2-methylpentadecan-2-ol | 60129-23-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-methylpentadecan-2-ol
• 英文别名: 2-Methyl-2-pentadecanol
• CAS: 60129-23-9
• 化学式: C₁₆H₃₄O
• 分子量: 242.445
• InChiKey: STBVUIDGFXWZNR-UHFFFAOYSA-N

物化性质

• 沸点：
  160-162 °C(Press: 5 Torr)
• 密度：
  0.836 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-methylpentadecan-2-ol 在 三氯化铝 作用下， 生成 2-甲基-2-苯基十五烷
  参考文献：
  名称：

  On social percolation and small world network

  摘要：

  The social percolation model is generalized to include the propagation of two mutually exclusive competing effects on a one-dimensional ring and a two-dimensional square lattice. It is shown that the result depends significantly on which effect propagates first i.e. it is a non-commutative phenomenon. Then the propagation of one effect is studied on a small network. It generalizes the work of Moore and Newman of a disease spread to the case where the susceptibility of the population is random. Three variants of the Domany-Kinzel model are given. One of them (delayed) does not have a chaotic region for some value of the delay weight.

  DOI：

  10.1007/s100510070218
• 作为产物：
  描述：

  肉豆蔻酸 在 硫酸 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 21.0h， 生成 2-methylpentadecan-2-ol
  参考文献：
  名称：

  通过酸介导叔醇脱氧氟化合成叔氟化物

  摘要：

  据报道，甲磺酸和氟化氢钾的组合用于叔醇的脱氧氟化。在无金属条件下，使用容易获得、廉价且易于处理的试剂，一系列叔醇可以以优异的产率转化为相应的氟化物（23个例子的平均产率为85%）。机理研究表明，反应在 0 °C 下进行，部分通过消除/氢氟化途径进行，但没有观察到残留烯烃。还证明了这些条件在醚和酯的氟化中的应用。

  DOI：

  10.1021/acs.joc.3c01558

文献信息

• PROCESS FOR PRODUCING ESTER COMPOUND
  申请人：Imazeki Shigeaki

  公开号：US20100324314A1

  公开（公告）日：2010-12-23

  PROBLEM To provide an environmentally-friendly method for producing industrially an ester compound. SOLUTION The present invention is a method for producing an ester compound which comprises subjecting a carboxylic acid and an alcohol to dehydration-condensation reaction using an involatile acid catalyst and then removing the residual acid catalyst by bringing a weak basic substance into contact with the residual acid catalyst.

  问题提供一种生产工业酯化合物的环保方法。 解决方案是一种生产酯化合物的方法，包括将羧酸和醇经过脱水缩合反应，使用一种不挥发的酸催化剂，然后通过将弱碱性物质与残留的酸催化剂接触来去除残留的酸催化剂。
• METHOD FOR PRODUCING 2-HALOGENATED BENZOIC ACIDS
  申请人：SUMITOMO SEIKA CHEMICALS CO., LTD.

  公开号：US20180086687A1

  公开（公告）日：2018-03-29

  The purpose of the present invention is to provide a method for producing 2-halogenated benzoic acids, the method imparting high regioselectivity (high selectivity) and having a shorter reaction time than does the conventional reaction. This method for producing 2-halogenated benzoic acids, in order to achieve the above purpose, is characterized in that benzoic acids and a halogenating agent are reacted in the presence of an alkaline compound, making it possible to highly selectively obtain 2-halogenated benzoic acids.

  本发明的目的是提供一种生产2-卤代苯甲酸的方法，该方法具有高区域选择性（高选择性），且反应时间比传统方法更短。为了实现上述目的，这种生产2-卤代苯甲酸的方法的特点在于在碱性化合物存在下，将苯甲酸和卤代试剂反应，从而能够高度选择性地获得2-卤代苯甲酸。
• Complexed surfactant system
  申请人：Ko Ki-Hwan

  公开号：US20050164903A1

  公开（公告）日：2005-07-28

  The present invention relates to a mixed surfactant system, and particularly to a mixed surfactant system which comprises an anionic surfactant and a compound comprising at least one kind of non-ionic group or cationic group, and which thus increases cleaning power of the anionic surfactant, increases stability to hard water, lowers surface tension and cmc, and can control initial foamability and foam stability by the mixing ratio of the non-ionic surfactant and the cationic surfactant that can be added together, and that is therefore very useful for a detergent of solid, liquid, gel, or paste types.

  本发明涉及一种混合表面活性剂系统，特别是一种包含阴离子表面活性剂和至少一种非离子基团或阳离子基团的化合物的混合表面活性剂系统，从而增强阴离子表面活性剂的清洁能力，增加对硬水的稳定性，降低表面张力和cmc，并且可以通过非离子表面活性剂和阳离子表面活性剂的混合比例来控制初始泡沫性和泡沫稳定性，因此非常适用于固体、液体、凝胶或糊状洗涤剂。
• Hybrid onium salt
  申请人：Ishihara Masami

  公开号：US20050020710A1

  公开（公告）日：2005-01-27

  The present invention relates to a hybrid type onium salt having an iodonium salt and a sulfonium salt in the molecule, useful, for example, as a cationic type photopolymerization initiator and an acid generator for a chemically amplified resist and provides a hybrid type onium salt shown by the general formula [1]: [wherein R 1 to R 3 are each independently a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group or an amino group which maybe substituted; Q 1 is a direct-linkage, an oxygen atom, a sulfur atom or a lower alkylene chain; T 1 is an alkylene group or an arylene group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted; and R 4 is an alkyl group, an alkenyl group, an aryl group or an aralkyl group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted or a group shown by the general formula [2]: (wherein R 5 to R 7 are each independently a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group or an amino group which maybe substituted; Q 2 is a direct-linkage, an oxygen atom, a sulfur atom or a lower alkylene chain; T 2 an alkylene group or an arylene group, which may have a substituent selected from the group consisting of a halogen atom, an alkyl group, a haloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group and an amino group which may be substituted; A 3 is a counter anion; m is an integer of 0 to 4; and two ns are each independently an integer of 0 to 5); A 1 and A 2 are each independently a counter anion; and m and n are the same as described above], and a polymerization initiator or an acid generator, comprising said onium salt.

  本发明涉及一种杂化型离子盐，其分子中具有碘化离子盐和亚砜盐，例如，作为阳离子型光聚合引发剂和化学放大型抗蚀剂的酸发生剂有用，并提供由通式[1]所示的杂化型离子盐：[其中R1至R3分别独立地是卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基或氨基，可被取代；Q1是直链、氧原子、硫原子或较低的烷基链；T1是烷基或芳基，可具有从卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基中选择的取代基；R4是烷基、烯丙基、芳基或芳基烷基，可具有从卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基中选择的取代基或由通式[2]所示的基：（其中R5至R7分别独立地是卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基或氨基，可被取代；Q2是直链、氧原子、硫原子或较低的烷基链；T2是烷基或芳基，可具有从卤素原子、烷基、卤代烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基和可被取代的氨基中选择的取代基；A3是一个对离子；m是0到4的整数；两个n各自独立地是0到5的整数）；A1和A2各自独立地是一个对离子；m和n与上述描述相同]，以及包含该离子盐的聚合引发剂或酸发生剂。
• Copolymer compositions comprising a copolymer and one or more lubricating additives
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0450695A1

  公开（公告）日：1991-10-09

  Copolymer compositions comprising an alternating copolymer of carbon monoxide and one or more lubricating additives of the general formula X-R, in which X represents a polar moiety which is one of the following groups: (a) alcoholic -OH, (b) -O-R', (c) -CO-O-R', (d) -O-CO-R', and (e) -CO-OH, in which R' represents an alkyl group having up to 4 carbon atoms which may be substituted with 1 to 3 groups selected from (1) -O-R", (2) -CO-O-R" and (3) -O-CO-R", wherein each R", independently, represents hydrogen or an alkyl group having up to 4 carbon atoms, and R represents a monovalent hydrocarbyl radical having 5 to 30 carbon atoms which is attached to (one of) the polar group(s); and a process for improving flow properties of alternating copolymers of carbon monoxide comprising the addition thereto of one or more of said lubricating additives.

  由一氧化碳与一种或多种通式为 X-R 的润滑添加剂交替共聚而成的共聚物组合物，其中 X 代表极性基团，该极性基团为以下基团之一：(a)醇-OH，(b)-O-R'，(c)-CO-O-R'，(d)-O-CO-R'和(e)-CO-OH，其中 R'代表具有最多 4 个碳原子的烷基，可被 1 至 3 个选自(1)-O-R"、(2)-CO-O-R "和(3)-O-CO-R "的基团取代、其中每个 R "独立地代表氢或具有最多 4 个碳原子的烷基，R 代表具有 5 至 30 个碳原子的单价烃基，该烃基连接到（其中一个）极性基团上；以及一种改善一氧化碳交替共聚物流动特性的工艺，包括在其中加入一种或多种所述润滑添加剂。