4-Cyclopropylcyclohexene | 80105-51-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 4-Cyclopropylcyclohexene
• CAS: 80105-51-7
• 化学式: C₉H₁₄
• 分子量: 122.21
• InChiKey: DFVNMKGXTHPRJM-UHFFFAOYSA-N

物化性质

• 沸点：
  35 °C(Press: 13 Torr)
• 密度：
  0.965±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  重氮甲烷 、 4-乙烯基-1-环己烯 在 palladium diacetate 作用下， 以 乙醚 为溶剂， 反应 0.17h， 以77%的产率得到4-Cyclopropylcyclohexene
  参考文献：
  名称：

  Cyclopropanation of Terminal Olefins Using Diazomethane/Palladium(II) Acetate

  摘要：

  DOI：

  10.1055/s-1981-29572

文献信息

• Regioselective Simmons–Smith-type cyclopropanations of polyalkenes enabled by transition metal catalysis
  作者：Jacob Werth、Christopher Uyeda

  DOI：10.1039/c7sc04861k

  日期：——

  A cobalt catalyst imparts a high degree of regioselectivity in the reductive cyclopropanation of polyalkenes.

  一种钴催化剂在多烯的还原环丙烷化反应中赋予高度的位置选择性。
• Gai, Yonghua; Julia, Marc; Verpeaux, Jean-Noel, Bulletin de la Societe Chimique de France, 1996, vol. 133, # 9, p. 817 - 829
  作者：Gai, Yonghua、Julia, Marc、Verpeaux, Jean-Noel

  DOI：——

  日期：——
• Reaction of diazoalkanes with unsaturated compounds Communication 1. Cyclopropanation of olefins with diazomethane in the presence of copper compounds
  作者：O. M. Nefodov、I. E. Dolgii、Yu. V. Tomilov、V. G. Bordakov

  DOI：10.1007/bf00956238

  日期：1984.1
• Synthesis of Polycyclic Hydrocarbons Containing Cyclopropyl Groups¹
  作者：STANLEY D. KOCH、ROBERT M. KLISS、DOLORES V. LOPIEKES、ROBERT J. WINEMAN

  DOI：10.1021/jo01067a019

  日期：1961.9
• Regioselectivity and solvent effects in cyclopropanation of alkadienes
  作者：Edwin C. Friedrich、Fatemeh Niyati-Shirkhodaee

  DOI：10.1021/jo00006a044

  日期：1991.3

  A comparison of the regioselectivities for monocyclopropanation of limonene and 4-vinylclohexene using diiodomethane with zinc dust and copper(I) chloride in ether, with diethylzinc in toluene, or with triethylaluminum in toluene-dichloromethane has been carried out. Some studies were also done using dibromomethane with zinc dust and copper(I) chloride in ether. The procedure using diethylzinc in toluene exhibited the least steric hindrance toward cyclopropanation at more highly substituted, electron-rich double bonds. In a study of solvent effects on the diiodomethane, zinc dust, and copper(I) chloride procedure, use of diisopropyl ether as a reaction solvent proved to be a satisfactory method for almost doubling the steric requirements of the cyclopropanating reagent.