sodium 4-acetylphenoxide | 3019-86-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: sodium 4-acetylphenoxide
• 英文别名: sodium 4-acetylphenolate；p-COMePhONa；NaO-p-C6H4COMe；sodium salt of p-hydroxy-acetophenone；Sodium;4-acetylphenolate
• CAS: 3019-86-1
• 化学式: C₈H₇O₂*Na
• 分子量: 158.132
• InChiKey: BAZPPGZSEXGRPI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.03
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  sodium 4-acetylphenoxide 以 sodium 1,3-benzodioxol-5-olate 为溶剂， 生成 5-(4-bromo-3-methyl-2-butenyloxy)-1,3-benzodioxol
  参考文献：
  名称：

  Insecticidal 1,3-benzodioxol derivatives

  摘要：

  本发明涉及以下结构的新化合物：##EQU1## 其中R.sub.2到R.sub.9具有不同的含义，包括例如烷基，X和Y包括O和S，s、v、w和z为0或整数，Ar.sub.1为##SPC1## 而R.sub.1为环烷基或##SPC2## 这些化合物具有杀虫性能。

  公开号：

  US03933804A1
• 作为产物：
  描述：

  对羟基苯乙酮 在 sodium hydride 作用下， 以 苯 为溶剂， 反应 0.5h， 以100%的产率得到sodium 4-acetylphenoxide
  参考文献：
  名称：

  Al Sabbagh, Mohamed Mowafak; Calmon, Michelle; Calmon, Jean-Pierre, Bulletin de la Societe Chimique de France, 1983, vol. 2, # 3-4, p. 73 - 77

  摘要：

  DOI：

文献信息

• 신규한 비닐페닐옥시기를 포함하는 화합물 및 이를 포함하는 감광성 포토레지스트 조성물
  申请人：Treeel Co.,Ltd 주식회사 트리엘(120160970130) Corp. No ▼ 134511-0269660BRN ▼582-87-00143

  公开号：KR20180084716A

  公开（公告）日：2018-07-25

  본 발명은 하기 [화학식 A] 내지 [화학식 C] 중 어느 하나로 표시되는 비닐페닐옥시기를 포함하는 화합물 및 이를 포함하는 감광성 포토레지스트 조성물에 관한 것으로서, 상기 [화학식 A] 내지 [화학식 C]는 발명의 상세한 설명에 기재된 바와 같다.

  This invention relates to a compound containing a vinylphenyloxy group represented by either [chemical formula A] to [chemical formula C], and a photosensitive photoresist composition containing the compound, wherein [chemical formula A] to [chemical formula C] are as described in the detailed description of the invention.
• Diaryl Ether Formation Merging Photoredox and Nickel Catalysis
  作者：Le Liu、Cristina Nevado

  DOI：10.1021/acs.organomet.1c00018

  日期：2021.7.26

  Photoredox and Ni catalysis are combined to produce diaryl ethers under mild conditions. A broad range of aryl halides and phenol derivatives are cross-coupled in the presence of a readily available organic photocatalyst and NiBr2(dtbpy). Symmetrical diaryl ethers have also been directly obtained from aryl bromides in the presence of water. Mechanistic investigations support the involvement of Ni(0)

  Photoredox 和 Ni 催化在温和条件下结合产生二芳基醚。在容易获得的有机光催化剂和 NiBr 2 (dtbpy)存在下，广泛的芳基卤化物和苯酚衍生物交叉偶联。对称二芳基醚也已在水存在下由芳基溴化物直接获得。机理研究支持在反应开始时 Ni(0) 物质的参与以及在生产性 C(sp 2 )-OAr 还原消除之前的 Ni(II)/Ni(III) 光催化单电子转移过程。
• Composition and method for combating insects with alkylenedioxyphenyl
  申请人：Sandoz Ltd.

  公开号：US03968235A1

  公开（公告）日：1976-07-06

  The present invention concerns the use of the compounds of the formula: ##EQU1## wherein R.sub.1 to R.sub.9 have various significances including e.g. alkyl, X and Y include O and S, and s, v, w and z are O or whole numbers and Ar.sub.1 is substituted phenyl, as insecticides, and insecticidal compositions containing said compounds as active agent.

  本发明涉及使用以下式的化合物：##EQU1## 其中R.sub.1到R.sub.9具有不同的含义，包括例如烷基，X和Y包括O和S，s、v、w和z为O或整数，Ar.sub.1为取代苯基，作为杀虫剂，并含有所述化合物作为活性剂的杀虫剂组合物。
• Importance of Open Structure of Nonmetal Based Catalyst in Hydrogen Bond Promoted Methanolysis of Activated Amide: Structure Dynamics between Monomer and Dimer Enabling Recombinant Covalent, Dative, and Hydrogen Bonds
  作者：Shunsuke Oishi、Junichi Yoshimoto、Susumu Saito

  DOI：10.1021/ja9029494

  日期：2009.7.1

  aminoorganoboron (AOB) compounds that involved a recombinant of covalent, dative, and hydrogen bonds. A combination process occurred via reorganizing elements and bonds between the two major structures (open and closed), which were chemically switchable through precise adjustment of either acidic or basic conditions. The structural dynamics favoring an open structure seem to be more important for catalysis, as represented

  我们揭示了隐藏在一系列氨基有机硼 (AOB) 化合物背后的结构动力学，这些化合物涉及共价键、配位键和氢键的重组。通过重组两个主要结构（开放和封闭）之间的元素和键，发生了一个组合过程，这两个主要结构可以通过精确调整酸性或碱性条件进行化学切换。有利于开放结构的结构动力学似乎对催化更为重要，如活化酰胺的甲醇分解。
• Ether of thioether substituted benzaldehydes
  申请人：Sandoz Ltd.

  公开号：US03978134A1

  公开（公告）日：1976-08-31

  The present invention concerns novel compounds of the formula: ##EQU1## wherein R.sub.1 to R.sub.9 have various significances including e.g. alkyl, X and Y include O and S and s, v, w and z are O or whole numbers and Ar.sub.1 is a formyl phenyl radical. The compounds possess insecticidal properties.

  本发明涉及以下结构的新化合物：##EQU1## 其中R.sub.1到R.sub.9具有不同的含义，包括例如烷基，X和Y包括O和S，s、v、w和z为O或整数，Ar.sub.1是一个甲酰基苯基基团。这些化合物具有杀虫性能。