hexadec-8t-enedioic acid | 121626-90-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: hexadec-8t-enedioic acid
• 英文别名: Hexadec-8t-endisaeure；hexadec-8-enedioic acid；Δ⁸-Hexadecandisaeure-(1,16)；(E)-hexadec-8-enedioic acid
• CAS: 121626-90-2
• 化学式: C₁₆H₂₈O₄
• 分子量: 284.396
• InChiKey: GMHMDWRXZOZTFA-OWOJBTEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  20
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  hexadec-8t-enedioic acid 在 吡啶 、 甲醇 、 氯化亚砜 、 对甲苯磺酸 作用下， 以 乙醚 、 二氯甲烷 、 苯 为溶剂， 反应 14.5h， 生成 bis[2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethyl] (E)-hexadec-8-enedioate
  参考文献：
  名称：

  Design, synthesis, and activity of membrane-disrupting bolaphiles

  摘要：

  DOI：

  10.1021/ja00171a026
• 作为产物：
  描述：

  8-溴辛酸 在 air 、 sodium hexamethyldisilazane 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 生成 hexadec-8t-enedioic acid
  参考文献：
  名称：

  容易从磷化磷中获得对称的Z-烯烃

  摘要：

  在无盐条件下，通过自氧化过程，可以从phospho盐以良好的定量收率获得对称的Z-烯烃。

  DOI：

  10.1016/0040-4039(96)01737-6

文献信息

• METHODS OF REFINING AND PRODUCING FUEL AND SPECIALTY CHEMICALS FROM NATURAL OIL FEEDSTOCKS
  申请人：Cohen Steven A.

  公开号：US20130035502A1

  公开（公告）日：2013-02-07

  Methods are provided for refining natural oil feedstocks. The methods comprise reacting the feedstock with a low-molecular-weight olefin or mid-weight olefin in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the olefins from the esters in the metathesized product. In certain embodiments, the methods further comprise transesterifying the esters in the presence of an alcohol to form a transesterified product.

  提供了一种精制天然油料的方法。该方法包括在存在交换催化剂的条件下，将油料与低分子量烯烃或中分子量烯烃反应，以形成包含烯烃和酯的交换产物。在某些实施例中，该方法还包括将交换产物中的烯烃与酯分离。在某些实施例中，该方法还包括在醇存在下对酯进行酯交换反应，以形成酯交换产物。
• Methods of Making Functionalized Internal Olefins and Uses Thereof
  申请人：Elevance Renewable Sciences, Inc.

  公开号：US20140171677A1

  公开（公告）日：2014-06-19

  A method of isomerizing a substance includes combining a substance including a terminal alkenyl group and a substance including a fluorosulfonic acid group in a reaction mixture, and forming a substance including a 2-alkenyl group from the substance including a terminal alkenyl group in the reaction mixture. The method may be used to functionalize a substance, as the substance including a 2-alkenyl group can be reacted with a functionalizing agent to form a substance including a first functional group. The methods may be used to form a dicarboxylic acid, such as suberic acid, from a renewable feedstock.

  一种异构化物质的方法包括将包含末端烯基基团的物质和包含氟磺酸基团的物质组合在反应混合物中，并从反应混合物中的包含末端烯基基团的物质形成包含2-烯基基团的物质。该方法可用于官能化物质，因为包含2-烯基基团的物质可以与官能化剂反应，形成包含第一官能团的物质。该方法可用于从可再生原料形成二羧酸，例如戊二酸。
• METHODS OF REFINING AND PRODUCING DIBASIC ESTERS AND ACIDS FROM NATURAL OIL FEEDSTOCKS
  申请人：Snead Thomas E.

  公开号：US20130085288A1

  公开（公告）日：2013-04-04

  Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

  提供了一种提炼天然油原料和生产二元酯和/或二元酸的方法。该方法包括在存在交换催化剂的情况下，将末端烯烃与内部烯烃反应，形成二元酯和/或二元酸。在某些实施例中，通过在存在交换催化剂的条件下反应原料来形成烯烃酯，以形成包含烯烃和酯的交换产物，将烯烃与酯从交换产物中分离，并在存在醇的情况下对酯进行酯交换反应，形成具有烯烃酯的酯交换产物。
• METHODS OF REFINING AND PRODUCING ISOMERIZED FATTY ACID ESTERS AND FATTY ACIDS FROM NATURAL OIL FEEDSTOCKS
  申请人：ELEVANCE RENEWABLE SCIENCES, INC.

  公开号：US20130204022A1

  公开（公告）日：2013-08-08

  Methods are provided for refining natural oil feedstocks and producing isomerized esters and acids. The methods comprise providing a C4-C18 unsaturated fatty ester or acid, and isomerizing the fatty acid ester or acid in the presence of heat or an isomerization catalyst to form an isomerized fatty ester or acid. In some embodiments, the methods comprise forming a dibasic ester or dibasic acid prior to the isomerizing step. In certain embodiments, the methods further comprise hydrolyzing the dibasic ester to form a dibasic acid. In certain embodiments, the olefin is formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having unsaturated esters.

  提供了一种精制天然油原料和生产异构酯和酸的方法。该方法包括提供C4-C18不饱和脂肪酸酯或酸，并在热或异构化催化剂存在下异构化脂肪酸酯或酸以形成异构化脂肪酸酯或酸。在某些实施例中，该方法包括在异构化步骤之前形成二元酯或二元酸。在某些实施例中，该方法进一步包括水解二元酯以形成二元酸。在某些实施例中，烯烃是通过在丙烯酸酯催化剂存在下反应原料以形成包含烯烃和酯的交换产物，从交换产物中分离烯烃和酯，然后在醇存在下对酯进行酯交换反应以形成具有不饱和酯的酯交换产物来形成的。
• Methods of Refining and Producing Fuel and Specialty Chemicals from Natural Oil Feedstocks
  申请人：Elevance Renewable Sciences, Inc.

  公开号：US20140336399A1

  公开（公告）日：2014-11-13

  Methods are provided for refining natural oil feedstocks. The methods include reacting the feedstock with a molar excess of low-molecular-weight olefins in the presence of a metathesis catalyst. In certain embodiments, the methods further include separating at least a portion of the unreacted low-molecular-weight olefins. In certain embodiments, the methods further include recycling the separated unreacted low-molecular-weight olefins.

  提供了一种精制天然油原料的方法。该方法包括在存在交换催化剂的情况下，将原料与低分子量烯烃的摩尔过量反应。在某些实施例中，该方法还包括分离至少部分未反应的低分子量烯烃。在某些实施例中，该方法还包括回收分离的未反应的低分子量烯烃。