2-氯-4-甲氧基吡啶氮氧化物 | 38608-87-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2-氯-4-甲氧基吡啶氮氧化物
• 英文名称: 2-Chlor-4-methoxy-pyridin-N-oxid
• 英文别名: 2-chloro-4-methoxypyridine N-oxide；Pyridine, 2-chloro-4-methoxy-, 1-oxide；2-chloro-4-methoxy-1-oxidopyridin-1-ium
• CAS: 38608-87-6
• 化学式: C₆H₆ClNO₂
• 分子量: 159.572
• InChiKey: YLWRUNDOGZQCEM-UHFFFAOYSA-N

物化性质

• 熔点：
  99-100 °C
• 沸点：
  345.4±22.0 °C(Predicted)
• 密度：
  1.29±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  34.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-氯-4-甲氧基吡啶氮氧化物 在 三乙胺 、 三氯氧磷 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以38.3%的产率得到2,6-二氯-4-甲氧基吡啶
  参考文献：
  名称：

  [EN] NOVEL 6-ARYLAMINO PYRIDONE SULFONAMIDES AND 6-ARYLAMINO PYRAZINONE SULFONAMDIES AS MEK INHIBITORS
  [FR] NOUVEAUX SULFONAMIDES DE 6-ARYLAMINO-PYRIDONE ET SULFONAMIDES DE 6-ARYLAMINO-PYRAZINONE SERVANT D'INHIBITEURS DE MEK

  摘要：

  公开号：

  WO2010145197A8
• 作为产物：
  描述：

  2-氯吡啶-N-氧化物 在 sodium hydride 作用下， 反应 0.5h， 生成 2-氯-4-甲氧基吡啶氮氧化物
  参考文献：
  名称：

  Alker, David; Ollis, W. David; Shahriari-Zavareh, Hooshang, Journal of the Chemical Society. Perkin transactions I, 1990, # 6, p. 1623 - 1630

  摘要：

  DOI：

文献信息

• N-(unsubstituted or substituted)-4-substituted-6-(unsubstituted or substituted)phenoxy-2-pyridinecarboxamides or thiocarboxamides, processes for producing the same, and herbicides
  申请人：Kureha Kagaku Kogyo Kabushiki Kaisha

  公开号：US06339045B1

  公开（公告）日：2002-01-15

  N-(substituted or unsubstituted)-4-substituted-6-(substituted or unsubstituted) phenoxy-2-pyridine carboxamide or thiocarboxamide represented by the general formula (I) and a process for producing the compound. A herbicide containing as an effective ingredient N-(substituted or unsubstituted)-4-substituted-6-(substituted or unsubstituted) phenoxy-2-pyridine carboxamide or thiocarboxamide represented by the general formula (I).

  N-(取代或未取代)-4-取代-6-(取代或未取代)苯氧基-2-吡啶羧酰胺或硫代羧酰胺，其通式表示为(I)，以及制备该化合物的方法。 包含N-(取代或未取代)-4-取代-6-(取代或未取代)苯氧基-2-吡啶羧酰胺或硫代羧酰胺，其通式表示为(I)，作为有效成分的除草剂。
• 6-(Nonsubstituted or substituted) phenoxy picolinic acids, process of preparing the same, and agricultural/horticultural germicides containing the same
  申请人：Kureha Kagaku Kabushiki Kaisha

  公开号：US06200933B1

  公开（公告）日：2001-03-13

  An agricultural or horticultural fungicide containing 6-(unsubstituted or substituted) phenoxy picolinic acid represented by the general formula (I), as an effective ingredient. wherein R is a halogen atom, a C1 to C4 alkyl group, a C1 to C4 haloalkyl group, a C1 to C4 alkoxy group, a C1 to C4 haloalkoxy group, a C1 to C4 alkylthio group, a C1 to C4 alkylamino group, a di(C1 to C4 alkyl)amino group or a C7 to C8 aralkyl(C1 to C4 alkyl)amino group; n2 is an integer of 0 to 3; Y is a C1 to C4 alkyl group, a C1 to C4 haloalkyl group, a C1 to C4 alkoxy group, a C1 to C4 haloalkoxy group, a C1 to C4 alkylthio group, a C1 to C4 haloalkylthio group or a halogen atom; and m is an integer of 0 to 5, and when m and n2 are not less than 2, Rs and Ys may be the same or different, respectively. The compound is useful as an effective ingredient of agricultural or horticultural fungicides.

  一种包含6-(未取代或取代)苯氧基吡啶甲酸的农业或园艺杀菌剂，其通式为(I)，作为有效成分。其中R是卤素原子，C1至C4烷基，C1至C4卤代烷基，C1至C4烷氧基，C1至C4卤代烷氧基，C1至C4烷硫基，C1至C4烷基胺基，二(C1至C4烷基)胺基或C7至C8芳基(C1至C4烷基)胺基；n2为0至3的整数；Y为C1至C4烷基，C1至C4卤代烷基，C1至C4烷氧基，C1至C4卤代烷氧基，C1至C4烷硫基，C1至C4卤代烷硫基或卤素原子；m为0至5的整数，当m和n2均不小于2时，Rs和Ys可以分别相同或不同。该化合物可作为农业或园艺杀菌剂的有效成分。
• Pharmaceutical compositions
  申请人：National Research Development Corp.

  公开号：US04587240A1

  公开（公告）日：1986-05-06

  Compounds which are a 1-hydroxypyrid-2-one in which one or more of the hydrogen atoms attached to ring carbon atoms are replaced by a substituent selected from aliphatic acyl, aliphatic amide, aliphatic amine, carboxy, cyano, aliphatic ester, halogen, hydroxy and sulpho groups, alkoxy groups and alkoxy groups substituted by an alkoxy, aliphatic amide, aliphatic amine, aliphatic ester, halogen or hydroxy group, aliphatic hydrocarbon groups and aliphatic hydrocarbon groups substituted by an alkoxy, aliphatic ester, halogen or hydroxy group, but excluding compounds in which said replacement of hydrogen atoms in the compound is effected only by substituents selected from aliphatic hydrocarbon groups, halogen groups and aliphatic hydrocarbon groups substituted by a halogen group, or a salt thereof containing a physiolgically acceptable ion or ions, are of value in the treatment of patients having a toxic concentration of a metal, particularly iron, in the body whilst the iron complexes of such compounds are of value in the treatment of iron deficiency anaemia.

  具有1-羟基吡啶-2-酮结构的化合物，其中环碳原子上的氢原子被从脂肪酰基，脂肪酰胺，脂肪胺，羧基，氰基，脂肪酯，卤素，羟基和磺酸基，烷氧基以及被烷氧基，脂肪酰胺，脂肪胺，脂肪酯，卤素或羟基取代的烷氧基取代的取代基所取代，脂肪烃基以及被烷氧基，脂肪酯，卤素或羟基取代的脂肪烃基，但不包括仅通过脂肪烃基，卤素基和被卤素基取代的脂肪烃基所取代的化合物，或者其含有生理上可接受的离子的盐，对于治疗体内有毒浓度的金属，尤其是铁，尤其有价值，而这些化合物的铁络合物对于治疗缺铁性贫血也具有价值。
• 6-phenoxy picolinic acid alkylidene hydrazide derivative, process for
  申请人：Kureha Kagaku Kogyo Kabushiki Kaisha

  公开号：US06159901A1

  公开（公告）日：2000-12-12

  A 6-phenoxy picolinic acid alkylidene hydrazide derivative, a process for producing the derivative and a herbicide containing the derivative as an effective ingredient. Such a compound is a novel compound and is useful as an effective ingredient of herbicides.

  一种6-苯氧基吡啶甲酸烷基亚肼衍生物，一种制备该衍生物的方法以及一种含有该衍生物作为有效成分的除草剂。这种化合物是一种新颖的化合物，可作为除草剂的有效成分。
• Calibrachoa plant named ‘Docaltitor50’
  申请人：DUMMEN GROUP B.V.

  公开号：USPP034313P2

  公开（公告）日：2022-06-07

  A new and distinct cultivar of Calibrachoa plant named ‘Docaltitor50’, characterized by its outwardly spreading, trailing and decumbent plant habit; vigorous growth habit; freely branching habit; early and freely flowering habit; large flowers with purplish red-colored petals with dark red-colored centers and venation and vivid yellow-colored throats and central star; and good garden performance.

  一种新的、独特的Calibrachoa植物品种，名为“Docaltitor50”，其特征为向外扩展、蔓延和倾斜的植株习性；生长旺盛；分枝自由；早期和自由开花习性；大花，紫红色花瓣，中心和脉红色，鲜黄色喉部和中央星形；以及良好的园艺表现。