1-diethoxyphosphoryl-3-[3-(3-diethoxyphosphorylpropylsulfanyl)propylsulfanyl]propane | 193073-68-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: 1-diethoxyphosphoryl-3-[3-(3-diethoxyphosphorylpropylsulfanyl)propylsulfanyl]propane
• CAS: 193073-68-6
• 化学式: C₁₇H₃₈O₆P₂S₂
• 分子量: 464.565
• InChiKey: CYONRIGRKKXMAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.16
• 重原子数：
  27.0
• 可旋转键数：
  20.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  71.06
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  1-diethoxyphosphoryl-3-[3-(3-diethoxyphosphorylpropylsulfanyl)propylsulfanyl]propane 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 生成 3-[3-(3-Phosphanylpropylsulfanyl)propylsulfanyl]propylphosphane
  参考文献：
  名称：

  Smith, C. J.; Katti, K. V.; Higginbotham, C., Journal of labelled compounds and radiopharmaceuticals, 1997, vol. 40, p. 444 - 446

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3-丙二硫醇 、 二乙基(3-溴丙基)膦酸酯 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 生成 1-diethoxyphosphoryl-3-[3-(3-diethoxyphosphorylpropylsulfanyl)propylsulfanyl]propane
  参考文献：
  名称：

  Smith, C. J.; Katti, K. V.; Higginbotham, C., Journal of labelled compounds and radiopharmaceuticals, 1997, vol. 40, p. 444 - 446

  摘要：

  DOI：

文献信息

• Polymer Network Formation Using the Phosphane–ene Reaction: A Thiol–ene Analogue with Diverse Postpolymerization Chemistry
  作者：Ryan Guterman、Amir Rabiee Kenaree、Joe B. Gilroy、Elizabeth R. Gillies、Paul J. Ragogna

  DOI：10.1021/cm504784e

  日期：2015.2.24

  Air-stable primary phosphines were photopolymerized using phosphane-ene chemistry, the phosphorus analogue of the thiolene reaction, to fabricate a completely new class of polymer networks. It was demonstrated that the tunable thermal and physical properties accessible using thiol-ene chemistry could also be achieved using an analogous phosphane-ene reaction. At the same time, the presence of the P-31 nucleus that is easily observed using NMR spectroscopy allowed the chemical structures of the networks to be directly probed using solid state NMR spectroscopy. Following its incorporation into the network, phosphorus offers the distinct difference and advantage of being able to undergo a diverse array of further derivatization to afford functional materials. For example, the networks were demonstrated to serve as effective oxygen scavengers and to bind transition metals (e.g., Pd). By using the air stable ferrocenyl phosphine (FcCH(2)CH(2))PH2, redox-active networks were produced and these materials could be pyrolyzed to yield magnetic ceramics. Overall, this demonstrates the promise of phosphane-ene chemistry as an alternative to thiol-ene systems for providing functional materials for a diverse range of applications.