperfluoroalkanesulfonylimides and evaluation of their inhibition on bovine carbonic anhydrase
  作者：Zohra Benfodda、Franck Guillen、Hubert Blancou

  DOI：10.1002/hc.20452

  日期：2008.7

  describes a synthesis of symmetric and dissymmetric bis[(perfluoroalkane)-sulfonyl]imides by the reaction of the sodium salt of perfluoroalkanesulfonamide RFSO2NH−Na+ (RF = C4F9, C6F13, C8F17) with hexamethyldisilazane and perfluoroalkanesulfonylfluoride RFSO2F (RF = C4F9, C6F13, C8F17). They are obtained, in two steps, in moderate overall yield. Moreover, this paper provides a study of their inhibition on

  本研究描述了通过全氟烷烃磺酰胺 RFSO2NH−Na+（RF = C4F9、C6F13、C8F17）的钠盐与六甲基二硅氮烷和全氟烷烃磺酰氟 RFSO2F（RF = C4F39 , )。它们分两步以中等总产率获得。此外，本文还研究了它们对牛碳酸酐酶的抑制作用。© 2008 Wiley Periodicals, Inc. 杂原子化学 19:542–548, 2008; 在线发表于 Wiley InterScience (www.interscience.wiley.com)。DOI 10.1002/hc.20452
• Pharmaceutical Compositions Based on Fluorinated Sulphamides and Sulphinimides
  申请人：Blancou Hubert

  公开号：US20080015255A1

  公开（公告）日：2008-01-17

  Pharmacuetical composition comprising compounds of formula (I): NZ 1 Z 2 Z 3 (I) in which: Z 1 , Z 2 , Z 3 each independently of the others represents: a hydrogen atom; C 1 -C 6 -alkyl group; a group —SO 2 R 3 wherein R 3 represents a linear or branched C 1 -C 12 -alkyl, -alkenyl or -alkynyl group, a C 3 -C 10 -cycloalkyl group or a C 6 -C 10 -aryl group, a (C 1 -C 6 )-alkyl-(C 6 -C 14 )-aryl group, or a C 5 -C 10 -heteroaryl group; it being understood that at least one of the groups Z 1 , Z 2 , Z 3 represents a group of formula (II) X—R F —(CH 2 ) n —SO 2 —  (II) X, RF and n being as defined in claim 1.

  含有以下式(I)的化合物的药物组合物：NZ1Z2Z3(I)其中：Z1、Z2、Z3分别独立地表示：氢原子；C1-C6-烷基团；—SO2R3基团其中R3表示线性或支链的C1-C12烷基、烯基或炔基团、C3-C10环烷基团或C6-C10芳基团、(C1-C6)-烷基-(C6-C14)-芳基团或C5-C10杂环芳基团；理解至少有一个Z1、Z2、Z3基团表示如下式(II)的基团X—RF—(CH2)n—SO2—  (II)其中X、RF和n如权利要求1中定义。
• Active OLED display, method for preparing an active OLED display and compound
  申请人：Novaled GmbH

  公开号：US11201306B2

  公开（公告）日：2021-12-14

  The present invention relates to a display device comprising—a plurality of OLED pixels comprising at least two OLED pixels, the OLED pixels comprising an anode, a cathode, and a stack of organic layers, wherein the stack of organic layers—is arranged between and in contact with the cathode and the anode, and—comprises a first electron transport layer, a first hole transport layer, and a first light emitting layer provided between the first hole transport layer and the first electron transport layer, and—a driving circuit configured to separately driving the pixels of the plurality of OLED pixels, wherein, for the plurality of OLED pixels, the first hole transport layer is provided in the stack of organic layers as a common hole transport layer shared by the plurality of OLED pixels, and the first hole transport layer comprises (i) at least one first hole transport matrix compound consisting of covalently bound atoms and (ii) at least one electrical p-dopant selected from metal salts and from electrically neutral metal complexes comprising a metal cation and at least one anion and/or at least one anionic ligand consisting of at least 4 covalently bound atoms, wherein the metal cation of the electrical p-dopant is selected from alkali metals; alkaline earth metals, Pb, Mn, Fe, Co, Ni, Zn, Cd; rare earth metals in oxidation state (II) or (III); Al, Ga, In; and from Sn, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and W in oxidation state (IV) or less, a method for preparing the display device and a chemical compound for use therein.

  本发明涉及一种显示装置，包括-多个 OLED 像素，该多个 OLED 像素包括至少两个 OLED 像素，该 OLED 像素包括阳极、阴极和有机层堆叠，其中有机层堆叠-布置在阴极和阳极之间并与阴极和阳极接触，并且-包括第一电子传输层、第一空穴传输层和设置在第一空穴传输层和第一电子传输层之间的第一发光层，以及-驱动电路，该驱动电路被配置为分别驱动多个 OLED 像素中的像素，其中、对于多个 OLED 像素，第一空穴传输层作为多个 OLED 像素共享的共用空穴传输层被设置在有机层堆叠中、第一空穴传输层包括：(i) 至少一种由共价结合原子组成的第一空穴传输基质化合物；(ii) 至少一种选自金属盐和电中性金属复合物的电 p-掺杂剂，电中性金属复合物包括金属阳离子和至少一种阴离子和/或至少一种由至少 4 个共价结合原子组成的阴离子配体，其中电 p-掺杂剂的金属阳离子选自碱金属碱土金属、Pb、Mn、Fe、Co、Ni、Zn、Cd；氧化态（II）或（III）的稀土金属；Al、Ga、In；以及氧化态（IV）或更低的Sn、Ti、Zr、Hf、V、Nb、Ta、Cr、Mo和W。
• ACTIVE OLED DISPLAY, METHOD FOR PREPARING AN ACTIVE OLED DISPLAY AND COMPOUND
  申请人：Novaled GmbH

  公开号：EP3583637B1

  公开（公告）日：2022-05-04
• Active OLED Display, Method for Preparing an Active OLED Display and Compound
  申请人：Novaled GmbH

  公开号：US20220059787A1

  公开（公告）日：2022-02-24

  The present invention relates to a display device comprising a plurality of OLED pixels comprising at least two OLED pixels, the OLED pixels comprising an anode, a cathode, and a stack of organic layers, wherein the stack of organic layers is arranged between and in contact with the cathode and the anode, and comprises a first electron transport layer, a first hole transport layer, and a first light emitting layer provided between the first hole transport layer and the first electron transport layer, and a driving circuit configured to separately driving the pixels of the plurality of OLED pixels, wherein, for the plurality of OLED pixels, the first hole transport layer is provided in the stack of organic layers as a common hole transport layer shared by the plurality of OLED pixels, and the first hole transport layer comprises (i) at least one first hole transport matrix compound consisting of covalently bound atoms and (ii) at least one electrical p-dopant selected from metal salts and from electrically neutral metal complexes comprising a metal cation and at least one anion and/or at least one anionic ligand consisting of at least 4 covalently bound atoms, wherein the metal cation of the electrical p-dopant is selected from alkali metals; alkaline earth metals, Pb, Mn, Fe, Co, Ni, Zn, Cd; rare earth metals in oxidation state (II) or (III); Al, Ga, In; and from Sn, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and W in oxidation state (IV) or less, a method for preparing the display device and a chemical compound for use therein.