allyl 1-hydroxycyclohexanoate

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: allyl 1-hydroxycyclohexanoate
• 英文别名: 1-hydroxy-cyclohexanecarboxylic acid allyl ester；1-Hydroxy-cyclohexancarbonsaeure-allylester；Prop-2-enyl 1-hydroxycyclohexane-1-carboxylate
• 化学式: C₁₀H₁₆O₃
• 分子量: 184.235
• InChiKey: UPNHFONCYFGVDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (三苯基膦烯)乙烯酮 、 allyl 1-hydroxycyclohexanoate 在 苯甲酸 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以85%的产率得到4-allyloxy-1-oxaspiro[4.5]dec-3-en-2-one
  参考文献：
  名称：

  An Unusual Domino Claisen−Conia Reaction Producing 3,5-Dispirodihydrofuran-2,4-diones

  摘要：

  Allyl tetronates 3 can be selectively converted either (in acetonitrile) into Claisen-rearranged 3-allyltetronic adds 5 or (in toluene) into novel Claisen-Conia-rearranged 3-(spirocyclopropyl)dihydrofuran-2,4-diones 6, featuring up to three new stereogenic centres. The mechanism and the stereochemistry of this process is discussed and an X-ray crystal structure of one of the two diastereoisomers of (+/-)-6c is presented.

  DOI：

  10.1002/1099-0690(200105)2001:10<1951::aid-ejoc1951>3.0.co;2-y
• 作为产物：
  描述：

  Alpha-羟基-环己基甲酸 、 烯丙醇 在 硫酸 作用下， 以 氯仿 为溶剂， 以79%的产率得到allyl 1-hydroxycyclohexanoate
  参考文献：
  名称：

  An Unusual Domino Claisen−Conia Reaction Producing 3,5-Dispirodihydrofuran-2,4-diones

  摘要：

  Allyl tetronates 3 can be selectively converted either (in acetonitrile) into Claisen-rearranged 3-allyltetronic adds 5 or (in toluene) into novel Claisen-Conia-rearranged 3-(spirocyclopropyl)dihydrofuran-2,4-diones 6, featuring up to three new stereogenic centres. The mechanism and the stereochemistry of this process is discussed and an X-ray crystal structure of one of the two diastereoisomers of (+/-)-6c is presented.

  DOI：

  10.1002/1099-0690(200105)2001:10<1951::aid-ejoc1951>3.0.co;2-y

文献信息

• Thermosetting powdery coating composition
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0301557A1

  公开（公告）日：1989-02-01

  The thermosetting powdery coating composition of the invention comprises (A) from 40 to 98 parts by weight of a fluorinecontaining copolymer, which is a copolymer of a fluoroolefin and a comonomer having a crosslinkable reactive group, e.g., hydroxy, carboxyl, amino and glycidyl groups, containing at least 10% by weight of fluorine and having an intrinsic viscosity of 0.05-2 dl/g (30 °C, tetrahydrofuran) and a glass transition temperature of 30-120 °C and (B) from 60 to 2 parts by weight of a curing agent capable of forming crosslinks by reacting with the crosslinkable reactive groups in (A). The powdery coating composition of the invention is excellent in the dispersibility of pigments and efficiency in the coating works therewith and capable of giving a coating film having improved adhesion to the substrate surface, surface luster, impact resistance and insusceptibility to stain.

  本发明的热固性粉状涂料组合物包括 (A) 40 至 98 份（按重量计）的含氟共聚物，它是氟烯烃和具有可交联反应基团（如羟基、羧基、氨基和缩水甘油基）的共聚物，含氟量至少为 10%（按重量计），固有粘度为 0.05-2 dl/g（30℃，四氢呋喃）、(B) 60 至 2 份（按重量计）能与（A）中的可交联反应基团反应形成交联的固化剂。本发明的粉末涂料组合物在颜料的分散性和涂布效率方面都非常出色，能使涂膜与基材表面的附着力、表面光泽、抗冲击性和抗污性得到改善。
• LAMINATE AND PRODUCTION PROCESS THEREOF
  申请人：AGC Inc.

  公开号：EP3290204B1

  公开（公告）日：2019-07-03
• US5147934A
  申请人：——

  公开号：US5147934A

  公开（公告）日：1992-09-15
• US5439896A
  申请人：——

  公开号：US5439896A

  公开（公告）日：1995-08-08
• An Unusual Domino Claisen−Conia Reaction Producing 3,5-Dispirodihydrofuran-2,4-diones
  作者：Rainer Schobert、Sven Siegfried、Gary Gordon、Mark Nieuwenhuyzen、Stig Allenmark

  DOI：10.1002/1099-0690(200105)2001:10<1951::aid-ejoc1951>3.0.co;2-y

  日期：2001.5

  Allyl tetronates 3 can be selectively converted either (in acetonitrile) into Claisen-rearranged 3-allyltetronic adds 5 or (in toluene) into novel Claisen-Conia-rearranged 3-(spirocyclopropyl)dihydrofuran-2,4-diones 6, featuring up to three new stereogenic centres. The mechanism and the stereochemistry of this process is discussed and an X-ray crystal structure of one of the two diastereoisomers of (+/-)-6c is presented.