bis(2-aminobutoxy)methane

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis(2-aminobutoxy)methane
• 英文别名: formaldehyde-[bis-(2-amino-butyl)-acetal]；Bis-(2-amino-butyloxy)-methan；1-(2-Aminobutoxymethoxy)butan-2-amine
• 化学式: C₉H₂₂N₂O₂
• 分子量: 190.286
• InChiKey: YGHGKQDGTZOZEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  70.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  Bis-(2-nitro-butoxy)-methan 在 二氧化碳 、 水 、 镍 作用下， 75.0 ℃ 、12.75 MPa 条件下， 生成 bis(2-aminobutoxy)methane
  参考文献：
  名称：

  Acetals of Nitro Alcohols and Corresponding Amino Acetals¹

  摘要：

  DOI：

  10.1021/ja01198a041

文献信息

• SALTS OF DIAMINOACETALS AND DIAMINOKETALS AND THEIR SYNTHESIS, AND THEIR TRANSFORMATIONS TO DIAMINOACETALS AND DIAMINOKETALS
  申请人：Connora Technologies, Inc.

  公开号：US20190016667A1

  公开（公告）日：2019-01-17

  This application relates, in part, to novel salts represented by the following structure of Formula (1): wherein R 1a is selected from the group consisting of hydrogen and optionally substituted alkyl (e.g., unsubstituted C 1-6 alkyl, e.g., —CH 3 ); R 1b is optionally substituted alkyl (e.g., unsubstituted C 1-6 alkyl, e.g., —CH 3 ); each occurrence of R 2 and R 3 is independently selected from the group consisting of hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, and optionally substituted aryl; R 2 and R 3 can combine with each other to form optionally substituted cycloalkyl; each m and n is independently an integer ranging from 1 to 20 (e.g., m and n is independently an integer ranging from 1 to 5); and each of Q 1 ⊖ and Q 2 ⊖ is independently a counterion (e.g., each of Q 1 ⊖ and Q 2 ⊖ is independently a counterion selected from the group consisting of chloride, bromide, fluoride, iodide, acetate, carboxylate, hydrogen sulfate, nitrate, and phenolate, and sulfonate, e.g., chloride), and methods of making the same.

  本申请部分涉及以下结构的新型盐（化学式（1））：其中R1a从氢和可选择地取代的烷基（例如，未取代的C1-6烷基，例如，-CH3）中选择；R1b是可选择地取代的烷基（例如，未取代的C1-6烷基，例如，-CH3）；R2和R3的每次出现独立地选择自氢、可选择地取代的烷基、可选择地取代的环烷基和可选择地取代的芳基组成；R2和R3可以相互结合形成可选择地取代的环烷基；每个m和n独立地是从1到20的整数范围（例如，m和n独立地是从1到5的整数）；Q1⊖和Q2⊖中的每一个独立地是一个反离子（例如，Q1⊖和Q2⊖中的每一个独立地是从氯化物、溴化物、氟化物、碘化物、乙酸盐、羧酸盐、硫酸氢盐、硝酸盐、苯酚盐和磺酸盐等组成中选择的反离子，例如氯化物），以及其制备方法。
• Silicon-containing compositions and their methods of use
  申请人：Aditya Birla Chemicals (USA) LLC

  公开号：US10919839B2

  公开（公告）日：2021-02-16

  Provided herein are silicon-containing recyclable polyamino compounds; epoxy resin compositions containing these silicon-containing reworkable or recyclable polyamino compounds; and methods of their use.

  本文提供了含硅的可回收聚氨基化合物；含有这些含硅的可再加工或可回收聚氨基化合物的环氧树脂组合物；以及它们的使用方法。
• Salts of diaminoacetals and diaminoketals and their synthesis, and their transformations to diaminoacetals and diaminoketals
  申请人：Aditya Birla Chemicals (USA) LLC

  公开号：US11124473B2

  公开（公告）日：2021-09-21

  This application relates, in part, to novel salts represented by the following structure of Formula (1): wherein R1a is selected from the group consisting of hydrogen and optionally substituted alkyl (e.g., unsubstituted C1-6 alkyl, e.g., —CH3); R1b is optionally substituted alkyl (e.g., unsubstituted C1-6 alkyl, e.g., —CH3); each occurrence of R2 and R3 is independently selected from the group consisting of hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, and optionally substituted aryl; R2 and R3 can combine with each other to form optionally substituted cycloalkyl; each m and n is independently an integer ranging from 1 to 20 (e.g., m and n is independently an integer ranging from 1 to 5); and each of Q1⊖ and Q2⊖ is independently a counterion (e.g., each of Q1⊖ and Q2⊖ is independently a counterion selected from the group consisting of chloride, bromide, fluoride, iodide, acetate, carboxylate, hydrogen sulfate, nitrate, and phenolate, and sulfonate, e.g., chloride), and methods of making the same.

  本申请部分涉及由以下式 (1) 结构代表的新型盐： 其中 R1a 选自由氢和任选取代的烷基（例如未取代的 C1-6 烷基，如 -CH3）组成的组；R1b 是任选取代的烷基（例如未取代的 C1-6 烷基，如、-R2和R3各自独立地选自氢、任选取代的烷基、任选取代的环烷基和任选取代的芳基组成的组；R2和R3可相互结合形成任选取代的环烷基；m和n各自独立地为1至20的整数（例如、Q1⊖和Q2⊖中的每一个独立地为反离子（例如，Q1⊖和Q2⊖中的每一个独立地为选自氯化物、溴化物、氟化物、碘化物、醋酸盐、羧酸盐、硫酸氢盐、硝酸盐、苯酚盐和磺酸盐组成的组中的反离子，例如氯化物），以及制造这些反离子的方法。
• US2363464
  申请人：——

  公开号：——

  公开（公告）日：——
• SILICON-CONTAINING COMPOSITIONS AND THEIR METHODS OF USE
  申请人：Connora Technologies, Inc.

  公开号：US20190016870A1

  公开（公告）日：2019-01-17

  Provided herein are silicon-containing recyclable polyamino compounds; epoxy resin compositions containing these silicon-containing reworkable or recyclable polyamino compounds; and methods of their use.