9,10-di(5-methylthien-2-yl)-9,10-dihydro-phenanthrene-9,10-diol | 1010812-04-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 9,10-di(5-methylthien-2-yl)-9,10-dihydro-phenanthrene-9,10-diol
• 英文别名: 9,10-Bis(5-methylthiophen-2-yl)phenanthrene-9,10-diol
• CAS: 1010812-04-0
• 化学式: C₂₄H₂₀O₂S₂
• 分子量: 404.554
• InChiKey: CGMOVRRAYGWRHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  96.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  9,10-di(5-methylthien-2-yl)-9,10-dihydro-phenanthrene-9,10-diol 在 盐酸 、 溶剂黄146 、 锌 作用下， 以 水 为溶剂， 以80.1%的产率得到9,10-di(5-methylthien-2-yl)-phenanthrene
  参考文献：
  名称：

  Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s

  摘要：

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.

  DOI：

  10.1021/ol702873z
• 作为产物：
  描述：

  菲醌 、 alkaline earth salt of/the/ methylsulfuric acid 在 正丁基锂 、 水 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以66.8%的产率得到9,10-di(5-methylthien-2-yl)-9,10-dihydro-phenanthrene-9,10-diol
  参考文献：
  名称：

  Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s

  摘要：

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.

  DOI：

  10.1021/ol702873z

文献信息

• Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s
  作者：Bo He、Hongkun Tian、Yanhou Geng、Fosong Wang、Klaus Müllen

  DOI：10.1021/ol702873z

  日期：2008.3.1

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.