N-(4-(10-naphthalen-2-yl)anthracen-9-yl)phenyl-N-phenylnaphthalen-2-amine | 1335315-07-5

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: N-(4-(10-naphthalen-2-yl)anthracen-9-yl)phenyl-N-phenylnaphthalen-2-amine
• 英文别名: N-[4-(10-naphthalen-2-ylanthracen-9-yl)phenyl]-N-phenylnaphthalen-2-amine
• CAS: 1335315-07-5
• 化学式: C₄₆H₃₁N
• 分子量: 597.759
• InChiKey: BPQMUBYGVHXZPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.4
• 重原子数：
  47
• 可旋转键数：
  5
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  9-(2-萘)蒽 在 1,1'-双(二苯基膦)二茂铁 、 tris-(dibenzylideneacetone)dipalladium(0) 、 N-溴代丁二酰亚胺(NBS) 、 四(三苯基膦)钯 、 正丁基锂 、 potassium carbonate 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 水 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 67.5h， 生成 N-(4-(10-naphthalen-2-yl)anthracen-9-yl)phenyl-N-phenylnaphthalen-2-amine
  参考文献：
  名称：

  High efficient and high color pure blue light emitting materials: New asymmetrically highly twisted host and guest based on anthracene

  摘要：

  New asymmetrically highly twisted anthracene derivatives serve as a matched host and guest material in high efficiency blue OLEDs. 2-(2-Methylnaphtathalene-1-yl)-9,10-di(naphthalene-2-yl)anthracene and N-(4-(10-naphthalene-2-yl)anthracene-9-yl)phenyl-N-phenylnaphthalene-2-amine were prepared as host material and as guest material, respectively. Multilayer organic electroluminecent devices constructed using these foregoing twisted anthracene derivatives as the emitting layer gave quantum efficiencies 01 5% and exhibited a pure blue emission with CIE chromaticity coordinates x = 0.15, y = 0.14-0.18. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.06.008

文献信息

• High efficient and high color pure blue light emitting materials: New asymmetrically highly twisted host and guest based on anthracene
  作者：Il Kang、Jang-Yeol Back、Ran Kim、Yun-Hi Kim、Soon-Ki Kwon

  DOI：10.1016/j.dyepig.2011.06.008

  日期：2012.1

  New asymmetrically highly twisted anthracene derivatives serve as a matched host and guest material in high efficiency blue OLEDs. 2-(2-Methylnaphtathalene-1-yl)-9,10-di(naphthalene-2-yl)anthracene and N-(4-(10-naphthalene-2-yl)anthracene-9-yl)phenyl-N-phenylnaphthalene-2-amine were prepared as host material and as guest material, respectively. Multilayer organic electroluminecent devices constructed using these foregoing twisted anthracene derivatives as the emitting layer gave quantum efficiencies 01 5% and exhibited a pure blue emission with CIE chromaticity coordinates x = 0.15, y = 0.14-0.18. (C) 2011 Elsevier Ltd. All rights reserved.