9,9'-biacridine | 3295-68-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 9,9'-biacridine
• 英文别名: 9,9'-biacridinyl；9,9′-biacridine；9,9'-Biacridyl；9-acridin-9-ylacridine
• CAS: 3295-68-9
• 化学式: C₂₆H₁₆N₂
• 分子量: 356.426
• InChiKey: HZWAAAURPDLNLJ-UHFFFAOYSA-N

物化性质

• 熔点：
  400 °C(Solv: pyridine (110-86-1))
• 沸点：
  535.1±35.0 °C(Predicted)
• 密度：
  1.283±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  28
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,9'-biacridine 在 盐酸 、 锌 作用下， 生成 9,9'-Biacriden
  参考文献：
  名称：

  Decker; Petsch, Journal fur praktische Chemie (Leipzig 1954), 1935, vol. <2> 143, p. 223,227

  摘要：

  DOI：
• 作为产物：
  描述：

  9-氯吖啶 在 锌 作用下， 生成 9,9'-biacridine
  参考文献：
  名称：

  On the TICT Mechanism of 9,9′-Biaryl Compounds

  摘要：

  The UV/Vis absorption and fluorescence spectra for 9,9'-biacridinyl (BAC) and 9-(9'-acridyl)carbazole (C9AC) were recorded in approximately 50 different solvents. The analysis of the solvatochromic behaviour of the two chromophores, in terms of both polarity and polarizability (SPP), revealed that TICT emission in C9AC prevails only in solvents with SPP greater than or equal to 0.63, while that in BAC predominates throughout the solvent range studied [from 2-methylbutane (SPP = 0.479) to DMSO (SPP = 1.0)]. The peculiar behaviour of BAC suggests that the chromophore requires no cooperation from the solvent to trigger its TICT mechanism. Various hypotheses usually employed in analysing the TICT mechanism of biaryl compounds, including model emissions used to deconvolute spectra, the variation of TICT emission with the difference in redox potential between the chromophores involved, etc., are discussed.

  DOI：

  10.1002/(sici)1099-0690(199808)1998:8<1697::aid-ejoc1697>3.0.co;2-w

文献信息

• Co-crystals of 9,9′-bianthracene-10,10′-dicarboxylic acid with linear bidentate basic ligand molecules: synthesis, crystal structure, and properties based on the layer structure exfoliated by water
  作者：Misaki Okayasu、Shoko Kikkawa、Hidemasa Hikawa、Isao Azumaya

  DOI：10.1039/c9ce01460h

  日期：——

  Co-crystals of 9,9′-dianthracene-10,10′-dicarboxylic acid (1) with the linear bidentate bases 9,9′-biacridine (bac), phenazine (phez), 4,4′-dipyridine (dpy), and DABCO (dabco) were synthesized. In the crystal structures of the co-crystals of 1 and bac, phez, and dpy, one-dimensional (1D) structures were formed through the hydrogen bonding between the acid and the base. For each combination of the acid

  9,9'-二蒽-10,10'-二羧酸（1）与线性双齿双碱基9,9'-双cr啶（bac），吩嗪（phez），4,4'-联吡啶（dpy）的共晶体，并合成了DABCO（dabco）。在1与bac，phez和dpy的共晶体的晶体结构中，通过酸和碱之间的氢键形成一维（1D）结构。对于酸和碱的每种组合，获得了几种具有相似结构的多晶型共晶体。其中1和dabco的组合得到三种具有层状结构的共晶体。在一种共晶体中，观察到一种现象，其中的晶体层可能因滴水而剥落。共晶体的二维（2D）指纹图表明，形成一维结构的主要相互作用是O–H⋯N氢键，形成层状结构的主要相互作用是CH–π相互作用，并且后者在晶体坚固性上的相互作用要强于前者在共晶体中的相互作用。
• Luminescent compounds
  申请人：Patsenker D. Leonid

  公开号：US20080076188A1

  公开（公告）日：2008-03-27

  Reporter compounds based on aromatic and heterocyclic compounds, including intermediates used to synthesize the reporter compounds, and methods of synthesizing and using the reporter compounds, where the reporter compounds generally have the structure: where at least one pair of adjacent substituents (R a , R b ), (R b , R c ), (R c , R d ), (R d , R e ), (R e , R f ), (R f , R a ) is either a substituted cyclic or polycyclic group; or at least one set of three substituents (R a , R b , R c ), (R b , R c , R d ), (R c , R d , R e ), (R d , R e , R f ), (R e , R f , R a ) is a substituted cyclic or polycyclic group.

  基于芳香和杂环化合物的报告化合物，包括用于合成报告化合物的中间体，以及合成和使用报告化合物的方法，其中报告化合物通常具有以下结构：至少有一对相邻的取代基（Ra，Rb），（Rb，Rc），（Rc，Rd），（Rd，Re），（Re，Rf），（Rf，Ra）中的一对要么是取代的环或多环基团；或者至少有一组三个取代基（Ra，Rb，Rc），（Rb，Rc，Rd），（Rc，Rd，Re），（Rd，Re，Rf），（Re，Rf，Ra）是取代的环或多环基团。
• Novel 10, 10'-substituted-9,9'-biacridine luminescent molecules and their preparation
  申请人：PIERCE CHEMICAL COMPANY

  公开号：EP1026156A3

  公开（公告）日：2001-10-24

  Novel symmetrical and asymmetrical 10,10'-substituted-9,9'-biacridines and the synthesis of such symmetrical and asymmetrical 10,10'-substituted-9,9'-biacridine molecules and their derivatives is disclosed. These molecules are shown to produce light by chemiluminescence in the presence of signal solutions. These symmetrical or asymmetrical 10,10'-substituted-9,9'-biacridines are used alone or attached to haptens or macromolecules and are utilized as labels in the preparation of chemiluminescent, homogeneous or heterogeneous assays. They are also used in conjunction with other chemiluminescent label molecules to produce multiple analyte chemiluminescent assays.

  本发明揭示了对称和非对称的10,10'-取代-9,9'-联苯并及其衍生物的合成。这些分子在信号溶液存在下通过化学发光产生光。这些对称或非对称的10,10'-取代-9,9'-联苯并可以单独使用或附着在半抗原或大分子上，用于制备化学发光的均质或非均质检测。它们也可以与其他化学发光标记分子结合使用，以产生多种分析物的化学发光检测。
• Synthesis and solvent vapor-induced transformations of crystals of 1D coordination polymers assembled with continuous void space
  作者：M. Fukushima、S. Kikkawa、H. Hikawa、I. Azumaya

  DOI：10.1039/c7ce00640c

  日期：——

  (1b·THF), [Ag(L1)(CH3OH)]n(BF4)n·1.5n(furan) (1a·Furan), [Ag(L1)]n(BF4)n·nDCM (1a·DCM, DCM = dichloromethane), [Ag(L1)]n(ClO4)n·nDCM (1b·DCM), and [Ag2(L1)(CF3COO)2]n (1c). We also synthesized crystals of phenazine (L2) complexed with silver(I) cations which featured layered structures with no void space. In the crystals of 1a·THF and 1b·THF, a linear channel structure formed, which was filled with

  9,9'-双cr啶（L 1）具有垂直连接的a啶部分的三维结构，在分子的任一端具有两个配位点。用银（I）盐结晶L 1可以得到各种一维配位聚合物，其结构取决于所用的结晶溶剂和抗衡阴离子。我们合成了六种配合物：[Ag（L 1）] n（BF 4）n ·2 n THF（1a · THF，THF =四氢呋喃），[Ag（L 1）] n（ClO 4）n·2 n THF（1b · THF），[Ag（L 1）（CH 3 OH）] n（BF 4）n ·1.5 n（呋喃）（1a · Furan），[Ag（L 1）] n（BF 4）n · n DCM（1a · DCM，DCM =二氯甲烷），[Ag（L 1）] n（ClO 4）n · n DCM（1b · DCM）和[Ag2（ L 1）（CF 3 COO） 2 ] n（ 1c）。我们还合成了与银（ I）阳离子络合的吩嗪（ L 2）晶体，这些晶体具有没有空隙空间的分层结构。在1a
• NOVEL 10,10'-SUBSTITUTED-9,9'-BIACRIDINE LUMINESCENT MOLECULES AND THEIR PREPARATION
  申请人：——

  公开号：US20020034828A1

  公开（公告）日：2002-03-21

  Novel symmetrical and asymmetrical 10,10′-substituted-9,9′-biacridines and the synthesis of such symmetrical and asymmetrical 10,10′-substituted-9,9′-biacridine molecules and their derivatives is disclosed. These molecules are shown to produce light by chemiluminescence in the presence of signal solutions. These symmetrical or asymmetrical 10,10′-substituted-9,9′-biacridines are used alone or attached to haptens or macromolecules and are utilized as labels in the preparation of chemiluminescent, homogeneous or heterogeneous assays. They are also used in conjunction with other chemiluminescent label molecules to produce multiple analyte chemiluminescent assays.

  本发明揭示了新型对称和非对称的10,10'-取代-9,9'-联苯并化合物及其衍生物的合成方法。这些化合物在信号溶液存在下通过化学发光产生光。这些对称或非对称的10,10'-取代-9,9'-联苯并化合物可单独使用或连接到半抗原或大分子中，并用于制备化学发光的均相或不均相测定中的标记。它们还与其他化学发光标记分子结合使用，以产生多分析物化学发光测定。

表征谱图