3-methyloxonan-2-one

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 3-methyloxonan-2-one
• 化学式: C₉H₁₆O₂
• 分子量: 156.225
• InChiKey: YNTDEAJPDJLXKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-methyloxonan-2-one 在 二异丁基氢化铝 作用下， 以 二氯甲烷 为溶剂， 反应 0.25h， 生成 8-hydroxy-2-methyloctanal
  参考文献：
  名称：

  2-羟基-1,4-萘醌与乳酸酯的三组分还原烷基化

  摘要：

  通过DIBAL还原相应的内酯I并与羟醛互变异构体III平衡获得的Lactols II与2-羟基-1,4-萘醌进行三组分还原烷基化反应，得到一系列3-烷基化的2-羟基-1，4-萘醌衍生物IV。

  DOI：

  10.1016/j.tetlet.2016.01.036
• 作为产物：
  描述：

  8-溴辛酸 在 正丁基锂 、 四丁基氟化铵 、 二异丙胺 作用下， 以 四氢呋喃 、 正己烷 、 叔丁醇 为溶剂， 反应 4.75h， 生成 3-methyloxonan-2-one
  参考文献：
  名称：

  2-羟基-1,4-萘醌与乳酸酯的三组分还原烷基化

  摘要：

  通过DIBAL还原相应的内酯I并与羟醛互变异构体III平衡获得的Lactols II与2-羟基-1,4-萘醌进行三组分还原烷基化反应，得到一系列3-烷基化的2-羟基-1，4-萘醌衍生物IV。

  DOI：

  10.1016/j.tetlet.2016.01.036

文献信息

• Lactone modified, aminated dispersant additives useful in oleaginous compositions
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0263704A2

  公开（公告）日：1988-04-13

  Poly (C₅ - C₉ lactone) adducts are made by reacting a C₅ - C₉ lactone with an aminated hydrocarbyl substituted C₄ - C₁₀ monounsaturated dicarboxylic acid producing material, e.g. a polyisobutenyl succinimide, which, in turn, preferably is made by reacting a polymer of a C₂ to C₁₀ monoolefin, preferably polyisobutylene, having a molecular weight of about 700 to 5,000 with a C₄ to C₁₀ monunsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are about 0.7 to 2.00 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture, and then reacting the substituted acid, anhydride or ester with an amine. The resulting adducts are useful per se as oil soluble dispersant additives. They are also useful in fuel and lubricating oil compositions, as well as in concentrates and additive packages.

  聚(C₅-C₉内酯)加合物是由 C₅ - C₉ 内酯与胺化的烃基取代的 C₄ - C₁₀ 单不饱和二羧酸生产材料（例如）反应而成。聚异丁烯基琥珀酰亚胺，它最好是由分子量在 700 至 5,000 之间的 C₂ 至 C₁₀ 单烯烃（最好是聚异丁烯）聚合物与 C₄ 至 C₁₀ 单不饱和酸、酐或酯（最好是马来酸酐）反应而成，从而产生约 0.在反应混合物中，每分子所述烯烃聚合物含有约 0.7 至 2.00 个二羧酸生成分子，然后将取代的酸、酐或酯与胺反应。生成的加合物本身可用作油溶性分散剂添加剂。它们还可用于燃料和润滑油组合物以及浓缩物和复合添加剂。
• Adducts or reactants modified with a lactone and oleaginous compositions containing same
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0263706A2

  公开（公告）日：1988-04-13

  C₅-C₉ lactone based adduct materials are made by reacting a C₅-C₉ lactone with a polyamine, a polyol or an amino alcohol to form a lactone adduct intermediate, and thereafter reacting the intermediate with a hydrocarbyl substituted C₄-C₁₀ monounsaturated dicarboxylic acid producing material, e.g., a polyisobutenyl succinimide, which, in turn, preferably was made by reacting a polymer of a C₂ to C₁₀ monoolefin, preferably polyisobutylene, having a molecular weight of about 300 to 10,000 with a C₄ to C₁₀ monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are 0.7 to 2.0 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture. The resulting adduct material are useful per se, as oil soluble dispersant additives, and are useful in fuel and lubricating oil compositions including concentrates containing the additives.

  C₅-C₉内酯基加合物材料是通过使 C₅-C₉内酯与多胺、多元醇或氨基醇反应形成内酯加合物中间体，然后使该中间体与烃基取代的 C₄-C₁₀单不饱和二羧酸生产材料（例如）反应制成的、聚异丁烯基琥珀酰亚胺，而聚异丁烯基琥珀酰亚胺最好是通过将分子量约为 300 至 10,000 的 C₂ 至 C₁₀ 单烯烃（最好是聚异丁烯）聚合物与 C₄ 至 C₁₀ 单不饱和酸、酐或酯（最好是马来酸酐）反应制成，从而产生 0.在反应混合物中，每分子所述烯烃聚合物含有 0.7 至 2.0 个产生二羧酸的分子。生成的加成材料本身可用作油溶性分散剂添加剂，也可用于燃料和润滑油组合物，包括含有添加剂的浓缩物。
• Lactone modified dispersant additives useful in oleaginous compositions
  申请人：EXXON CHEMICAL PATENTS INC.

  公开号：EP0336717A2

  公开（公告）日：1989-10-11

  Lactone modified adducts are made by first reacting a non-polymerizable lactone or thiolactone and then a polymerizable C₅-C₉ lactone with an aminated hydrocarbyl substituted C₄ - C₁₀ monounsaturated dicarboxylic acid producing material, e.g. a polyisobutenyl succinimide, which, in turn, preferably is made by reacting a polymer of a C₂ to C₁₀ monoolefin, preferably polyisobutylene, having a molecular weight of about 700 to 5,000 with a C₄ to C₁₀ monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are about 0.7 to 2.0 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture, and then reacting the substituted acid, anhydride or ester with an amine. The resulting adducts are useful per se as oil soluble dispersant additives. They are also useful in fuel and lubricating oil compositions, as well as in concentrates and additive packages.

  内酯改性加合物是先将不可聚合的内酯或硫内酯，然后将可聚合的 C₅-C₉内酯与胺化的烃基取代的 C₄ - C₁₀ 单不饱和二羧酸生产材料（例如）反应制成的。聚异丁烯基琥珀酰亚胺，它最好是由分子量在 700 至 5,000 之间的 C₂ 至 C₁₀ 单烯烃（最好是聚异丁烯）聚合物与 C₄ 至 C₁₀ 单不饱和酸、酐或酯（最好是马来酸酐）反应而成，从而产生约 0.在反应混合物中，每分子所述烯烃聚合物中约有 0.7 至 2.0 个二羧酸生成分子，然后将取代的酸、酐或酯与胺反应。生成的加合物本身可用作油溶性分散剂添加剂。它们还可用于燃料和润滑油组合物以及浓缩物和复合添加剂。
• Mixtures of acetylpolyalkylindanes and acetylpolyalkyltetralines
  申请人：PFW AROMA CHEMICALS B.V.

  公开号：EP0565783A1

  公开（公告）日：1993-10-20

  The invention is directed to a mixture of acetylpolyalkylindanes and acetylpolyalkyl-tetralines obtainable by cycloalkylation of p-cymene and/or p, α-dimethylstyrene and/or 8-p-cymenyl halides and/or 8-p-cymenyl alcohol with a mixture of alkenes consisting of one or more methylbutene isomers and one or more dimethylbutene isomers, followed by acetylation of the intermediate mixture of polyalkylindanes and polyalkyltetralines.

  本发明涉及一种乙酰基聚烷基茚满和乙酰基聚烷基四氢萘的混合物，该混合物可通过对甲苯和/或对、α-二甲基苯乙烯和/或 8-对亚甲基卤化物和/或 8-对亚甲基醇与由一种或多种甲基丁烯异构体和一种或多种二甲基丁烯异构体组成的烯烃混合物进行环烷基化反应，然后对中间的聚烷基茚满和聚烷基四氢萘混合物进行乙酰化反应而获得。
• Polymeric viscosity modifiers for use in lubricants
  申请人：Afton Chemical Corporation

  公开号：US10836976B2

  公开（公告）日：2020-11-17

  A lubricating oil composition having greater than 50 wt % of a base oil and 0.1 wt % to 20 wt %, both based on the total weight of the lubricating oil composition, of a dispersant viscosity modifier obtainable by: A) reacting: a) at least one of a lactone of formula (I) or a derivative thereof: wherein X is oxygen, and R is an optionally substituted hydrocarbylene group having from 1 to 20 carbon atoms; and  b) at least one compound selected from amines, alcohols and oxazolines; and B) reacting the reaction product of step A) onto an acylated olefin copolymer obtainable by acylating a copolymer of ethylene and one or more C3-C10 alpha-olefins having a number average molecular weight of 5,000 to 200,000 g/mol as measured by GPC, with an acylating agent. Methods employing the lubricating oil compositions and uses of the lubricating compositions as engine oils are also described.

  一种润滑油组合物，其中基础油的重量百分比大于 50%，分散剂粘指剂的重量百分比为 0.1%至 20%（均以润滑油组合物的总重量为基准），分散剂粘指剂可通过以下方法获得： A) 反应： a) 至少一种式 (I) 的内酯或其衍生物： 其中 X 是氧，R 是具有 1 至 20 个碳原子的任选取代的碳氢基团；以及 b) 至少一种选自胺、醇和噁唑啉的化合物；以及 B）将步骤 A 的反应产物与酰化烯烃共聚物反应，酰化烯烃共聚物可通过将乙烯与一种或多种 C3-C10 α-烯烃的共聚物酰化而获得，乙烯与一种或多种 C3-C10 α-烯烃的共聚物经 GPC 测定的平均分子量为 5,000 至 200,000 g/mol，酰化烯烃共聚物可通过将乙烯与一种或多种 C3-C10 α-烯烃的共聚物酰化而获得。此外，还介绍了使用润滑油组合物的方法以及润滑油组合物作为发动机油的用途。