2,2'-二[(二苯基膦基)甲基]-1,1'-联苯 | 111982-81-1

• 物质功能分类: 化学试剂 - 有机试剂 - 膦配体
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,2'-二[(二苯基膦基)甲基]-1,1'-联苯
• 中文别名: 2,2'-双(二苯基膦基甲基)-1,1'-联苯
• 英文名称: bisbi
• 英文别名: 2,2'-bis((diphenylphosphino)methyl)-1,1'-biphenyl；2,2′-bis(diphenylphosphinomethyl)-1,1′-biphenyl；Phosphine, [[1,1'-biphenyl]-2,2'-diylbis(methylene)]bis[diphenyl-；[2-[2-(diphenylphosphanylmethyl)phenyl]phenyl]methyl-diphenylphosphane
• CAS: 111982-81-1
• 化学式: C₃₈H₃₂P₂
• 分子量: 550.62
• InChiKey: SZKMTZNASRXXCE-UHFFFAOYSA-N

物化性质

• 熔点：
  84-86°C
• 沸点：
  695.6±55.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  40
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

SDS

MSDS英文版

反应信息

• 作为反应物：
  描述：

  2,2'-二[(二苯基膦基)甲基]-1,1'-联苯 、 RuH₂(CO)(PPh₃)₃ 以 甲苯 为溶剂， 以65%的产率得到RuH2(CO)(PPh3)(2,2'-bis(diphenylphosphinomethyl)-1,1'-biphenyl)
  参考文献：
  名称：

  Synthesis of novel ruthenium complexes of 2,2′-bis(diphenylphosphinomethyl)-1,1′-biphenyl and their catalytic hydrogenation reactions to α,β-unsaturated aldehydes

  摘要：

  Three ruthenium complexes containing BISBI [2,2'-bis(diphenylphosphinomethyl)-biphenyl], RuCl2(PPh3)(BISBI) 1, RuH-Cl(CO)(PPh3)(BISBI) 2 and RuH2(CO)(PPh3)(BISBI) 3, had been prepared. Their compositions and structures were characterized by P-31{H-1)-NMR,H-1-NMR and elemental analysis. Results of P-31{H-1}-NMR showed that the PPh3 in complex 1 was completely dissociated and a dimer complex [RuCl2(BISBI)](2) was generated in CDCl3 and C6D6 solutions. Molecular structure of 3 was also confirmed by single-crystal X-ray diffraction, the crystal belonged to a monoclinic system, P2(1)/n space group, a=16.771(3) Angstrom, b = 20.688(4) Angstrom, c = 17.139(3) Angstrom, beta = 106.03(3)degrees, V= 5715(3) Angstrom(3) and Z = 4. The hydrogenation results revealed that the three complexes showed much higher activities and selectivities than their analogous triphenylphosphine complexes for the hydrogenation of C=O bond in citral (3,7-dimethyl-2,6-octadienal) and cinnamaldehyde. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00726-2
• 作为产物：
  描述：

  (o-Chlorbenzyl)-diphenylphosphin 生成 2,2'-二[(二苯基膦基)甲基]-1,1'-联苯
  参考文献：
  名称：

  PUCKETTE, THOMAS A.

  摘要：

  DOI：
• 作为试剂：
  描述：

  哌啶 、 1-己烯 、 一氧化碳 在 2,2'-二[(二苯基膦基)甲基]-1,1'-联苯 、 dicarbonylacetylacetonato rhodium (I) 、 氢气 作用下， 以 甲醇 、 甲苯 为溶剂， 反应 4.0h， 以78.6%的产率得到N-heptylpiperidine
  参考文献：
  名称：

  使用带有四聚体磷配体的Rh配合物将末端烯烃对区域胺的高度区域选择性氢氨基甲基化

  摘要：

  已经开发了具有2、2'，6、6'-四（（二苯基膦基）甲基）-1,1'-联苯（Tetrabi）配体的Rh配合物催化的末端烯烃的高度区域选择性氢氨基甲基化。使用该方法，在底物/铑前体比率（S / Rh）为1000的情况下，可获得高达99％的胺选择性，168个线性/支链胺产物比率（n / i）和97.4％线性胺产率。在10000 S / Rh的比率下，周转次数达到6930，n / i可以达到> 525。几种不同的烯烃和仲胺以高的化学选择性（99％），收率（> 98％）和区域选择性（> 120）成功应用。

  DOI：

  10.1002/chem.201103073

文献信息

• [EN] DIHYDROFURAN DERIVATIVES AS INSECTICIDAL COMPOUNDS<br/>[FR] DÉRIVÉS DE DIHYDROFURANE EN TANT QUE COMPOSÉS INSECTICIDES
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2013026726A1

  公开（公告）日：2013-02-28

  The present invention provides compounds of formula I wherein Q is Q1 or Q2; A1, A2, A3 and A4 are independently of each other C-H, C-R7, or nitrogen; R1 is C1-C8haloalkyl; R2 is aryl or aryl substituted by one to five R11, or heteroaryl or heteroaryl substituted by one to five R11; and R3, R4, R5, R6 and R7 are as defined in the claims. The invention also provides methods of controlling insects, acarines, nematodes or molluscs which methods comprise applying to a pest, to a locus of a pest, or to a plant susceptible to attack by a pest an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula (I).

  本发明提供了式I的化合物，其中Q是Q1或Q2；A1、A2、A3和A4分别独立地为C-H、C-R7或氮；R1为C1-C8卤代烷基；R2为芳基或被1至5个R11取代的芳基，或者为杂环芳基或被1至5个R11取代的杂环芳基；以及R3、R4、R5、R6和R7如权利要求中所定义的。该发明还提供了控制昆虫、螨虫、线虫或软体动物的方法，该方法包括向害虫、害虫的生境或易受害虫侵害的植物施加式(I)的化合物的杀虫、杀螨、杀线虫或杀软体动物的有效量。
• HYDROFORMYLATION METHOD AND CATALYST USING RHODIUM-RUTHENIUM DUAL METAL AND TETRADENTATE PHOSPHINE LIGAND
  申请人：Wuhan Catalys Technology CO., LTD

  公开号：US20190337866A1

  公开（公告）日：2019-11-07

  A homogeneous catalytic reaction method and a catalyst for isomerization and hydroformylation of long-chain internal olefins are disclosed. A rhodium-ruthenium metal complex is used as a catalyst; and the ligands are tetradentate phosphine ligands. By means of the catalytic system, homogeneous internal olefin isomerization aid hydroformylation can be performed under a certain temperature and pressure to obtain aldehyde products having high normal to iso ratios. The present invention is applicable to not only long-chain internal olefins (≥C8) but also internal olefins having a carbon number less than 8.

  揭示了一种长链内烯烃异构化和氢甲酰化的均相催化反应方法和催化剂。使用铑-钌金属配合物作为催化剂；配体为四齿膦配体。通过该催化系统，可以在一定的温度和压力下进行均相内烯烃异构化和氢甲酰化，以获得具有高正对异比率的醛类产品。本发明不仅适用于长链内烯烃（≥C8），还适用于碳数小于8的内烯烃。
• ORGANIC MAGNESIUM PHOSPHIDE AND MANUFACTURING METHOD THEREOF, ORGANIC MAGNESIUM PHOSPHIDE COMPLEX AND MANUFACTURING METHOD THEREOF, AND MANUFACTURING METHOD OF ORGANIC PHOSPHORUS COMPOUND USING SAID PHOSPHIDE
  申请人：HOKKO CHEMICAL INDUSTRY CO., LTD.

  公开号：US20190248815A1

  公开（公告）日：2019-08-15

  An organic magnesium phosphide expressed by Formula (1) below and an organic magnesium phosphide complex expressed by Formula (9) below are provided, and a manufacturing method of organic phosphorus compound is characterized in that the above compounds used as a reagent is reacted with an electrophile: wherein R 1 and R 2 are each independently an aliphatic group, heteroaliphatic group, alicyclic group, or heterocyclic group, and X is chlorine, bromine, or iodine, wherein R 3 and R 4 are each independently an aliphatic group, heteroaliphatic group, aromatic group, alicyclic group, or heterocyclic group, and X and Y are each independently chlorine, bromine, or iodine.

  提供了以下公式（1）表示的有机磷化镁和以下公式（9）表示的有机磷化镁复合物，并且有机磷化合物的制备方法的特点在于将上述化合物作为试剂与电子亲和剂发生反应：其中R1和R2分别独立地为脂肪基、杂脂肪基、脂环基或杂环基，X为氯、溴或碘，其中R3和R4分别独立地为脂肪基、杂脂肪基、芳香基、脂环基或杂环基，X和Y分别独立地为氯、溴或碘。
• Cobalt-catalysed asymmetric hydrovinylation of 1,3-dienes
  作者：Yam N. Timsina、Rakesh K. Sharma、T. V. RajanBabu

  DOI：10.1039/c5sc00929d

  日期：——

  of bidentate 1,n-bis-diphenylphosphinoalkane-CoCl2 complexes Cl2Co[P~P]} and Me3Al or methylaluminoxane, acyclic (E)-1,3-dienes react with ethylene (1 atmosphere) to give excellent yields of hydrovinylation products. The regioselectivity (1,4- or...

  在双齿 1,n-双-二苯基膦烷-CoCl2 络合物 Cl2Co[P~P]} 和 Me3Al 或甲基铝氧烷存在下，无环 (E)-1,3-二烯与乙烯（1 个大气压）反应，得到优异的产率氢乙烯基化产物。区域选择性（1,4-或...
• [EN] ACETYLENE TOLERANT HYDROFORMYLATION CATALYSTS<br/>[FR] CATALYSEURS D'HYDROFORMYLATION TOLÉRANT L'ACÉTYLÈNE
  申请人：EASTMAN CHEM CO

  公开号：WO2010030339A1

  公开（公告）日：2010-03-18

  Hydrofoimylation catalysts which can tolerate high levels of alkyne impurities in an olefin feed stream. The catalysts are composed of rhodium in combination with fluorophosphite ligands or rhodium in combination with certain bidentate ligands. Propionaldehyde has been produced by the hydrofoimylation of ethylene streams containing up to 1000 parts per million of acetylene without any loss of activity due to the presence of the acetylene. Ethylene contaminated with acetylene at 10,000 ppm can also be converted to propionaldehyde but some loss of activity occurs.

  可以容忍烯烃进料流中高浓度炔烃杂质的水合甲醛催化剂。这些催化剂由铑与氟磷酸酯配体或铑与某些双齿配体组合而成。在含有高达1000万分之一的乙炔的乙烯流中水合甲醛已经被生产出来，而且由于存在乙炔而没有任何活性损失。含有10000 ppm乙炔的乙烯也可以转化为水合甲醛，但会有一定程度的活性损失。