1,7-二氢吡咯并[3,2-f]吲哚 | 7075-70-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 1,7-二氢吡咯并[3,2-f]吲哚
• 英文名称: dihydrobenzo-<1,2-b:5,4-b'>-dipyrrole
• 英文别名: 1H,7H-Pyrrolo<3,2-f>indole；pyrroloindole；1,7-dihydro-pyrrolo[3,2-f]indole；1H,7H-Pyrrolo[3,2-F]indole；1,7-dihydropyrrolo[3,2-f]indole
• CAS: 7075-70-9
• 化学式: C₁₀H₈N₂
• 分子量: 156.187
• InChiKey: BRVRBWQXOMAOMF-UHFFFAOYSA-N

物化性质

• 熔点：
  215-216 °C
• 沸点：
  180 °C(Press: 0.01 Torr)
• 密度：
  1.366±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  31.6
• 氢给体数：
  2
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,7-二氢吡咯并[3,2-f]吲哚 以 四氢呋喃 、 乙腈 为溶剂， 反应 4.0h， 生成 3,5-Bis(dimethylaminomethyl)-1H,7H-pyrrolo<3,2-f>indole dimethiodide
  参考文献：
  名称：

  Synthesis and pharmacological activity of pyrroloindole and bisindole quaternary ammonium salts

  摘要：

  DOI：

  10.1007/bf00770314
• 作为产物：
  描述：

  4,6-二硝基-1,3-二甲苯 在 palladium on activated charcoal 氢气 作用下， 以 乙酸乙酯 、 N,N-二甲基甲酰胺 为溶剂， 25.0~120.0 ℃ 、101.33 kPa 条件下， 生成 1,7-二氢吡咯并[3,2-f]吲哚
  参考文献：
  名称：

  快速合成二氢苯并-[2,1- b：3,4- b ']-，[1,2- b：5,4- b ']和[1,2- b：4,5- b ' ]-双吡咯

  摘要：

  基于双烯胺（4）-（6）的催化还原反应，通过二甲基甲酰胺的缩合反应，对标题化合物（1）-（3）进行了简单，高产率的两步合成乙缩醛与适当的二硝基二甲苯。

  DOI：

  10.1039/c39870001176

文献信息

• CONJUGATED POLYMERS
  申请人：MERCK PATENT GMBH

  公开号：US20150076418A1

  公开（公告）日：2015-03-19

  The invention relates to novel conjugated polymers comprising in their backbone one or more divalent donor units, like for example benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl (BDT), that are linked on both sides to an acceptor unit, to methods of preparing the polymers and educts or intermediates used in such preparation, to polymer blends, mixtures and formulations containing the polymers, to the use of the polymers, polymer blends, mixtures and formulations as semiconductors organic electronic (OE) devices, especially in organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising these polymers, polymer blends, mixtures or formulations.

  该发明涉及一种新型的共轭聚合物，其主链中包含一个或多个二价供体单元，例如苯并[1,2-b:4,5-b′]二噻吩-2,6-二基 (BDT)，这些供体单元在两侧连接到一个受体单元，以及制备这些聚合物的方法和用于制备的底物或中间体，包含这些聚合物的聚合物混合物、混合物和配方，以及将这些聚合物、聚合物混合物、混合物和配方用作半导体有机电子（OE）器件，特别是在有机光伏（OPV）器件和有机光电探测器（OPD）中，以及包括这些聚合物、聚合物混合物、混合物或配方的OE、OPV和OPD器件。
• Keratin dyeing compounds, keratin dyeing compositions containing them, and use thereof
  申请人：Glenn Wayne Robert

  公开号：US20050193504A1

  公开（公告）日：2005-09-08

  Tricyclic 5-6-5 heteroaromatic keratin dyeing compounds having two heteroatoms. Compositions for the oxidative dyeing of keratin fibers, comprising a medium suitable for dyeing and one or more tricyclic 5-6-5 heteroaromatic keratin dyeing compounds having two heteroatoms. A method for oxidative dyeing of keratin fibers, comprising applying such compositions in the presence of an oxidizing agent, for a period sufficient to develop the desired coloration.

  三环5-6-5杂环角蛋白染料化合物具有两个杂原子。用于角蛋白纤维氧化染色的组合物，包括适用于染色的介质和一个或多个具有两个杂原子的三环5-6-5杂环角蛋白染料化合物。一种用于氧化染色的角蛋白纤维的方法，包括在氧化剂的存在下施用这样的组合物，以发展所需的着色。
• Organic electroluminescent element, and lighting device and display device each using same
  申请人：Konica Minolta, Inc.

  公开号：US10411203B2

  公开（公告）日：2019-09-10

  Provided is an organic electroluminescent element containing an anode, a cathode, and an organic functional layer containing one or a plurality of light-emitting layers, the organic functional layer being interposed between the anode and the cathode, wherein at least one of the light-emitting layers contains a compound having two condensed aromatic rings bonded to each other with a linking group; and the condensed aromatic rings form a π-π stacking structure in the molecule.

  本发明提供了一种有机电致发光元件，该元件包含阳极、阴极和含有一个或多个发光层的有机功能层，有机功能层位于阳极和阴极之间，其中至少一个发光层含有一种化合物，该化合物具有两个用连接基团相互键合的缩合芳香环；缩合芳香环在分子中形成π-π堆叠结构。
• Hydrogen storage by reversible hydrogenation of pi-conjugated substrates
  申请人：Pez Peter Guido

  公开号：US20050002857A1

  公开（公告）日：2005-01-06

  Processes are provided for the storage and release of hydrogen by means of a substantially reversible catalytic hydrogenation of extended pi-conjugated substrates which include large polycyclic aromatic hydrocarbons, polycyclic aromatic hydrocarbons with nitrogen heteroatoms, polycyclic aromatic hydrocarbons with oxygen heteroatoms, polycyclic aromatic hydrocarbons with alkyl, alkoxy, nitrile, ketone, ether or polyether substituents, pi-conjugated molecules comprising 5 membered rings, pi-conjugated molecules comprising six and five membered rings with nitrogen or oxygen hetero atoms, and extended pi-conjugated organic polymers. The hydrogen, contained in the at least partially hydrogenated form of the extended pi-conjugated system, can be facilely released for use by a catalytic dehydrogenation of the latter in the presence of a dehydrogenation catalyst which can be effected by lowering the hydrogen gas pressure, generally to pressures greater than 0.1 bar or raising the temperature to less than 250° C. or less, or by a combination of these two process parameters.

  本发明提供了通过对扩展的π-共轭基质进行基本可逆的催化加氢来储存和释放氢气的工艺、具有烷基、烷氧基、腈基、酮基、醚基或聚醚基取代基的多环芳香烃，由 5 个成员环组成的π-共轭分子，由具有氮或氧杂质原子的 6 个和 5 个成员环组成的π-共轭分子，以及扩展的π-共轭有机聚合物。扩展π-共轭体系的至少部分氢化形式中含有的氢，可以在脱氢催化剂的存在下，通过催化脱氢反应方便地释放出来，脱氢反应可以通过降低氢气压力（一般压力大于 0.1 巴）或将温度升高到低于 250 摄氏度或更低，或通过这两种工艺参数的组合来实现。
• Dehydrogenation of liquid fuel in microchannel catalytic reactor
  申请人：Toseland Allen Bernard

  公开号：US20060143981A1

  公开（公告）日：2006-07-06

  The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps: introducing a hydrogenated organic compound to a microchannel reactor incorporating a dehydrogenation catalyst; effecting dehydrogenation of said hydrogenated organic compound under conditions whereby said hydrogenated organic compound is present as a liquid phase; generating a reaction product comprised of a liquid phase dehydrogenated organic compound and gaseous hydrogen; separating the liquid phase dehydrogenated organic compound from gaseous hydrogen; and, recovering the hydrogen and liquid phase dehydrogenated organic compound.

  本发明是一种通过有机化合物的可逆氢化/脱氢来储存和输送氢气的改进工艺，其中有机化合物最初处于氢化状态。氢气生成路线的改进在于脱氢步骤和脱氢有机化合物的回收，具体步骤如下：将氢化有机化合物引入含有脱氢催化剂的微通道反应器；在所述氢化有机化合物以液相形式存在的条件下对所述氢化有机化合物进行脱氢；生成由液相脱氢有机化合物和气态氢组成的反应产物；将液相脱氢有机化合物与气态氢分离；以及回收氢和液相脱氢有机化合物。