9-(2,3-epithiopropyl)-9H-carbazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(2,3-epithiopropyl)-9H-carbazole
• 英文别名: 9-(thiiran-2-ylmethyl)carbazole；2-(9-carbazolyl)methylthiirane；3-(Carbazol-9-yl)-1,2-epithiopropane
• 化学式: C₁₅H₁₃NS
• 分子量: 239.341
• InChiKey: HZJVVCTVNBVJBV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  30.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-(2,3-epithiopropyl)-9H-carbazole 在 potassium carbonate 作用下， 以 甲苯 为溶剂， 反应 24.0h， 生成 2-(4-diethylaminophenyl)-3-phenyl-5-(carbazolyl-9-methyl)thiazolidine
  参考文献：
  名称：

  3-（咔唑-9-YL）-1,2-表硫丙烷与芳香胺的相互作用的研究

  摘要：

  DOI：

  10.1007/bf02256851
• 作为产物：
  描述：

  9-(环氧-2-甲基)-9H-咔唑 在 三聚氯氰 、 硫氰酸铵 作用下， 以 四氢呋喃 为溶剂， 反应 20.0h， 以82%的产率得到9-(2,3-epithiopropyl)-9H-carbazole
  参考文献：
  名称：

  Star-shaped poly(2-(9-carbazolyl)methylthiirane): Synthesis, analysis and photoluminescencent properties

  摘要：

  The polymerization of 2-(9-carbazolyl)methylthiirane (CMT) in the presence of cyclic oligo(potassium glycidoxide) as the macroinitiator activated 18-crown-6 leads to star-shaped polythioether with a cyclic core and mainly six arms, and with molecular masses relatively near to the calculated ones. A particularly intensive blue photoluminescence is shown by poly(CMT) in tetrahydrofuran solution at the concentration equal to 2 x 10(-6) mol/dm(3). This polymer dispersed in commercially available transparent polymers, i.e. poly(methyl methacrylate), polycarbonate or polystyrene gives blue photoluminescent materials. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2011.08.035

文献信息

• MULLIN V. A.; ZOLOTOV A. N.; SHISHKINA V. I., IZV. VUZOV. XIMIYA I XIM. TEXNOL., 1980, 23, HO 1, 41-43
  作者：MULLIN V. A.、 ZOLOTOV A. N.、 SHISHKINA V. I.

  DOI：——

  日期：——
• MULLIN V. A.; ZOLOTOV A. N.; SHISHKKINA V. I., IZV. VUZOV. XIMIYA I XIM. TEXNOL., 1980, 23, HO 3, 288-292
  作者：MULLIN V. A.、 ZOLOTOV A. N.、 SHISHKKINA V. I.

  DOI：——

  日期：——
• BATYROVA, L. M.;ROVKINA, N. M.;IVANOV, G. N.;ZAPARA, A. A., XIM. TEXNOL., SVOJSTVA I PRIMENENIE PLASTMASS, L.,(1988) 53-56
  作者：BATYROVA, L. M.、ROVKINA, N. M.、IVANOV, G. N.、ZAPARA, A. A.

  DOI：——

  日期：——
• Investigation of 3-(carbazol-9-YL)-1,2-epithiopropane interaction with aromatic amines
  作者：A. Stanishauskaite、V. Getautis、A. Railaite

  DOI：10.1007/bf02256851

  日期：2000.1
• Star-shaped poly(2-(9-carbazolyl)methylthiirane): Synthesis, analysis and photoluminescencent properties
  作者：Andrzej Swinarew、Andrzej Stolarzewicz、Zbigniew Grobelny、Beata Swinarew、Juozas V. Grazulevicius、Jurate Simokaitiene、Egle Andrikaityte

  DOI：10.1016/j.molstruc.2011.08.035

  日期：2011.11

  The polymerization of 2-(9-carbazolyl)methylthiirane (CMT) in the presence of cyclic oligo(potassium glycidoxide) as the macroinitiator activated 18-crown-6 leads to star-shaped polythioether with a cyclic core and mainly six arms, and with molecular masses relatively near to the calculated ones. A particularly intensive blue photoluminescence is shown by poly(CMT) in tetrahydrofuran solution at the concentration equal to 2 x 10(-6) mol/dm(3). This polymer dispersed in commercially available transparent polymers, i.e. poly(methyl methacrylate), polycarbonate or polystyrene gives blue photoluminescent materials. (C) 2011 Elsevier B.V. All rights reserved.