(E)-十四碳-12-烯-9-炔醇 | 42521-44-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: (E)-十四碳-12-烯-9-炔醇
• 英文名称: (E)-Tetradec-12-en-9-yn-1-ol
• 英文别名: 12-Tetradecen-9-yn-1-ol, (12E)-
• CAS: 42521-44-8
• 化学式: C₁₄H₂₄O
• 分子量: 208.344
• InChiKey: BSIFYCYOKFFUMK-NSCUHMNNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 海关编码：
  2905290000

反应信息

• 作为反应物：
  描述：

  (E)-十四碳-12-烯-9-炔醇 在 P-2 Ni 氢气 作用下， 以 乙醇 为溶剂， 以85%的产率得到9顺12反-十四碳二烯醇
  参考文献：
  名称：

  Stereodirectional synthesis of the main component of pheromone (9Z,12E)-tetradeca-9,12-dienyl acetate by cross-coupling

  摘要：

  By cross-coupling of alkynyl cuprate with crotyl halides was synthesized (9Z,12E)-tetradeca-9-12-dienyl acetate, the main component of pheromones of several insect species Lepidoptera. The assignment of the chemical shifts of diene system was performed by H-1 and (NMR)-N-13 spectroscopy.

  DOI：

  10.1007/bf02757427
• 作为产物：
  描述：

  9-癸炔-1-醇 在 盐酸 、 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 4.5h， 生成 (E)-十四碳-12-烯-9-炔醇
  参考文献：
  名称：

  Stereodirectional synthesis of the main component of pheromone (9Z,12E)-tetradeca-9,12-dienyl acetate by cross-coupling

  摘要：

  By cross-coupling of alkynyl cuprate with crotyl halides was synthesized (9Z,12E)-tetradeca-9-12-dienyl acetate, the main component of pheromones of several insect species Lepidoptera. The assignment of the chemical shifts of diene system was performed by H-1 and (NMR)-N-13 spectroscopy.

  DOI：

  10.1007/bf02757427

文献信息

• ODINOKOV, V. N.;TOLSTIKOV, G. A.;ISHMURATOV, G. YU.;BOTSMAN, L. P.;LADENK+
  作者：ODINOKOV, V. N.、TOLSTIKOV, G. A.、ISHMURATOV, G. YU.、BOTSMAN, L. P.、LADENK+

  DOI：——

  日期：——
• Stereodirectional synthesis of the main component of pheromone (9Z,12E)-tetradeca-9,12-dienyl acetate by cross-coupling
  作者：E. D. Matveeva、A. S. Erin、I. F. Leshcheva、A. L. Kurts

  DOI：10.1007/bf02757427

  日期：2000.6

  By cross-coupling of alkynyl cuprate with crotyl halides was synthesized (9Z,12E)-tetradeca-9-12-dienyl acetate, the main component of pheromones of several insect species Lepidoptera. The assignment of the chemical shifts of diene system was performed by H-1 and (NMR)-N-13 spectroscopy.