cis-1.2-dimethoxy-cyclohexane | 30363-80-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cis-1.2-dimethoxy-cyclohexane
• 英文别名: cis-1.2-Dimethoxy-cyclohexan；cis-1,2-Dimethoxycyclohexane；(1R,2S)-1,2-dimethoxycyclohexane
• CAS: 30363-80-5
• 化学式: C₈H₁₆O₂
• 分子量: 144.214
• InChiKey: BSGBGTJQKZSUTQ-OCAPTIKFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2909209000

反应信息

• 作为产物：
  描述：

  cis-1,2-cyclohexane 、 碘甲烷 在 silver(l) oxide 作用下， 反应 18.0h， 生成 cis-1.2-dimethoxy-cyclohexane
  参考文献：
  名称：

  Brettle,R.; Sutton,J.R., Journal of the Chemical Society. Perkin transactions I, 1975, p. 1947 - 1954

  摘要：

  DOI：

文献信息

• Aminocyclohexyl ether compounds and uses thereof
  申请人：Barrett G.M.

  公开号：US20070099983A1

  公开（公告）日：2007-05-03

  Aminocyclohexyl ether compounds are disclosed. The compounds of the present invention may be incorporated in compositions and kits. The present invention also discloses uses for the compounds and compositions, including the treatment of arrhythmia.

  本发明公开了氨基环己醚化合物。本发明的化合物可纳入组合物和套件中。本发明还公开了化合物和组合物的用途，包括治疗心律失常。
• AMINOCYCLOHEXYL ETHER COMPOUNDS AND USES THEREOF
  申请人：Jung Grace

  公开号：US20070254945A1

  公开（公告）日：2007-11-01

  Aminocyclohexyl ether compounds are disclosed. The compounds of the present invention may be incorporated in compositions and kits. The present invention also discloses uses for the compounds and compositions, including the treatment of arrhythmia.

  本发明揭示了氨基环己基醚化合物。本发明的化合物可被纳入组合物和套件中。本发明还揭示了化合物和组合物的用途，包括治疗心律失常。
• Mousseron; Granger; Merle, Bulletin de la Societe Chimique de France, 1947, p. 459,460
  作者：Mousseron、Granger、Merle

  DOI：——

  日期：——
• Photoinduced Electron Transfer Initiated Activation of Organoselenium Substrates as Carbocation Equivalents: Sequential One-Pot Selenylation and Deselenylation Reaction
  作者：Ganesh Pandey、B. B. V. Soma Sekhar

  DOI：10.1021/jo00103a031

  日期：1994.12

  The investigation presented in this paper explores the mechanistic aspects and synthetic potentials of PET activation of organoselenium substrates. Fluorescence quenching of (DCN)-D-1* by a number of organoselenium compounds (RCH(2)SeR', 1-4), correlation of the fluorescence quenching rate constants with the oxidation potentials of 1-4, and the dependence of photodissociation quantum yields of 1-4 on their concentration suggests the occurrence of electron transfer processes between (DCN)-D-1* and 1-4. Steady-state photolysis of 1-4 in the presence of (DCN)-D-1* leads to the efficient one-electron oxidative heterolytic dissociation of the carbon-selenium bond to produce the carbocation (RCH(2)(+) or equivalent) and radical-centered selenium species (R'Se-.) via the intermediacy of cation-radical [(RCH(2)SeR')(+.)]. Nucleophilic assistance in the fragmentation of (RCH(2)SeR')(+.) by methanol has been suggested on the basis of products obtained from the control PET reaction of neopentyl phenyl selenide (8). The synthetic utility of these findings has been demonstrated for the deselenylation (Table 4) as well as one-spot sequential selenylation-deselenylation (Table 5) reactions.
• Mousseron, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1942, vol. 215, p. 201
  作者：Mousseron

  DOI：——

  日期：——

表征谱图