1-methoxy-4-(4-methoxyphenyl)cyclohexa-1,3-diene | 110417-01-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-methoxy-4-(4-methoxyphenyl)cyclohexa-1,3-diene
• 英文别名: 1-Methoxy-4-(4-methoxycyclohexa-1,3-dien-1-yl)benzene
• CAS: 110417-01-1
• 化学式: C₁₄H₁₆O₂
• 分子量: 216.28
• InChiKey: RAFZZWDPWBKEAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-methoxy-4-(4-methoxyphenyl)cyclohexa-1,3-diene 在 sodium sulfide 、 吩噻嗪 、 盐酸羟胺 、 sodium acetate 、 甲基磺酰氯 、 三乙胺 作用下， 以 甲醇 、 乙醇 、 二氯甲烷 、 水 、 甲苯 为溶剂， 反应 29.0h， 生成 4-cyanomethyl-4-(4-methoxyphenyl)-2-cyclohexen-1-one
  参考文献：
  名称：

  Studies on the synthesis of morphinan and its related compounds: construction of morphinan skeleton

  摘要：

  DOI：

  10.1021/jo00232a032
• 作为产物：
  描述：

  1,1-dimethoxy-4-(4-methoxyphenyl)cyclohex-3-ene 在 碘代三甲硅烷 、 六甲基二硅氮烷 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 以90.5%的产率得到1-methoxy-4-(4-methoxyphenyl)cyclohexa-1,3-diene
  参考文献：
  名称：

  Studies on the synthesis of morphinan and its related compounds: construction of morphinan skeleton

  摘要：

  DOI：

  10.1021/jo00232a032

文献信息

• Liquid-crystalline polyester blend compositions
  申请人：Ueno Fine Chemicals Industry, Ltd.

  公开号：EP2264127A1

  公开（公告）日：2010-12-22

  The present invention provides a liquid-crystalline polyester blend composition comprising 100 parts by weight of a liquid-crystalline polyester blend and 0.1 - 300 parts by weight of calcium titanate and/or barium titanate: wherein said liquid-crystalline polyester blend is obtainable by combining liquid-crystalline polyester (A) (LCP A) and liquid-crystalline polyester (B) (LCP B) such that the ratio by weight of (LCP A)/ (LCP B) is 99/1 to 80/20; wherein, LCP A consists of 100 molar parts of major repeating units and optionally 0.1 - 2 molar parts of one or two repeating units that come from corresponding minor copolymerizing components, wherein the major repeating units are selected from the group consisting of aromatic oxycarbonyl repeating unit, aromatic dioxy repeating unit and aromatic dicarbonyl repeating unit, wherein 40 - 8C mol% of the major repeating units are the unit represented by formula (I); and the amounts of the aromatic dioxy repeating unit and the aromatic dicarbonyl repeating unit in the major repeating units are equimolar; and LCP B is selected from the group consisting of liquid-crystalline polyester (b-1) (LCP b-1) and liquid-crystalline polyester (b-2) (LCP b-2), each consisting of 100 molar parts of major repeating units and optionally 0.1 - 2 molar parts of one or two repeating units that come from corresponding minor copolymerizing components; wherein the major repeating units of LCP b-1 are aromatic oxycarbonyl repeating units; and the major repeating units of LCP b-2 are selected from the group consisting of aromatic oxycarbonyl repeating unit, aromatic dioxy repeating unit and aromatic dicarbonyl repeating unit, wherein the amounts of aromatic dioxy repeating unit and aromatic dicarbonyl repeating unit in the major repeating units are equimolar, wherein greater than or equal to 90 mol% of the major repeating units of LCP b-1 and LCP b-2 each are repeating units represented by formulae (I) and (II), and the molar proportion of the repeating units represented by formulae (I) to (II) is from 10/90 to 50/50; provided that at least one of LCP A and LCP B comprises one or two repeating units that come from corresponding minor copolymerizing components selected from the group consisting of aromatic diol, aromatic dicarboxylic acid, aromatic monocarboxylic acid and aromatic monohydroxy compound The liquid-crystalline polyester blend composition of the present invention exhibits excellent dielectric properties as well as good mechanical properties and thermal properties.

  本发明提供了一种液晶聚酯混合物组合物，该组合物由 100 份（按重量计）的液晶聚酯混合物和 0.1 - 300 份（按重量计）的钛酸钙和/或钛酸钡组成： 其中，所述液晶聚酯混合物可通过将液晶聚酯（A）（LCP A）和液晶聚酯（B）（LCP B）混合，使（LCP A）/（LCP B）的重量比为 99/1 至 80/20； 其中 LCP A 由 100 摩尔份的主要重复单元和 0.1 - 2 摩尔份的一个或两个重复单 元组成，这些重复单元来自相应的次要共聚组分、 其中主要重复单元选自芳香族氧羰基重复单元、芳香族二氧羰基重复单元和芳香族二羰基重复单元组成的组，其中 40 - 8C 摩尔%的主要重复单元是式 (I) 所代表的单元；主要重复单元中芳香族二氧羰基重复单元和芳香族二羰基重复单元的量为等摩尔；以及 LCP B 选自液晶聚酯（b-1）（LCP b-1）和液晶聚酯（b-2）（LCP b-2）所组成的组，每种液晶聚酯（b-1）由 100 摩尔份的主要重复单元和 0.1-2 摩尔份的一个或两个重复单元组成，这些重复单元来自相应的次要共聚组分； 其中 LCP b-1 的主要重复单元是芳香氧羰基重复单元；以及 LCP b-2 的主要重复单元选自芳香族氧羰基重复单元、芳香族二氧重复单元和芳香族二羰基重复单元组成的组，其中芳香族二氧重复单元和芳香族二羰基重复单元在主要重复单元中的含量为等摩尔、 其中 LCP b-1 和 LCP b-2 的主要重复单元中大于或等于 90 摩尔%分别为式 (I) 和 (II) 所代表的重复单元，且式 (I) 至 (II) 所代表的重复单元的摩尔比例为 10/90 至 50/50； 条件是 LCP A 和 LCP B 中至少有一个包含一个或两个重复单元，这些重复单元来自选 自芳香族二元醇、芳香族二羧酸、芳香族单羧酸和芳香族单羟基化合物的相应次要共聚组 分 本发明的液晶聚酯共混物具有优异的介电性能、机械性能和热性能。
• POLYARYLATE RESIN, FILM FORMED FROM SAME AND LAMINATE
  申请人：Unitika Ltd.

  公开号：EP3467003A1

  公开（公告）日：2019-04-10

  The present invention provides a polyarylate resin which is excellent in heat-resisting properties, abrasion-resisting properties, solubility properties in non-halogenated organic solvents, a water vapor-barrier property, mechanical properties, liquid sag-resisting properties and deformation-resisting properties (such as adhesive properties). The present invention relates to a polyarylate resin comprising a dihydric phenol residue shown in general formula (1) and an aromatic dicarboxylic acid residue shown in general formula (2), a film comprising the same and a laminated product thereof: (wherein X represents a liner or branched bivalent hydrocarbon group having 4 to 8 carbon atoms.) (wherein R1 and R2 respectively and independently represent a monovalent hydrocarbon group having 1 to 6 carbon atoms, which may be substituted by one or more halogen atoms, or a halogen atom, and p and q respectively and independently represent an integer of 0 to 4.).

  本发明提供了一种聚芳酸酯树脂，它具有优异的耐热性、耐磨性、在非卤化有机溶剂中的溶解性、水蒸气阻隔性、机械性能、抗液体下垂性能和抗变形性能（如粘合性）。本发明涉及一种由通式（1）所示的二水苯酚残基和通式（2）所示的芳香族二羧酸残基组成的聚芳酸酯树脂、由其组成的薄膜及其层压产品： (其中 X 代表具有 4 至 8 个碳原子的衬里或支链二价烃基）。 (其中 R1 和 R2 分别独立地代表具有 1 至 6 个碳原子的一价烃基，该烃基可被一个或多个卤素原子或卤素原子取代，p 和 q 分别独立地代表 0 至 4 的整数）。
• KAMETANI, TETSUJI;NISHIMURA, MASATO;HIGURASHI, KATSUYUKI;SUZUKI, YUKIO;TS+, J. ORG. CHEM., 52,(1987) N 23, 5233-5239
  作者：KAMETANI, TETSUJI、NISHIMURA, MASATO、HIGURASHI, KATSUYUKI、SUZUKI, YUKIO、TS+

  DOI：——

  日期：——
• Studies on the synthesis of morphinan and its related compounds: construction of morphinan skeleton
  作者：Tetsuji Kametani、Masato Nishimura、Katsuyuki Higurashi、Yukio Suzuki、Masayoshi Tsubuki、Toshio Honda

  DOI：10.1021/jo00232a032

  日期：1987.11