2-(2-(2-(2-hydroxy)ethoxy)ethoxy)ethyl-3(4-(9H-carbazol-9-yl)butoxy)-5-(4-(9-H-carbazol-9-yl)butoxy)benzoate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 2-(2-(2-(2-hydroxy)ethoxy)ethoxy)ethyl-3(4-(9H-carbazol-9-yl)butoxy)-5-(4-(9-H-carbazol-9-yl)butoxy)benzoate
• 英文别名: 2-[2-[2-(2-Hydroxyethoxy)ethoxy]ethoxy]ethyl 3,5-bis(4-carbazol-9-ylbutoxy)benzoate；2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethyl 3,5-bis(4-carbazol-9-ylbutoxy)benzoate
• 化学式: C₄₇H₅₂N₂O₈
• 分子量: 772.938
• InChiKey: FCCHCAOBSVCLDZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  57
• 可旋转键数：
  25
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.34
• 拓扑面积：
  103
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  9-(4-溴丁基)-9H-咔唑 在 4-二甲氨基吡啶 、 potassium carbonate 、 N,N'-二环己基碳二亚胺 、 potassium hydroxide 作用下， 以 四氢呋喃 、 乙醇 、 二氯甲烷 为溶剂， 反应 48.5h， 生成 2-(2-(2-(2-hydroxy)ethoxy)ethoxy)ethyl-3(4-(9H-carbazol-9-yl)butoxy)-5-(4-(9-H-carbazol-9-yl)butoxy)benzoate
  参考文献：
  名称：

  Electrochemical fabrication of graphene nanomesh via colloidal templating

  摘要：

  通过将聚苯乙烯（PS）球阵列到CVD沉积的石墨烯上，电沉积吲哚单元，去除PS模板和电化学氧化蚀刻，实现了石墨烯纳米网格（GNM）的简单制备。通过扫描电子显微镜（SEM）、原子力显微镜（AFM）和拉曼光谱对GNM进行了表征。

  DOI：

  10.1039/c5cc01831e

文献信息

• METHODS FOR PREPARING POLYMER COATINGS BY ELECTROCHEMICAL GRAFTING OF POLYMER BRUSHES, COMPOSITIONS PREPARED THEREBY AND COMPOSITIONS FOR PREPARING THE COATINGS
  申请人：Advincula Rigoberto

  公开号：US20090236229A1

  公开（公告）日：2009-09-24

  New methods for the grafting of complex polymer coatings onto conducting surfaces, new grafting compositions and new substrates with grafted coating of the grafting compositions are disclosed. The method offers a new and convenient approach for the preparation of polymer coatings by electrochemically grafting and reactive crosslinking, and/or graft polymerizing.

  本发明公开了将复杂聚合物涂层移植到导电表面的新方法，新的移植组合物和移植组合物移植到基底上的新涂层。该方法通过电化学移植和反应性交联和/或移植聚合的新颖和便捷的方法，提供了制备聚合物涂层的新方法。
• NEW TYPES OF ELECTRODEPOSITED POLYMER COATINGS WITH REVERSIBLE WETTABILITY AND ELECTRO-OPTICAL PROPERTIES
  申请人：UNIVERSITY OF HOUSTON SYSTEM

  公开号：US20160237305A1

  公开（公告）日：2016-08-18

  Novel coatings are disclosed prepared by electropolymerization of non-fluorinated conducting pre-grafted hydrophobic electropolymerizable monomers onto a conducting layer of a substrate, where the electropolymerized coating exhibit both unique reversible wettability and electro-optical properties. The coating may also include one or more layers of polymer particles upon which the non-fluorinated conducting pre-grafted hydrophobic electropolymerizable monomers are polymerized imparting a submicron structure to the coating. Methods for making and using the coatings are also disclosed.

  本发明揭示了一种新型涂层，通过将非氟化导电预接枝疏水电聚合单体电聚合到基底的导电层上制备而成，其中电聚合涂层具有独特的可逆润湿性和电光性能。该涂层还可以包括一层或多层聚合物颗粒，其中非氟化导电预接枝疏水电聚合单体被聚合，从而赋予涂层亚微米结构。还揭示了制备和使用该涂层的方法。
• US9079999B2
  申请人：——

  公开号：US9079999B2

  公开（公告）日：2015-07-14
• Electrochemical fabrication of graphene nanomesh via colloidal templating
  作者：J. D. Mangadlao、A. C. C. de Leon、M. J. L. Felipe、R. C. Advincula

  DOI：10.1039/c5cc01831e

  日期：——

  A simple fabrication of graphene nanomesh (GNM) was accomplished by arraying polystyrene (PS) spheres onto a CVD-deposited graphene, electro-deposition of carbazole units, removal of PS template and electrochemical oxidative etching. The GNM was characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM) and Raman spectroscopy.

  通过将聚苯乙烯（PS）球阵列到CVD沉积的石墨烯上，电沉积吲哚单元，去除PS模板和电化学氧化蚀刻，实现了石墨烯纳米网格（GNM）的简单制备。通过扫描电子显微镜（SEM）、原子力显微镜（AFM）和拉曼光谱对GNM进行了表征。