3,3-diphenyl-9,10-di-n-undecyloxypyrano[3,2-a]phenazine

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 英文名称: 3,3-diphenyl-9,10-di-n-undecyloxypyrano[3,2-a]phenazine
• 英文别名: 3,3-Diphenyl-9,10-di(undecoxy)pyrano[3,2-a]phenazine；3,3-diphenyl-9,10-di(undecoxy)pyrano[3,2-a]phenazine
• 化学式: C₄₉H₆₂N₂O₃
• 分子量: 727.043
• InChiKey: FGOMPISDRIFSFA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.2
• 重原子数：
  54
• 可旋转键数：
  24
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  53.5
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2,5-二羟基-1,4-苯喹酮 在 9-溴-9-硼杂双环-[3.3.1]壬烷 、 titanium(IV) tetraethanolate 、 三溴化硼 、 potassium carbonate 、 三乙胺 、 cesium fluoride 作用下， 以 乙醇 、 二氯甲烷 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 24.0h， 生成 3,3-diphenyl-9,10-di-n-undecyloxypyrano[3,2-a]phenazine
  参考文献：
  名称：

  Photochromic Guests in Organogels

  摘要：

  3,3-Diphenyl-9,10-di-n-undecyloxypyrano[3,2-a]phenazine 3 was designed to be incorporated into fibres of 2,3-di-n-undecyloxyphenazine which display gel-forming ability in various fluids. A spectrokinetic study and the determination of the temperatures of gel-to-sol phase transition, give evidence of the insertion of the photochromic chromene into the organogelator network. Under continuous irradiation, the photochromic reaction induces a decrease of the gel strength which can be used to trigger the gel-to-sol phase transition.

  DOI：

  10.1080/10587250008023821

文献信息

• Photochromic Guests in Organogels
  作者：J. L. Pozzo、G. Clavier、F. Rustemeyer、H. Bouas-Laurent

  DOI：10.1080/10587250008023821

  日期：2000.6.1

  3,3-Diphenyl-9,10-di-n-undecyloxypyrano[3,2-a]phenazine 3 was designed to be incorporated into fibres of 2,3-di-n-undecyloxyphenazine which display gel-forming ability in various fluids. A spectrokinetic study and the determination of the temperatures of gel-to-sol phase transition, give evidence of the insertion of the photochromic chromene into the organogelator network. Under continuous irradiation, the photochromic reaction induces a decrease of the gel strength which can be used to trigger the gel-to-sol phase transition.