6,8-dioxo-bicyclo[3.2.2]nonane-1,5-dicarboxylic acid diethyl ester | 21170-91-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 6,8-dioxo-bicyclo[3.2.2]nonane-1,5-dicarboxylic acid diethyl ester
• 英文别名: 6,8-Dioxo-bicyclo[3.2.2]nonan-1,5-dicarbonsaeure-diaethylester；Diaethyl-6.8-dioxobicyclo<3.2.2>nonan-1.5-dicarboxylat；1,5-Diaethoxycarbonylbicyclo<3.2.2>nonandion-(6,8)；1,5-Biscarbethoxybicyclo<3.2.2>nonan-6,8-dion；Diethyl 6,8-dioxobicyclo[3.2.2]nonane-1,5-dicarboxylate
• CAS: 21170-91-2
• 化学式: C₁₅H₂₀O₆
• 分子量: 296.32
• InChiKey: BNHRUAKQHCIHOS-UHFFFAOYSA-N

物化性质

• 沸点：
  407.8±45.0 °C(Predicted)
• 密度：
  1.280±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  86.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  6,8-dioxo-bicyclo[3.2.2]nonane-1,5-dicarboxylic acid diethyl ester 在 盐酸 作用下， 生成 二环[3.2.2]壬烷-7,9-二酮
  参考文献：
  名称：

  Gleiter, Rolf; Doerner, Thomas; Irngartinger, Hermann, Liebigs Annalen, 1996, # 3, p. 381 - 391

  摘要：

  DOI：
• 作为产物：
  描述：

  1,4-环己二酮-2,5-二甲酸二乙酯 、 1,3-二溴丙烷 在 sodium hydride 作用下， 以 乙二醇二甲醚 为溶剂， 生成 6,8-dioxo-bicyclo[3.2.2]nonane-1,5-dicarboxylic acid diethyl ester
  参考文献：
  名称：

  Gleiter, Rolf; Doerner, Thomas; Irngartinger, Hermann, Liebigs Annalen, 1996, # 3, p. 381 - 391

  摘要：

  DOI：

文献信息

• Synthesis of polymer intermediates containing the bicyclo[3.2.2]nonane ring
  作者：Ludek Taimr、James G. Smith

  DOI：10.1139/v70-201

  日期：1970.4.15

  The preparation of 1,5-biscarbethoxybicyclo[3.2.2]nonane and 1,5-bis(hydroxymethyl)bicyclo[3.2.2]nonane is described. The procedure generally followed that reported for the analogous bicyclo[2.2.2]...

  描述了 1,5-双碳甲氧基双环 [3.2.2] 壬烷和 1,5-双（羟甲基）双环 [3.2.2] 壬烷的制备。该程序通常遵循为类似的双环[2.2.2] ...
• High mountain psychro-xerophilous calcicolous pastures of the Iberian Peninsula:Minuartio-Poion ligulatae
  作者：Julio Peñas、Javier Cabello、Francisco Valle、Juan F. Mota

  DOI：10.1007/bf02899986

  日期：2001.12

  A syntaxonomical review of the Minuartio-Poion ligulatae (Festuco hystricis-Ononidetea striatae) in the Iberian Peninsula, supported by numerical classification (complete linkage clustering) and ordination (correspondence analysis), is presented. Communities of psychro-xerophilous calcicolous plants occur in the high mountains and "parameras" of the south and central western Iberian Peninsula, areas which suffer from severe frosts. The data collected point to three large groups of communities: those of the chorological Carpetano-lberico-Leonesa Province; those of the Castellano-Maestrazgo-Manchega Province; and those of the Mica Province. Within the latter group, similarities and differences between the communities were analyzed and two new associations (Herniario boissieri-Festucetum hystricis and Pimpinello gracilis-Festucetum nevadensis) were described. In addition, data clearly support the existence of a humidity-xericity gradient responsible for the distinction of the communities into different syntaxonomic units.
• Gleiter, Rolf; Doerner, Thomas; Irngartinger, Hermann, Liebigs Annalen, 1996, # 3, p. 381 - 391
  作者：Gleiter, Rolf、Doerner, Thomas、Irngartinger, Hermann

  DOI：——

  日期：——