5,8,14-trioctyl-diindolo[3,2-b:2',3'-h]carbazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 5,8,14-trioctyl-diindolo[3,2-b:2',3'-h]carbazole
• 英文别名: 5,15,25-Trioctyl-5,15,25-triazaheptacyclo[14.11.0.02,14.04,12.06,11.018,26.019,24]heptacosa-1(16),2(14),3,6,8,10,12,17,19,21,23,26-dodecaene
• 化学式: C₄₈H₆₃N₃
• 分子量: 682.048
• InChiKey: VLTBCKJHFOXAIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.2
• 重原子数：
  51
• 可旋转键数：
  21
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  14.8
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  N-octyl-2,7-bis(2'-nitrophenyl)carbazole 在 铜 N-溴代丁二酰亚胺(NBS) 、 copper(l) iodide 、 sodium hydride 、 potassium carbonate 、 tin(ll) chloride 作用下， 以 乙醇 、 二丁醚 、 乙酸乙酯 、 N,N-二甲基甲酰胺 、 丙酮 为溶剂， 反应 33.5h， 生成 5,8,14-trioctyl-diindolo[3,2-b:2',3'-h]carbazole
  参考文献：
  名称：

  Synthesis of Diindolocarbazoles by Ullmann Reaction:  A Rapid Route to Ladder Oligo(p-aniline)s

  摘要：

  New and facile synthesis of symmetric diindolocarbazoles was developed using the copper-catalyzed Ullmann reaction. The key step is a double-intramolecular cyclization reaction realized on N-alkyl-3,6-dibromo-2,7-bis(2'aminophenyl)carbazole derivatives which offers the desired symmetric ladder oligo(p-aniline)s. Depending upon the nature of the side- and/or end-groups, well-defined thin films and/or semiladder polymers could be obtained. These electroactive ladder oligomers may have great potential in organic electronics.

  DOI：

  10.1021/ol048543r

文献信息

• SUBSTITUTED INDOLOCARBAZOLES
  申请人：Wu Yiliang

  公开号：US20090036689A1

  公开（公告）日：2009-02-05

  A substituted indolocarbazole comprising at least one optionally substituted thienyl.

  一种含有至少一个可选择取代的噻吩基团的取代吲哚吡喃。
• Organic Electroluminescent Device
  申请人：Kai Takahiro

  公开号：US20120305904A1

  公开（公告）日：2012-12-06

  Disclosed is an organic electroluminescent device (organic EL device) that is improved in luminous efficiency, sufficiently secures driving stability, and has a simple configuration. This organic EL device has a light-emitting layer between an anode and a cathode piled one upon another on a substrate and the said light-emitting layer contains a fused polycyclic compound in which seven or more rings are fused together as a host material. The aforementioned fused polycyclic compound has a structure formed by fusing two or more indole rings to a carbazole ring. A specific example thereof is the compound represented by the following formula.
• US7173140B2
  申请人：——

  公开号：US7173140B2

  公开（公告）日：2007-02-06
• US7402681B2
  申请人：——

  公开号：US7402681B2

  公开（公告）日：2008-07-22
• US8110690B2
  申请人：——

  公开号：US8110690B2

  公开（公告）日：2012-02-07