9-nonylcarbazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-nonylcarbazole
• 英文别名: N-nonylcarbazole
• 化学式: C₂₁H₂₇N
• 分子量: 293.452
• InChiKey: WFCFRQFTZDVEPX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  22
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9-nonylcarbazole 在 N-碘代丁二酰亚胺 、 溶剂黄146 作用下， 以 氯仿 为溶剂， 以85%的产率得到3,6-diiodo-9-nonylcarbazole
  参考文献：
  名称：

  Engineering Solid-State Morphologies in Carbazole–Ethynylene Macrocycles

  摘要：

  We present a crystallographic study that systematically investigates the effects of the n-alkyl side-chain length on the crystal packing in shape-persistent macrocycles. The solid-state packing of carbazole-ethynylene-containing macrocycles is sensitive to the alkyl-chain length. In macrocycles containing n-alkyl side chains up to nine carbons in length, face-on aromatic. pi interactions predominate, while the addition of one carbon leads to a completely different packing arrangement. Macrocycles with C-10 or C-11 chains exhibit a novel packing motif wherein the alkyl chains intercalate between macrocycles, leading in one case to continuous solvent-filled channels. When crystals of the C-10 macrocycle are bathed in solvent, the included molecules exchange with the external solvent, and the alkyl chain disorder changes in response to changes in the guest volume in order to retain crystallinity. Powder X-ray diffraction data indicate that alkyl-macrocycle interactions in the longer chains "emulate" the distances typical of face-to-face pi interactions, leading to deceptive indicators of pi stacking.

  DOI：

  10.1021/ja204795q
• 作为产物：
  描述：

  1-溴壬烷 、 咔唑 在 potassium hydroxide 作用下， 以 丙酮 为溶剂， 反应 12.0h， 生成 9-nonylcarbazole
  参考文献：
  名称：

  主机间相互作用控制三咔唑大环化合物与抗静电的硫酸氢盐二聚体共组装的三层和双层甲板的自组装和交换

  摘要：

  当使用具有强大且结构明确定义的识别元素的构建基块时，分层组装为复杂的体系结构提供了一条途径。传统上，这些规则是使用具有可靠的金属-配体键合的阳离子模板来表达的，但由于阴离子与主体之间的接触较弱，因此很少使用阴离子。我们研究了一种方法，该方法依赖于宿主之间的相互作用来增强硫酸氢根阴离子二聚体[HSO4⋅⋅HSO4] 2−之间形成的组装以及形状持久的大环化合物，即三咔唑三唑并烷。这些大环具有显着的自我关联。在氯仿中，它们与硫酸氢盐二聚体形成高保真度的三层堆叠。宿主间相互作用的强度使3：2三碳：硫酸氢盐构架优先于离子对构架的形成，而离子对构架的自缔合作用要弱得多。人们期望并发现溶剂会调节主机与主机之间的接触，从而能够在三叠式和双叠式结构之间形成2：2复杂且由溶剂驱动的转换。2：2：2配合物的晶体学支持这样一种观点，即三偶碳稳定的π-堆积产生了与tricarb的显着的宿主-宿主相互作用。还进行了计

  DOI：

  10.1002/chem.201800827

文献信息

• C–H Functionalization Reactions of Unprotected <i>N</i>-Heterocycles by Gold-Catalyzed Carbene Transfer
  作者：Sripati Jana、Claire Empel、Chao Pei、Polina Aseeva、Thanh V. Nguyen、Rene M. Koenigs

  DOI：10.1021/acscatal.0c02230

  日期：2020.9.4

  The C–H functionalization reaction of N-heterocycles with an unprotected N–H group is one of the most step-economic strategies to introduce functional groups without the need for installation and removal of protecting groups. Despite recent significant advances in C–H functionalization chemistry, this strategy remains unsatisfactorily developed. In this report, we disclose a simple and straightforward

  N-杂环与未保护的N-H基团的C-H官能化反应是引入官能团而无需安装和除去保护基团的最经济的步骤之一。尽管最近在C–H官能化化学方面取得了重大进展，但该策略仍未令人满意地开发。在本报告中，我们公开了一种简单直接的方案，可以对未保护的双苯甲酰氮进行选择性C–H功能化通过金催化的卡宾转移反应生成杂环（29个实例，产率高达86％）。反应的范围也可以扩展到相应的受保护的杂环（37个实例，最高收率98％），进一步证明了该方法的普遍性。通过密度泛函理论（DFT）计算进行的机理研究证明了金催化剂的重要性，并表明该反应的选择性是由反应混合物中存在的痕量水驱动的。
• Host–Host Interactions Control Self‐assembly and Switching of Triple and Double Decker Stacks of Tricarbazole Macrocycles Co‐assembled with anti‐Electrostatic Bisulfate Dimers
  作者：James R. Dobscha、Sibali Debnath、Rachel E. Fadler、Elisabeth M. Fatila、Maren Pink、Krishnan Raghavachari、Amar H. Flood

  DOI：10.1002/chem.201800827

  日期：2018.7.11

  complex supports the idea that significant host–host interactions with tricarb arises from dipole‐stabilized π‐stacking. Computational studies were also conducted further highlighting the importance of host–host interactions in stacked complexes of tricarb. These findings unambiguously verify the importance of host–host interactions in the assembly and stability of discrete, responsive anion‐templated

  当使用具有强大且结构明确定义的识别元素的构建基块时，分层组装为复杂的体系结构提供了一条途径。传统上，这些规则是使用具有可靠的金属-配体键合的阳离子模板来表达的，但由于阴离子与主体之间的接触较弱，因此很少使用阴离子。我们研究了一种方法，该方法依赖于宿主之间的相互作用来增强硫酸氢根阴离子二聚体[HSO4⋅⋅HSO4] 2−之间形成的组装以及形状持久的大环化合物，即三咔唑三唑并烷。这些大环具有显着的自我关联。在氯仿中，它们与硫酸氢盐二聚体形成高保真度的三层堆叠。宿主间相互作用的强度使3：2三碳：硫酸氢盐构架优先于离子对构架的形成，而离子对构架的自缔合作用要弱得多。人们期望并发现溶剂会调节主机与主机之间的接触，从而能够在三叠式和双叠式结构之间形成2：2复杂且由溶剂驱动的转换。2：2：2配合物的晶体学支持这样一种观点，即三偶碳稳定的π-堆积产生了与tricarb的显着的宿主-宿主相互作用。还进行了计
• Fluorinated polycyclic compounds
  申请人：ISC CHEMICALS LIMITED

  公开号：EP0368561A2

  公开（公告）日：1990-05-16

  A fully fluorinated and fully-saturated heterocyclic organic compound of general formula wherein the saturated rings F are fully fluorinated, and where the Rf radical is selected from perfluoro-alkyl groups, perfluoro-alicyclic groups, and mixed perfluoro-cycloalkyl-alkyl groups, and wherein the Rf radical contains from 1 to 10 carbon atoms inclusive.

  通式为全氟全饱和杂环有机化合物 其中饱和环 F 为全氟化，Rf 基选自全氟烷基、全氟脂环基和全氟环烷基-烷基混合基团，Rf 基含有 1 至 10 个碳原子（含 10 个）。
• Development in synthesis and electrochemical properties of thienyl derivatives of carbazole
  作者：Joanna Cabaj、Krzysztof Idzik、Jadwiga Sołoducho、Antoni Chyla

  DOI：10.1016/j.tet.2005.09.142

  日期：2006.1

  A convenient and higher yielding synthetic route to N-alkyl-bis(thiophene)- and N-alkyl-bis(ethylenedioxythiophene) carbazole derivatives is reported and their aggregation, and electrochemical properties are characterized. The key step in the synthesis of this group of compounds has been the Stille-type coupling reaction between the N-alkyldibromocarbazole and tin derivatives of thiophene or ethylenedioxythiophene, as the best way for preparation of conjugated N-alkylcarbazole derivatives. For this group of compounds we also present an electrochemical polymerization effect. (c) 2005 Elsevier Ltd. All rights reserved.
• Functionalized Phenothiazine and Carbazole Chromophores: Synthesis and Characterization
  作者：Jacek Doskocz、Jadwiga Sołoducho、Joanna Cabaj、Anna Nowakowska、Szczepan Roszak

  DOI：10.1080/10426500902856354

  日期：2009.5.14

  Synthesis, characterization, and photophysical properties for a few optical chromophores are reported. Phenothiazine and carbazole units played an important role to contribute high electron donability and connect the resonance pathway via conjugate effect in the cyclized ring besides the aromatic ring. Theoretical calculations and an absorption spectroscopic study gave useful information about the energy states and structures of chromophores.