3,6-dimethyl-2,3,4,5,6,7-hexahydro-inden-1-one | 874532-44-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,6-dimethyl-2,3,4,5,6,7-hexahydro-inden-1-one
• 英文别名: 3,6-Dimethyl-2,3,4,5,6,7-hexahydro-inden-1-on；3,6-Dimethyl-2,3,4,5,6,7-hexahydroinden-1-one；3,6-dimethyl-2,3,4,5,6,7-hexahydroinden-1-one
• CAS: 874532-44-2
• 化学式: C₁₁H₁₆O
• 分子量: 164.247
• InChiKey: WUMGJDIHDFUJTH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  磷酸 、 3,6-dimethyl-2,3,4,5,6,7-hexahydro-inden-1-one 生成 1,5-Dimethyl-indan
  参考文献：
  名称：

  Nasarow; Pinkina, Zhurnal Obshchei Khimii, 1948, vol. 18, p. 681,682

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 磷酸 作用下， 生成 3,6-dimethyl-2,3,4,5,6,7-hexahydro-inden-1-one
  参考文献：
  名称：

  Nasarow; Pinkina, Zhurnal Obshchei Khimii, 1948, vol. 18, p. 681,682

  摘要：

  DOI：

文献信息

• [EN] SYNTHESIS OF CYCLIC ORGANIC COMPOUNDS AND METALLOCENES<br/>[FR] SYNTHÈSE DE COMPOSÉS ORGANIQUES CYCLIQUES ET DE MÉTALLOCÈNES
  申请人：UNIVATION TECH LLC

  公开号：WO2019067271A1

  公开（公告）日：2019-04-04

  A method comprising synthesizing a cyclic organic compound via reaction of an unsubstituted or substituted cyclohexene with an unsubstituted or substituted acrylic acid in the presence of phosphoric and/or sulfonic acid reagent to make the cyclic organic compound. Also, a method of synthesizing a ligand for a transition metal, and a related substituted ligand-metal complex and catalyst, from the unsubstituted or substituted cyclohexene and unsubstituted or substituted acrylic acid. Also, the cyclic organic compound, ligand, and substituted ligand-metal complex and catalyst synthesized thereby. Also a method of polymerizing an olefin with the catalyst to give a polyolefin, and the polyolefin made thereby.

  一种方法包括通过在磷酸和/或磺酸试剂存在下，将未取代或取代的环己烯与未取代或取代的丙烯酸反应合成一个环状有机化合物。此外，还包括一种合成过渡金属配体的方法，以及从未取代或取代的环己烯和未取代或取代的丙烯酸制备相关取代配体-金属配合物和催化剂的方法。还包括由此合成的环状有机化合物、配体和取代配体-金属配合物和催化剂。此外还包括一种利用该催化剂聚合烯烃以得到聚烯烃的方法，以及由此制得的聚烯烃。
• [EN] SYNTHESIS OF CYCLOPENTENONES WITH SULFONIC ACID REAGENTS<br/>[FR] SYNTHÈSE DE CYCLOPENTÉNONES À L'AIDE DE RÉACTIFS D'ACIDE SULFONIQUE
  申请人：DOW GLOBAL TECHNOLOGIES LLC

  公开号：WO2019067276A1

  公开（公告）日：2019-04-04

  A method comprising synthesizing a cyclic organic compound (3) via reaction of an unsubstituted or substituted alkene (1) with an unsubstituted or substituted acrylic acid (2) in the presence of a sulfonic acid reagent to make the cyclic organic compound (3) R1(H)C=C(H)R2 (1)

  一种方法包括在磺酸试剂的存在下，通过将未取代或取代的烯烃（1）与未取代或取代的丙烯酸（2）反应，合成一个环状有机化合物（3），使得环状有机化合物（3）为R1（H）C=C（H）R2（1）。
• Synthesis of cyclic organic compounds
  申请人：Univation Technologies, LLC

  公开号：US10975012B2

  公开（公告）日：2021-04-13

  A method comprising synthesizing a cyclic organic compound (3) via reaction of an substituted alkene (1) with an unsubstituted or substituted acrylic acid (2) in the presence of a sulfonic acid reagent to make the cyclic organic compound (3) R1(H)C═C(H)R2 (1)

  一种方法，包括在磺酸试剂存在下，通过取代的烯烃（1）与未取代或取代的丙烯酸（2）反应合成环状有机化合物（3），从而制得环状有机化合物（3） R1(H)C═C(H)R2 (1)
• Synthesis of cyclic organic compounds and metallocenes
  申请人：Univation Technologies, LLC

  公开号：US11059840B2

  公开（公告）日：2021-07-13

  A method comprising synthesizing a cyclic organic compound via reaction of an unsubstituted or substituted cyclohexene with an unsubstituted or substituted acrylic acid in the presence of phosphoric and/or sulfonic acid reagent to make the cyclic organic compound. Also, a method of synthesizing a ligand for a transition metal, and a related substituted ligand-metal complex and catalyst, from the unsubstituted or substituted cyclohexene and unsubstituted or substituted acrylic acid. Also, the cyclic organic compound, ligand, and substituted ligand-metal complex and catalyst synthesized thereby. Also a method of polymerizing an olefin with the catalyst to give a polyolefin, and the polyolefin made thereby.

  一种方法，包括在磷酸和/或磺酸试剂存在下，通过未取代或取代环己烯与未取代或取代丙烯酸反应合成环状有机化合物，从而制得环状有机化合物。另外，一种由未取代或取代的环己烯和未取代或取代的丙烯酸合成过渡金属配体以及相关取代配体-金属配合物和催化剂的方法。还有，由此合成的环状有机化合物、配体和取代配体-金属络合物及催化剂。还有一种用催化剂聚合烯烃以得到聚烯烃的方法，以及由此制得的聚烯烃。
• SYNTHESIS OF CYCLIC ORGANIC COMPOUNDS AND METALLOCENES
  申请人：Univation Technologies, LLC

  公开号：US20200277320A1

  公开（公告）日：2020-09-03

  A method comprising synthesizing a cyclic organic compound via reaction of an unsubstituted or substituted cyclohexene with an unsubstituted or substituted acrylic acid in the presence of phosphoric and/or sulfonic acid reagent to make the cyclic organic compound. Also, a method of synthesizing a ligand for a transition metal, and a related substituted ligand-metal complex and catalyst, from the unsubstituted or substituted cyclohexene and unsubstituted or substituted acrylic acid. Also, the cyclic organic compound, ligand, and substituted ligand-metal complex and catalyst synthesized thereby. Also a method of polymerizing an olefin with the catalyst to give a polyolefin, and the polyolefin made thereby.