2-(10,10-dimethyl-10H-indeno[1,2-b]triphenylene-12-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2-(10,10-dimethyl-10H-indeno[1,2-b]triphenylene-12-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• 英文别名: 2-(10,10-dimethyl-10H-indeno[1,2-b]triphenylen-12-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane；2-(10,10-dimethyl-10H-indeno[2,1-b]triphenylen-12-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane；10,10-dimethyl-(10H-indeno[1,2-b]triphenylen-12-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane；2-(18,18-dimethyl-20-hexacyclo[12.11.0.02,7.08,13.016,24.017,22]pentacosa-1(25),2,4,6,8,10,12,14,16,19,21,23-dodecaenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• 化学式: C₃₃H₃₁BO₂
• 分子量: 470.419
• InChiKey: OZZBPFWQVSIKNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.62
• 重原子数：
  36
• 可旋转键数：
  1
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(10,10-dimethyl-10H-indeno[1,2-b]triphenylene-12-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 在 四(三苯基膦)钯 、 potassium acetate 、 sodium carbonate 作用下， 以 1,4-二氧六环 、 乙醇 、 甲苯 为溶剂， 反应 36.0h， 生成 2-(4-(10,10-dimethyl-10H-indeno[2,1-b]triphenylen-12-yl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  参考文献：
  名称：

  FLUORENE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME

  摘要：

  本发明公开了一种新的芴化合物以及使用该化合物的有机EL器件。采用新的芴化合物作为主体材料的有机EL器件可以降低驱动电压，延长半寿命。芴化合物可以作为发光层的蓝色发射主体材料，并提高蓝色发射器件的CIE色纯度。芴化合物由以下式(A)表示：其中R1至R6相同或不同。R1至R6独立地选自氢原子、卤素、具有1至20个碳原子的烷基基团、具有6至30个碳原子的取代或未取代芳基团、具有6至30个碳原子的取代或未取代芳基烷基基团、具有6至30个碳原子的取代或未取代杂环芳基团的组成。R7至R13相同或不同，R7至R13独立地选自氢原子、卤素、烷基基团、芳基团、杂环芳基团。m和n分别是0到3的整数，X选自碳或氮。

  公开号：

  US20140151645A1
• 作为产物：
  描述：

  2-联苯硼酸 以 甲醇 、 乙醇 、 二氯甲烷 、 氮气 、 甲苯 为溶剂， 生成 2-(10,10-dimethyl-10H-indeno[1,2-b]triphenylene-12-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  参考文献：
  名称：

  COMPOUND FOR ORGANIC ELECTROLUMINESCENCE DEVICE

  摘要：

  本发明公开了一种由以下化学式(I)或化学式(II)表示的化合物，有机EL器件采用该化合物作为磷光主体材料、阻挡正孔材料、阻挡正孔电子传输材料，可以展示出良好的性能。本发明中描述的定义相同。

  公开号：

  US20150214492A1

文献信息

• Organic compound for organic electroluminescent device
  申请人：LUMINESCENCE TECHNOLOGY CORPORATION

  公开号：US09048437B2

  公开（公告）日：2015-06-02

  The present invention discloses a novel organic compound is represented by the following formula(A), the organic EL device employing the compound as blue emitting layer can lower driving voltage, prolong half-lifetime and increase the efficiency. Wherein m represent an integer of 0 to 8, n represent an integer of 0 to 10, p represent an integer of 0 to 7, HAr represent a hydrogen, a halide, a cyanine group, a substituted or unsusbstituted heteroaryl group system having 5 to 6 aromatic ring atoms, R1 to R4 are identical or different. R1 to R4 are independently selected from the group consisting of a hydrogen atom, alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms.

  本发明揭示了一种新型有机化合物，其表示为以下式(A)，采用该化合物作为蓝光发射层的有机EL器件可以降低驱动电压，延长半寿命并提高效率。其中m表示0到8的整数，n表示0到10的整数，p表示0到7的整数，HAr表示氢、卤素、氰基、具有5到6个芳香环原子的取代或未取代杂芳基团，R1至R4相同或不同。R1至R4可独立地选择自氢原子、具有1到30个碳原子的烷基团、具有6到30个碳原子的取代或未取代芳基团、具有6到30个碳原子的取代或未取代芳基烷基团。
• Fluorene compound and organic electroluminescent device using the same
  申请人：Yen Feng-Wen

  公开号：US09040174B2

  公开（公告）日：2015-05-26

  The present invention discloses a new fluorene compound and organic EL device using the compound. The organic EL device employing the new fluorene compound as host material can lower driving voltage, prolong half-lifetime. The fluorene compound can functions as blue emitting host material of a light emitting layer and improve CIE color purity in blue emitting device. The fluorene compound are represented by the following formula(A): Wherein R1 to R6 are identical or different. R1 to R6 are independently selected from the group consisting of a hydrogen atom, a halide, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 6 to 30 carbon atoms. R7˜R13 are identical or different R7 to R13 are independently selected from the group consisting of hydrogen atom, halide, alkyl group, aryl group, heteroaryl group. m and n are independently an integer of 0 to 3, X is selected from carbon or nitrogen.

  本发明揭示了一种新的芴化合物和使用该化合物的有机EL器件。采用新的芴化合物作为主体材料的有机EL器件可以降低驱动电压，延长半寿命。芴化合物可以作为发光层的蓝色发射主体材料，并提高蓝色发射器件的CIE色彩纯度。芴化合物的结构式为(A)，其中R1至R6相同或不同。R1至R6独立地选自以下组中的一种：氢原子、卤素、具有1至20个碳原子的烷基、具有6至30个碳原子的取代或未取代芳基、具有6至30个碳原子的取代或未取代芳基烷基、具有6至30个碳原子的取代或未取代杂环芳基。R7至R13相同或不同，R7至R13独立地选自以下组中的一种：氢原子、卤素、烷基、芳基、杂环芳基。m和n分别是0至3的整数，X选自碳或氮。
• ORGANIC COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
  申请人：LUMINESCENCE TECHNOLOGY CORPORATION

  公开号：US20140166988A1

  公开（公告）日：2014-06-19

  The present invention discloses a novel organic compound is represented by the following formula(I), the organic EL device employing the organic compound as host material or dopant material of emitting layer and/or as electron transporting material can lower driving voltage, prolong half-lifetime and increase the efficiency. wherein m represent an integer of 0 to 10, n represent an integer of 0 to 2. X is a divalent bridge selected from the atom or group consisting from O, S, C(R 5 ) 2 , N(R 5 ), Si(R 5 ) 2 . Ar, R 1 to R 4 are substituents and the same definition as described in the present invention.

  本发明揭示了一种新型有机化合物，其由以下式（I）表示，采用该有机化合物作为发射层的主体材料或掺杂材料和/或作为电子传输材料的有机EL器件可以降低驱动电压，延长半衰期并提高效率。其中，m表示0到10的整数，n表示0到2的整数。X是从O、S、C（R5）2、N（R5）、Si（R5）2组成的原子或基选择的二价桥。Ar、R1至R4是取代基，其定义与本发明中所述相同。
• INDENOTRIPHENYLENE DERIVATIVES AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME
  申请人：LUMINESCENCE TECHNOLOGY CORPORATION

  公开号：US20140175383A1

  公开（公告）日：2014-06-26

  The present invention discloses a new indenotriphenylene derivatives and organic light emitting device using the derivatives. The organic light emitting device employing new indenotriphenylene derivatives as host material can lower driving voltage, prolong half-lifetime, increasing efficiency. The new indenotriphenylene derivatives are represented by the following formula (A): Wherein A 1 , A 2 are substituted or unsubstituted fused ring hydrocarbon units with one to five rings. Preferably A 1 , A 2 are phenyl group, naphthyl group, anthracenyl group, pyrenyl group, chrysenyl group, perylenyl group. R 1 to R 4 are identical or different. R 1 to R 4 are independently selected from the group consisting of a hydrogen atom, a halide, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 6 to 30 carbon atoms. X is selected from carbon atom or nitrogen atom.

  本发明揭示了一种新的茚三苯衍生物以及使用该衍生物的有机发光装置。采用新的茚三苯衍生物作为主体材料的有机发光装置可以降低驱动电压，延长半寿命，提高效率。新的茚三苯衍生物由以下式(A)表示：其中，A1、A2是具有1到5个环的取代或未取代的融合环烃基。优选的是，A1、A2是苯基、萘基、蒽基、芘基、芥子基、苝基。R1到R4相同或不同。R1到R4独立地选自由氢原子、卤素、具有1到20个碳原子的烷基、具有6到30个碳原子的取代或未取代的芳基、具有6到30个碳原子的取代或未取代的芳基烷基、具有6到30个碳原子的取代或未取代的杂芳基。X选自碳原子或氮原子。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：LUMINESCENCE TECHNOLOGY CORPORATION

  公开号：US20140175384A1

  公开（公告）日：2014-06-26

  The present invention discloses a novel material is represented by the following formula (A), the organic EL device employing the material as blue emitting layer can lower driving voltage, prolong half-lifetime and increase the efficiency. Wherein m represent an integer of 0 to 4, R 1 and R 2 are identical or different. R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms. R 3 and R 4 are identical or different, R 3 and R 4 are independently selected from the group consisting of hydrogen atom, a halide, a substituted or unsubstituted arylamine, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms.

  本发明公开了一种新型材料，其由以下式（A）所表示，采用该材料作为蓝色发射层的有机EL器件可以降低驱动电压，延长半寿命并增加效率。其中m表示0到4的整数，R1和R2相同或不同。R1和R2独立地选自由1到20个碳原子的烷基，具有6到30个碳原子的取代或未取代芳基，具有6到30个碳原子的取代或未取代芳基烷基的群。R3和R4相同或不同，R3和R4独立地选自氢原子，卤素，取代或未取代芳基胺，具有1到20个碳原子的取代或未取代烷基，具有6到30个碳原子的取代或未取代芳基的群。