bis<4-<6-(carbazol-9-methyl)-7-(carbazol-9-yl)-3-hydroxy-5-oxa-1-thioheptyl>phenyl>sulphide

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: bis<4-<6-(carbazol-9-methyl)-7-(carbazol-9-yl)-3-hydroxy-5-oxa-1-thioheptyl>phenyl>sulphide
• 英文别名: 1-[2-(9H-carbazol-9-yl)-1-(9H-carbazol-9-ylmethyl)ethoxy]-3-[(4-{[4-({3-[2-(9H-carbazol-9-yl)-1-(9H-carbazol-9-ylmethyl)ethoxy]-2-hydroxypropyl}sulfanyl)phenyl]sulfanyl}phenyl)sulfanyl]-2-propanol；1-[1,3-di(carbazol-9-yl)propan-2-yloxy]-3-[4-[4-[3-[1,3-di(carbazol-9-yl)propan-2-yloxy]-2-hydroxypropyl]sulfanylphenyl]sulfanylphenyl]sulfanylpropan-2-ol
• 化学式: C₇₂H₆₂N₄O₄S₃
• 分子量: 1143.51
• InChiKey: FZLRTFAEMKLOPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.8
• 重原子数：
  83
• 可旋转键数：
  22
• 环数：
  14.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  155
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  乙酸酐 、 bis<4-<6-(carbazol-9-methyl)-7-(carbazol-9-yl)-3-hydroxy-5-oxa-1-thioheptyl>phenyl>sulphide 在 吡啶 作用下， 生成
  参考文献：
  名称：

  Electronic properties of indan-1,3-dione-carbazole-based compounds revealed by time resolved spectroscopy

  摘要：

  Two new indan-1,3-dione and carbazole-based (IDC) compounds with single and four covalently connected chromophores were synthesized and their optical properties were investigated in solutions and in solid films with the emphasis on the interchromophore interactions. Because of molecule twisting, opening transitions to n pi* states, IDC chromophores experience ultrafast excited state relaxation with the time constant of about 2 ps in solutions and several times slower solid films. Chromophore connection into quadruplicate molecules only weakly influence their spectroscopic properties in solutions, however prevents H-type aggregate formation and concomitant spectral changes in solid films. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2014.02.011
• 作为产物：
  描述：

  4'4-二巯基二苯硫醚 、 1,3-bis(carbazol-9-yl)-2-propanol glycidyl ether 在 三乙胺 作用下， 以 氯苯 为溶剂， 反应 1.0h， 以70.9%的产率得到bis<4-<6-(carbazol-9-methyl)-7-(carbazol-9-yl)-3-hydroxy-5-oxa-1-thioheptyl>phenyl>sulphide
  参考文献：
  名称：

  Synthesis of carbazole containing Organic Photosemiconductors using dimercapto compounds

  摘要：

  DOI：

  10.1002/prac.19953370165

文献信息

• Synthesis of carbazole containing Organic Photosemiconductors using dimercapto compounds
  作者：S. Kutkevicius、A. Stanisauskaite、V. Getautis、A. Railaite、S. Uss

  DOI：10.1002/prac.19953370165

  日期：——
• Electronic properties of indan-1,3-dione-carbazole-based compounds revealed by time resolved spectroscopy
  作者：Renata Karpicz、Marytė Daškevičienė、Vytautas Getautis、Alytis Gruodis、Vidmantas Gulbinas

  DOI：10.1016/j.dyepig.2014.02.011

  日期：2014.6

  Two new indan-1,3-dione and carbazole-based (IDC) compounds with single and four covalently connected chromophores were synthesized and their optical properties were investigated in solutions and in solid films with the emphasis on the interchromophore interactions. Because of molecule twisting, opening transitions to n pi* states, IDC chromophores experience ultrafast excited state relaxation with the time constant of about 2 ps in solutions and several times slower solid films. Chromophore connection into quadruplicate molecules only weakly influence their spectroscopic properties in solutions, however prevents H-type aggregate formation and concomitant spectral changes in solid films. (C) 2014 Elsevier Ltd. All rights reserved.