butyl-(1-methylen-allyl)-ether | 5648-32-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: butyl-(1-methylen-allyl)-ether
• 英文别名: Butyl-(1-methylen-allyl)-aether；2-Butoxy-buta-1,3-dien；2-Butyloxy-butadien-(1.3)；1-Buta-1,3-dien-2-yloxybutane
• CAS: 5648-32-8
• 化学式: C₈H₁₄O
• 分子量: 126.199
• InChiKey: XCCYSLQYQQSNAN-UHFFFAOYSA-N

物化性质

• 沸点：
  63-65 °C(Press: 40 Torr)
• 密度：
  0.8092 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  9
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,2-dibromo-1-butoxyethane 在 氢氧化钾 作用下， 生成 butyl-(1-methylen-allyl)-ether
  参考文献：
  名称：

  Schostakowskii; Mamedow, Zhurnal Obshchei Khimii, 1959, vol. 29, p. 3922,3924;engl.Ausg.S.3880,3882

  摘要：

  DOI：

文献信息

• FLUORINE-CONTAINING COPOLYMER HAVING EXCELLENT WASHING RESISTANCE AND SOIL RELEASE AGENT
  申请人：Uesugi Norimasa

  公开号：US20100093919A1

  公开（公告）日：2010-04-15

  Disclosed is a soil release agent composition essentially containing a fluorine-containing copolymer, which is essentially composed of (a) a fluorine-containing monomer having a fluoroalkyl group, (b) a polyalkyleneglycol (meth)acrylate, (c) a monomer having an acetoacetyl group and (d) a monomer having a cation-donating group, and a crosslinking agent. This soil release agent composition imparts a base material such as a fiber fabric with excellent oil repellency, antifouling property and soil releasing property, while maintaining washing resistance of the base material. The monomer (a) is preferably represented by the following formula (1). CH 2 ═C(—X)—C(═O)—Y-Z-Rf  (1) (In the formula, X represents a hydrogen atom, a linear or branched alkyl group having 1-21 carbon atoms, a fluorine atom, a chlorine atom or the like; Y represents —O— or —NH—; Z represents an aliphatic group having 1-10 carbon atoms, an aromatic group having 6-18 carbon atoms, an alicyclic group or the like; and Rf represents a linear or branched fluoroalkyl group having 1-21 carbon atoms.)

  本发明公开了一种土壤防污剂组合物，其基本上包含一种含氟共聚物，其基本上由(a)含有氟烷基的含氟单体，(b)聚烯烃醇醚（甲基）丙烯酸酯，(c)含有乙酰乙酰基的单体和(d)含有离子给体基团的单体组成，以及交联剂。该土壤防污剂组合物赋予基材料（例如纤维织物）优异的防油性、防污性和排污性，同时保持基材料的耐洗性。单体（a）最好由以下式子（1）表示： CH2═C(—X)—C(═O)—Y-Z-Rf  (1) （在公式中，X表示氢原子，具有1-21个碳原子的线性或支链烷基，氟原子，氯原子或类似物；Y表示—O—或—NH—；Z表示具有1-10个碳原子的脂肪族基，具有6-18个碳原子的芳香族基，脂环族基或类似物；Rf表示具有1-21个碳原子的线性或支链氟烷基。）
• PHOTOSENSITIVE RESIN COMPOSITION
  申请人：Asahi Kasei E-materials Corporation

  公开号：EP2221326A1

  公开（公告）日：2010-08-25

  There is provided a photosensitive resin composition comprising: (a) 100 parts by weight of a polyorganosiloxane obtained by a method of combining at least one silanol compound represented by the following formula (1):         R12Si(OH)2     (1) the groups in the formula being defined in the claims}, at least one alkoxysilane compound represented by the following formula (2):         R2aR3bSi(OR4)4-a-b     (2) the groups in the formula being defined in the claims} and a catalyst, and polymerizing them without active addition of water; (b) 1-50 parts by weight of a photopolymerization initiator; (c) 40-600 parts by weight of a fluorene compound represented by the following formula (3): the groups in the formula being defined in the claims}; and (d) 20-300 parts by weight of a compound other than component (c), having one or two (meth)acryloyl groups in the molecule.

  提供了一种光敏树脂组合物，其中包括 (a) 100 重量份的聚有机硅氧烷，该聚有机硅氧烷是通过将至少一种由下式(1) 代表的硅烷醇化合物结合的方法得到的： R12Si(OH)2 (1) 式中的基团在权利要求中定义}，至少一种由下式(2)代表的烷氧基硅烷化合物： R2aR3bSi(OR4)4-a-b (2) 权利要求中定义的式中基团}和催化剂，并在不主动加水的情况下进行聚合； (b) 1-50 份（按重量计）光聚合引发剂； (c) 40-600 份（重量）由下式（3）代表的芴化合物： 权利要求中定义的式中基团}；和 (d) 20-300 份（重量）除成分(c)外的化合物，其分子中有一个或两个（甲基）丙烯酰基。
• The Effect on Attribute Prediction of Location Uncertainty in Spatial Data
  作者：John Gabrosek、Noel Cressie

  DOI：10.1111/j.1538-4632.2002.tb01088.x

  日期：2002.7

  A datum is considered spatial if it contains location information. Typically, there is also attribute information, whose distribution depends on its location. Thus, error in location information can lead to error in attribute information, which is reflected ultimately in the inference drawn from the data. We propose a statistical model for incorporating location error into spatial data analysis. We investigate the effect of location error on the spatial lag, the covariance function, and optimal spatial linear prediction (that is, kriging). We show that the form of kriging after adjusting for location error is the same as that of kriging without adjusting for location error. However, location error changes entries in the matrix of explanatory variables, the matrix of co‐variances between the sample sites, and the vector of covariances between the sample sites and the prediction location. We investigate, through simulation, the effect that varying trend, measurement error, location error, range of spatial dependence, sample size, and prediction location have on kriging after and without adjusting for location error. When the location error is large, kriging after adjusting for location error performs markedly better than kriging without adjusting for location error, in terms of both the prediction bias and the mean squared prediction error.
• Acetylene Polymers and their Derivatives. XXIII. The Preparation and Polymerization of Oxyprenes
  作者：Harry B. Dykstra

  DOI：10.1021/ja01314a064

  日期：1935.11
• Petrow, Zhurnal Obshchei Khimii, 1949, vol. 19, p. 1051
  作者：Petrow

  DOI：——

  日期：——